Issue 20, 2017
From the journal:

Green Chemistry

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst†

A. P. C. Ribeiro, ORCID logo a   L. M. D. R. S. Martins ORCID logo *ab  and  A. J. L. Pombeiro ORCID logo a  

* Corresponding authors

a Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

b Chemical Engineering Department, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, Rua Conselheiro Emídio Navarro, 1959-007 Lisboa, Portugal
E-mail: lmartins@deq.isel.ipl.pt

Abstract

The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 × 103) directly from carbon dioxide is achieved by using H2 and the iron(II) scorpionate catalyst [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.

Graphical abstract: Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7GC01993A
Article type
Paper
Submitted
09 شوال 1438
Accepted
08 ذو الحجة 1438
First published
08 ذو الحجة 1438

Green Chem., 2017,19, 4811-4815

Permissions

Request permissions

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

A. P. C. Ribeiro, L. M. D. R. S. Martins and A. J. L. Pombeiro, Green Chem., 2017, 19, 4811 DOI: 10.1039/C7GC01993A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements