Issue 17, 2019

Cyclopropane–alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

Abstract

A gold(I)-catalyzed cyclopropane–alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent cyclopropane to an alkene, upon release of naphthalene or phenanthrene, allowing the diastereoselective synthesis of a wide range of aryl and vinyl cyclopropanes.

Graphical abstract: Cyclopropane–alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

Supplementary files

Article information

Article type
Communication
Submitted
08 جمادى الثانية 1440
Accepted
16 رجب 1440
First published
20 رجب 1440

Org. Biomol. Chem., 2019,17, 4216-4219

Cyclopropane–alkene metathesis by gold(I)-catalyzed decarbenation of persistent cyclopropanes

M. Mato, I. Martín-Torres, B. Herlé and A. M. Echavarren, Org. Biomol. Chem., 2019, 17, 4216 DOI: 10.1039/C9OB00359B

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