Issue 6, 2018

Copper-catalyzed three-component phosphorylation–peroxidation of alkenes

Abstract

A copper-catalyzed phosphorylation–peroxidation of alkenes has been developed. The three-component protocol provides practical access to multisubstituted β-phosphoryl peroxides by the reactions of P(O)–H compounds, alkenes and tert-butyl hydroperoxide (TBHP). The obtained β-phosphoryl peroxides can be applied to the synthesis of β-phosphoryl epoxides by using lithium bis(trimethylsilyl)amide (LHMDS) as a base.

Graphical abstract: Copper-catalyzed three-component phosphorylation–peroxidation of alkenes

Supplementary files

Article information

Article type
Research Article
Submitted
04 ربيع الأول 1439
Accepted
02 ربيع الثاني 1439
First published
03 ربيع الثاني 1439

Org. Chem. Front., 2018,5, 972-976

Copper-catalyzed three-component phosphorylation–peroxidation of alkenes

Y. Chen, Y. Chen, S. Lu and Z. Li, Org. Chem. Front., 2018, 5, 972 DOI: 10.1039/C7QO01045A

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