Issue 39, 2018
From the journal:

CrystEngComm

Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction†

Yiwen Zhang,ab   Kongzhao Su,a   Miao Hao,b   Lin Liu,*b   Zheng-Bo Hanb  and  Daqiang Yuan ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: ydq@firsm.ac.cn

b College of Chemistry, Liaoning University, Shenyang 110036, P. R. China
E-mail: ceshzb@lnu.edu.cn

Abstract

Two new three-dimensional metal–organic frameworks {[(CH3)2NH2]2[TM2(L)2]}n·x(solvent) (FJI-Y7, FJI = Fujian Institute, TM = Zn; FJI-Y8, TM = Cd) have been solvothermally prepared based on multifunctional pyridyl–tricarboxylate ligand 5-(5-carboxypyridin-3-yl)benzene-1,3-dicarboxylic acid (H3L). Single crystal X-ray analysis reveals that they possess non-interpenetrating binodal (4,4)-connected three-dimensional PtS-type networks with the Schläfli point symbol of {42·84}. Interestingly, both FJI-Y7 and FJI-Y8 can be used as highly efficient size-selective heterogeneous catalysts for the solvent-free cyanosilylation of acetaldehydes under mild conditions.

Graphical abstract: Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

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Article information

DOI
https://doi.org/10.1039/C8CE00694F
Article type
Paper
Submitted
13 شعبان 1439
Accepted
11 ذو القعدة 1439
First published
11 ذو القعدة 1439

CrystEngComm, 2018,20, 6070-6076

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Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

Y. Zhang, K. Su, M. Hao, L. Liu, Z. Han and D. Yuan, CrystEngComm, 2018, 20, 6070 DOI: 10.1039/C8CE00694F

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