Issue 37, 2016

Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex

Abstract

The 6,6′′-diaminoterpyridine palladium(II) methylperoxo complex eliminates methyl hydroperoxide and reacts with acetone to form a novel hemi-aminal palladium complex, whereas the analogous platinum(II) complex generates formaldehyde and a platinum(II) hydroxo complex.

Graphical abstract: Divergent reactivity of platinum(ii) and palladium(ii) methylperoxo complexes and the formation of an unusual hemi-aminal complex

Supplementary files

Article information

Article type
Communication
Submitted
22 رجب 1437
Accepted
20 شعبان 1437
First published
23 شعبان 1437

Dalton Trans., 2016,45, 14520-14523

Divergent reactivity of platinum(II) and palladium(II) methylperoxo complexes and the formation of an unusual hemi-aminal complex

A. R. Petersen, A. J. P. White and G. J. P. Britovsek, Dalton Trans., 2016, 45, 14520 DOI: 10.1039/C6DT01691J

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