Issue 77, 2018

Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

Abstract

Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Different behaviour is observed in the neptunyl system due to variations in the oxo interactions.

Graphical abstract: Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

Supplementary files

Article information

Article type
Communication
Submitted
15 شوال 1439
Accepted
06 ذو الحجة 1439
First published
06 ذو الحجة 1439

Chem. Commun., 2018,54, 10828-10831

Author version available

Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

M. K. Payne, M. M. Pyrch, M. Jubinsky, M. C. Basile and T. Z. Forbes, Chem. Commun., 2018, 54, 10828 DOI: 10.1039/C8CC05240A

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