Issue 43, 2024

An extremely electron poor Au(iii) trication bearing acetonitrile ligands

Abstract

The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C–H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene.

Graphical abstract: An extremely electron poor Au(iii) trication bearing acetonitrile ligands

Supplementary files

Article information

Article type
Communication
Submitted
10 شعبان 1445
Accepted
14 شوال 1445
First published
22 شوال 1445

Chem. Commun., 2024,60, 5586-5589

An extremely electron poor Au(III) trication bearing acetonitrile ligands

L. Barwise, L. J. Moon, B. Dhakal, C. F. Hogan, K. F. White and J. L. Dutton, Chem. Commun., 2024, 60, 5586 DOI: 10.1039/D4CC00818A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements