Issue 8, 2018

Metal-free intermolecular aminochlorination of unactivated alkenes

Abstract

We report a metal-free method for the synthesis of vicinal chloroamines by intermolecular aminochlorination of unactivated alkenes. This regioselective reaction is inexpensive, atom economical, and environmentally benign and tolerates various functional groups. The aminochlorinated product can be easily deprotected and subsequently transformed into valuable compounds.

Graphical abstract: Metal-free intermolecular aminochlorination of unactivated alkenes

Supplementary files

Article information

Article type
Research Article
Submitted
15 ربيع الثاني 1439
Accepted
23 جمادى الأولى 1439
First published
23 جمادى الأولى 1439

Org. Chem. Front., 2018,5, 1303-1307

Metal-free intermolecular aminochlorination of unactivated alkenes

N. Zhu, Y. Li and H. Bao, Org. Chem. Front., 2018, 5, 1303 DOI: 10.1039/C8QO00001H

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