Highly phosphorescent carbene–metal–carboranyl complexes of copper(I) and gold(I)

Samuel L. Powley; Charlotte Riley; Hwan-Hee Cho; Nguyen Le Phuoc; Mikko Linnolahti; Neil Greenham; Alexander S. Romanov

doi:10.1039/D3CC04091G

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Highly phosphorescent carbene–metal–carboranyl complexes of copper(i) and gold(i)†

Samuel L. Powley,

^a Charlotte Riley,

^a Hwan-Hee Cho,

^b Nguyen Le Phuoc,^c Mikko Linnolahti,

*^c Neil Greenham

*^b and Alexander S. Romanov

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Manchester, Oxford Rd., Manchester, UK
E-mail: alexander.romanov@manchester.ac.uk

^b Department of Physics, Cavendish Laboratory, Cambridge University, Cambridge CB3 0HE, UK
E-mail: ncg11@cam.ac.uk

^c Department of Chemistry, University of Eastern Finland, Joensuu Campus, FI-80101 Joensuu, Finland
E-mail: mikko.linnolahti@uef.fi

Abstract

New phosphorescent “carbene–metal–carboranyl” (CMC) Cu(I) and Au(I) complexes based on the diamidocarbene (DAC) ligand show up to 68% photoluminescence quantum yield and microsecond range lifetimes. CMC organic light emitting diodes (OLEDs) emit sky-blue and warm white electroluminescence.

This article is part of the themed collections: Celebrating the 200th Anniversary of the University of Manchester and 2023 Emerging Investigators

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DOI: https://doi.org/10.1039/D3CC04091G
Article type: Communication
Submitted: 07 صفر 1445
Accepted: 28 صفر 1445
First published: 28 صفر 1445

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Chem. Commun., 2023,59, 12035-12038

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Highly phosphorescent carbene–metal–carboranyl complexes of copper(I) and gold(I)

S. L. Powley, C. Riley, H. Cho, N. Le Phuoc, M. Linnolahti, N. Greenham and A. S. Romanov, Chem. Commun., 2023, 59, 12035 DOI: 10.1039/D3CC04091G

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Chemical Communications

Highly phosphorescent carbene–metal–carboranyl complexes of copper(i) and gold(i)†

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Highly phosphorescent carbene–metal–carboranyl complexes of copper(I) and gold(I)

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