Two-dimensional (2D) nucleation and crystallization of the helical aromatic hydrocarbon heptahelicene on the single crystalline copper(100) surface has been studied with scanning tunnelling microscopy. In contrast to previously observed racemic 2D crystals on Cu(111), separation into homochiral domains is observed for Cu(100).
J. Seibel, L. Zoppi and K. Ernst, Chem. Commun., 2014, 50, 8751 DOI: 10.1039/C4CC03574G
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