Issue 10, 2018
From the journal:

Chemical Communications

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications†‡

Victoria A. Pollard,a   Samantha A. Orr,a   Ross McLellan,a   Alan R. Kennedy, ORCID logo a   Eva Hevia ORCID logo a  and  Robert E. Mulvey ORCID logo *a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

Graphical abstract: Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

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Article information

DOI
https://doi.org/10.1039/C7CC08214B
Article type
Communication
Submitted
04 صفر 1439
Accepted
11 ربيع الأول 1439
First published
29 ربيع الثاني 1439
This article is Open Access
Creative Commons BY license

Chem. Commun., 2018,54, 1233-1236

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Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

V. A. Pollard, S. A. Orr, R. McLellan, A. R. Kennedy, E. Hevia and R. E. Mulvey, Chem. Commun., 2018, 54, 1233 DOI: 10.1039/C7CC08214B

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