Issue 1, 2020

Ring-opening metathesis polymerization of a strained stilbene-based macrocyclic monomer

Abstract

We report the synthesis of a new class of strained macrocycle that performs well in ring-opening metathesis polymerization (ROMP). The polymerization displays chain growth characteristics with evidence of secondary metathesis in the form of chain transfer. The unique structure enables access to stilbene-based polymers that are traditionally prepared via uncontrolled polymerizations.

Graphical abstract: Ring-opening metathesis polymerization of a strained stilbene-based macrocyclic monomer

Supplementary files

Article information

Article type
Research Article
Submitted
30 محرم 1441
Accepted
23 ربيع الأول 1441
First published
24 ربيع الأول 1441

Mater. Chem. Front., 2020,4, 252-256

Author version available

Ring-opening metathesis polymerization of a strained stilbene-based macrocyclic monomer

B. E. Lynde, R. L. Maust, P. Li, D. C. Lee, R. Jasti and A. J. Boydston, Mater. Chem. Front., 2020, 4, 252 DOI: 10.1039/C9QM00604D

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