Issue 8, 2016
From the journal:

Chemical Communications

A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly†

Pradip K. Sukul,a   Purnandhu Bose,a   Toshiaki Takei,a   Omar M. Yaghi,ab   Ying He,c   Myongsoo Leec  and  Kentaro Tashiro*a  

* Corresponding authors

a International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044, Japan
E-mail: TASHIRO.Kentaro@nims.go.jp
Fax: +81-29-860-4706
Tel: +81-29-860-4879

b Department of Chemistry, University of California–Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley, University of California–Berkeley, Berkeley, California 94720, USA

c College of Chemistry, Jilin University, Changchun 130-012, China

Abstract

Water-soluble metal–organic complex array 1, bearing Ru(II), Pt(II) and Rh(III) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembly behaviours in aqueous media. NaCl-induced aggregation of 1 at neutral pH was suppressed in phosphate buffered saline containing a mixture of Cl−, HPO42− and H2PO4−, which is unconventional for a peptide amphiphile.

Graphical abstract: A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

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Article information

DOI
https://doi.org/10.1039/C5CC08973E
Article type
Communication
Submitted
16 محرم 1437
Accepted
20 محرم 1437
First published
20 محرم 1437

Chem. Commun., 2016,52, 1579-1581

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A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

P. K. Sukul, P. Bose, T. Takei, O. M. Yaghi, Y. He, M. Lee and K. Tashiro, Chem. Commun., 2016, 52, 1579 DOI: 10.1039/C5CC08973E

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