Issue 21, 2019

Metallopolymers cross-linked with self-assembled Ln4L4 cages

Abstract

Herein, we fabricated a hybrid PDVB-Ln4L4 metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

Graphical abstract: Metallopolymers cross-linked with self-assembled Ln4L4 cages

Supplementary files

Article information

Article type
Communication
Submitted
13 ربيع الثاني 1440
Accepted
17 جمادى الثانية 1440
First published
18 جمادى الثانية 1440

Dalton Trans., 2019,48, 7080-7084

Metallopolymers cross-linked with self-assembled Ln4L4 cages

Q. Yan, L. Zhou, H. Zhou, Z. Wang, L. Cai, X. Guo, X. Sun and Q. Sun, Dalton Trans., 2019, 48, 7080 DOI: 10.1039/C8DT05015E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements