Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

Linfeng Cui; Yang'en You; Xueling Mi; Sanzhong Luo

doi:10.1039/C8QO00496J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines†

Linfeng Cui,^a Yang'en You,^b Xueling Mi

*^a and Sanzhong Luo

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry, Beijing Normal University, Xinjiekouwai Street 19, Beijing 100875, China
E-mail: xlmi@bnu.edu.cn

^b Key Laboratory for Molecular Recognition and Function, Institute of Chemistry, the Chinese Academy of Sciences, Beijing 100190, China
E-mail: luosz@iccas.ac.cn

Abstract

A simple chiral primary amine catalyst was identified to enable effective catalysis in direct α-sulfenylation of acyclic and cyclic β-ketocarbonyls with good yields and excellent enantioselectivities.

This article is part of the themed collection: Organic Chemistry Frontiers HOT articles for 2018

Download options Please wait...

Supplementary files

Supplementary information PDF (5553K)

Article information

DOI: https://doi.org/10.1039/C8QO00496J
Article type: Research Article
Submitted: 03 رمضان 1439
Accepted: 30 رمضان 1439
First published: 01 شوال 1439

Download Citation

Org. Chem. Front., 2018,5, 2313-2316

Permissions

Request permissions

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

L. Cui, Y. You, X. Mi and S. Luo, Org. Chem. Front., 2018, 5, 2313 DOI: 10.1039/C8QO00496J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Organic Chemistry Frontiers

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

Social activity

Search articles by author

Spotlight

Advertisements