Tuning intermediate adsorption in structurally ordered substituted PdCu3 intermetallic nanoparticles for enhanced ethanol oxidation reaction

Rajkumar Jana; Ayan Datta; Sudip Malik

doi:10.1039/D0CC08075F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Tuning intermediate adsorption in structurally ordered substituted PdCu₃ intermetallic nanoparticles for enhanced ethanol oxidation reaction†

Rajkumar Jana,^a Ayan Datta

*^a and Sudip Malik

*^b

Author affiliations

* Corresponding authors

^a School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata-700032, India
E-mail: spad@iacs.res.in

^b School of Applied & Interdisciplinary Sciences, Indian Association for the Cultivation of Science, Kolkata-700032, India
E-mail: psusm2@iacs.res.in

Abstract

Co and Ni-substituted structurally ordered intermetallic PdCu₃ nanoparticles (NPs) synthesized at low temperature exhibit remarkable enhancement of the ethanol electrooxidation (EOR) activity with improved durability. The first-principle calculations suggest that prompted generation of OH and CH₃CO radicals in close proximity and shifting of the d-band center towards the Fermi level boost the EOR efficiency.

This article is part of the themed collection: (Photo)electrocatalysis for renewable energy

Download options Please wait...

Supplementary files

Supplementary information PDF (15038K)

Article information

DOI: https://doi.org/10.1039/D0CC08075F
Article type: Communication
Submitted: 27 ربيع الثاني 1442
Accepted: 13 شعبان 1442
First published: 25 شعبان 1442

Download Citation

Chem. Commun., 2021,57, 4508-4511

Permissions

Request permissions

Tuning intermediate adsorption in structurally ordered substituted PdCu₃ intermetallic nanoparticles for enhanced ethanol oxidation reaction

R. Jana, A. Datta and S. Malik, Chem. Commun., 2021, 57, 4508 DOI: 10.1039/D0CC08075F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications