Issue 18, 2019

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

Abstract

Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4] affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)] (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)], the first DNIC featuring both linear/bent NO ligands and Fe 3dz2-to-HCS2 π* backbonding interaction.

Graphical abstract: Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2

Supplementary files

Article information

Article type
Communication
Submitted
21 ربيع الأول 1440
Accepted
28 ربيع الثاني 1440
First published
29 ربيع الثاني 1440

Dalton Trans., 2019,48, 5897-5902

Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)]via reaction with CS2

H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, 48, 5897 DOI: 10.1039/C8DT04714F

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