Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

Xu Liu; Zikuan Wang; Xianyuan Zhao; Xuefeng Fu

doi:10.1039/C5QI00269A

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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium†

Xu Liu,^a Zikuan Wang,^a Xianyuan Zhao^a and Xuefeng Fu*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn

Abstract

Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed. Mechanistic studies reveal that the rhodium aryl complex, (por)Rh-C₆F₄R, is the key intermediate.

This article is part of the themed collections: Celebrating 110th Anniversary of Chemistry at Peking University and 2015 Emerging Investigators by ICF

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DOI: https://doi.org/10.1039/C5QI00269A
Article type: Research Article
Submitted: 19 صفر 1437
Accepted: 22 جمادى الثانية 1437
First published: 27 جمادى الثانية 1437

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Inorg. Chem. Front., 2016,3, 861-865

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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

X. Liu, Z. Wang, X. Zhao and X. Fu, Inorg. Chem. Front., 2016, 3, 861 DOI: 10.1039/C5QI00269A

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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium†

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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

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