Issue 25, 2015

Synthesis and photophysical properties of platinum-acetylide copolymers with thiophene, selenophene and tellurophene

Abstract

A series of platinum-acetylide copolymers with thiophene, selenophene, and tellurophene have been synthesized and studied. Photoluminescence experiments show that polymers undergo intersystem crossing to triplet states, leading to phosphorescence. The observed phosphorescence decreases in intensity moving down the group. DFT calculations are used to further understand the optical properties.

Graphical abstract: Synthesis and photophysical properties of platinum-acetylide copolymers with thiophene, selenophene and tellurophene

Supplementary files

Article information

Article type
Communication
Submitted
28 محرم 1436
Accepted
23 صفر 1436
First published
25 صفر 1436

Chem. Commun., 2015,51, 5475-5478

Author version available

Synthesis and photophysical properties of platinum-acetylide copolymers with thiophene, selenophene and tellurophene

A. K. Mahrok, E. I. Carrera, A. J. Tilley, S. Ye and D. S. Seferos, Chem. Commun., 2015, 51, 5475 DOI: 10.1039/C4CC09312G

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