Issue 20, 2017

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst

Abstract

The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 × 103) directly from carbon dioxide is achieved by using H2 and the iron(II) scorpionate catalyst [FeCl23-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.

Graphical abstract: Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst

Supplementary files

Article information

Article type
Paper
Submitted
09 شوال 1438
Accepted
08 ذو الحجة 1438
First published
08 ذو الحجة 1438

Green Chem., 2017,19, 4811-4815

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

A. P. C. Ribeiro, L. M. D. R. S. Martins and A. J. L. Pombeiro, Green Chem., 2017, 19, 4811 DOI: 10.1039/C7GC01993A

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