Issue 45, 2021

Laser spectroscopy of helium solvated molecules: probing the inertial response

Abstract

Helium is the only solvent within which molecules can “freely” rotate, albeit with an increased moment of inertia relative to the gas phase. Evidence for this can be obtained by performing infrared laser spectroscopy on molecules embedded large helium clusters (nanodroplets), which often reveals rotationally resolved lines that are more closely spaced than in vacuo. The additional rotational inertia results from coupling of the helium to the molecule (rotor), and decreases in going from heavy (e.g., SF6) to light (e.g., CH4) rotors due to a partial breakdown in the adiabatic (following) approximation; faster (lighter) rotors cannot couple as well to helium since their effective interaction with helium is less anisotropic. In addition to this “mass” dependence to the coupling, there is also a time dependence to it, which shows up in the IR spectra as an asymmetry in the rovibrational lineshapes; this results from a delay in the response of helium to the change in rotational speed of the solvated molecule (when ΔJ = ±1). In this perspective we discuss the coupling between various probe molecules and helium that have been investigated by infrared laser spectroscopy in the frequency domain.

Graphical abstract: Laser spectroscopy of helium solvated molecules: probing the inertial response

Article information

Article type
Perspective
Submitted
16 صفر 1443
Accepted
28 ربيع الأول 1443
First published
28 ربيع الأول 1443

Phys. Chem. Chem. Phys., 2021,23, 25467-25479

Laser spectroscopy of helium solvated molecules: probing the inertial response

P. L. Raston, Phys. Chem. Chem. Phys., 2021, 23, 25467 DOI: 10.1039/D1CP04368D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements