Issue 21, 2014

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Abstract

The bimetallic bis(pentalene) complex (μ:η55-Pn)2Ti2 reductively splits CO2 to form a bis(oxo) bridged dimer [(η8-Pn)Ti(μ-O)]2, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (μ:η55-Pn)2[Ti(CO)]2.

Graphical abstract: Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Supplementary files

Article information

Article type
Communication
Submitted
27 ذو الحجة 1434
Accepted
16 ربيع الأول 1435
First published
16 ربيع الأول 1435

Chem. Commun., 2014,50, 2769-2771

Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

A. F. R. Kilpatrick and F. G. N. Cloke, Chem. Commun., 2014, 50, 2769 DOI: 10.1039/C3CC48379G

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