Issue 7, 2019

Copper-catalyzed arene amination in pure aqueous ammonia

Abstract

A simple protocol for copper-catalyzed arene amination using aqueous ammonia without any additional ligands and organic coordinating solvents has been developed. The reaction pathway via a Cu(I)/Cu(III) mechanism is proposed based on the results of control experiments as well as DFT calculations.

Graphical abstract: Copper-catalyzed arene amination in pure aqueous ammonia

Supplementary files

Article information

Article type
Communication
Submitted
22 صفر 1440
Accepted
08 ربيع الأول 1440
First published
11 ربيع الأول 1440

Org. Biomol. Chem., 2019,17, 1791-1795

Copper-catalyzed arene amination in pure aqueous ammonia

M. Takagi, A. Watanabe, S. Murata and R. Takita, Org. Biomol. Chem., 2019, 17, 1791 DOI: 10.1039/C8OB02708K

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