Issue 99, 2015

Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

Abstract

A nitro-substituted dipyrrolylphenol was synthesized as a precursor of a π-electronic anion, whose phenolate (phenoxide) moiety upon deprotonation was stabilized by the hydrogen-bond-donating pyrrole NH, thus forming solid-state ion pairs with various cationic species.

Graphical abstract: Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

Supplementary files

Article information

Article type
Communication
Submitted
23 ذو القعدة 1436
Accepted
29 ذو الحجة 1436
First published
01 محرم 1437

Chem. Commun., 2015,51, 17572-17575

Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

H. Maeda, A. Fukui, R. Yamakado and N. Yasuda, Chem. Commun., 2015, 51, 17572 DOI: 10.1039/C5CC07493B

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