Issue 5, 2018

Selective growth of two-dimensional phosphorene on catalyst surface

Abstract

Although the study of black phosphorene (BP) and its isomers has attracted enormous attention, the method of synthesizing high-quality samples in a large area is still pending. Here we explore the potential of using the chemical vapor deposition method to synthesize large-area two-dimensional (2D) phosphorene films on metal surfaces. Our ab initio calculations show that BP can be synthesized by using tin (Sn) as a catalyst, while one of its isomers, blue phosphorene (BLP), is very possible to be synthesized by using most other metals, such as Ag and Au. Besides, our study also suggests that the large binding energy between the 2D phosphorene and the active metal substrate may prohibit the exfoliation of the 2D phosphorene for real applications and, therefore, tin, silver and gold are predicted to be the most suitable catalysts for the synthesis of BP and BLP.

Graphical abstract: Selective growth of two-dimensional phosphorene on catalyst surface

Supplementary files

Article information

Article type
Communication
Submitted
26 صفر 1439
Accepted
13 ربيع الثاني 1439
First published
15 ربيع الثاني 1439

Nanoscale, 2018,10, 2255-2259

Selective growth of two-dimensional phosphorene on catalyst surface

L. Qiu, J. C. Dong and F. Ding, Nanoscale, 2018, 10, 2255 DOI: 10.1039/C7NR08507A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements