Themed collection ChemComm 60th Anniversary Collection
Electrochemical deconstructive functionalization of arylcycloalkanes via fragmentation of anodically generated aromatic radical cations
This highlight summarises electrochemical approaches for the deconstructive functionalization of arylcycloalkanes via the fragmentation of anodically generated aromatic radical cations.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03279A
Advancing the dynamic mechanical analysis of organic semiconductor materials
Dynamic mechanical analysis (DMA) is powerful for characterizing the mechanical properties of organic/polymeric semiconductors.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03254C
Stereochemistry of natural products from vibrational circular dichroism
VCD spectroscopy associated with DFT calculations is a powerful tool to unambiguously assign both the absolute configurations and conformations of chiral secondary metabolites directly in solution.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC02481H
Photocatalytic decarboxylation of free carboxylic acids and their functionalization
This highlight article summarizes the complete development of photodecarboxylative functionalization of free carboxylic acids via a concerted single electron transfer (SET) or energy transfer (ET) pathways.
Chem. Commun., 2024,60, 9645-9658
https://doi.org/10.1039/D4CC03189J
Time-resolved serial femtosecond crystallography for investigating structural dynamics of chemical systems
This article highlights the expansion of time-resolved serial femtosecond crystallography (TR-SFX) to chemical systems by overcoming the challenges in SFX for small molecules.
Chem. Commun., 2024,60, 9472-9482
https://doi.org/10.1039/D4CC03185G
Functional implications of unusual NOS and SONOS covalent linkages found in proteins
Novel NOS linkages stabilize protein tertiary and quaternary structures and may be as prevalent as disulfide bonds. They regulate enzyme activity and have other important roles.
Chem. Commun., 2024,60, 9463-9471
https://doi.org/10.1039/D4CC03191A
Chiral 2D and quasi-2D hybrid organic inorganic perovskites: from fundamentals to applications
The field of chiral 2D and quasi-2D perovskite is reviewed highlighting the most important results to date and indicating future directions for advancement.
Chem. Commun., 2024,60, 9310-9327
https://doi.org/10.1039/D4CC03314K
Lithium metal based battery systems with ultra-high energy density beyond 500 W h kg−1
This highlight focuses on breakthroughs, future perspectives and applications of ultra-high-energy-density lithium-based battery systems beyond 500 W h kg−1, represented by systems such as Li–S/Se batteries, Li–gas batteries, Li–CFx batteries, etc.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03177F
Recent advances in dual photoredox/nickel catalyzed alkene carbofunctionalised reactions
Alkene carbofunctionalization reactions have great potential for synthesizing complex molecules and constructing complex structures in natural products and medicinal chemistry.
Chem. Commun., 2024,60, 8946-8977
https://doi.org/10.1039/D4CC02914C
Silk-based intelligent fibers and textiles: structures, properties, and applications
This review summarizes the hierarchical structure and multifaceted properties of natural silk fibers, and provides an in-depth analysis of their extensive applications in the realms of biomedicine and advanced smart fiber technology.
Chem. Commun., 2024,60, 7801-7823
https://doi.org/10.1039/D4CC02276A
Electrifying oxidation of ethylene and propylene
This highlight discusses the advantages of various oxidation methods for improved performance of the electrochemical oxidation of ethylene and propylene, and provides an overview of current challenges and problems requiring further efforts.
Chem. Commun., 2024,60, 6703-6716
https://doi.org/10.1039/D4CC02025A
Evolution of catalyst design for controlled synthesis of chiral single-walled carbon nanotubes
Three strategies to realize the chirality-controlled growth of SWCNTs are presented.
Chem. Commun., 2024,60, 6222-6238
https://doi.org/10.1039/D4CC01227E
Recent developments in photocatalytic production of hydrogen peroxide
This highlight article summarizes the recent developments and challenges in photocatalytic production of hydrogen peroxide and looks forward to the development direction of this field.
Chem. Commun., 2024,60, 5354-5368
https://doi.org/10.1039/D4CC01577K
Recent advances in electrosynthesis of H2O2via two-electron oxygen reduction reaction
This review provides an electrosynthesis strategy of H2O2via the 2e− ORR, covering aspects of reaction mechanisms, performance assessment, catalyst engineering, and setups for scaling up H2O2 production.
Chem. Commun., 2024,60, 5232-5244
https://doi.org/10.1039/D4CC01476F
CRISPR/Cas systems combined with DNA nanostructures for biomedical applications
DNA nanostructures are easy to design and construct, have good biocompatibility, and show great potential in biosensing and drug delivery when combined with CRISPR/Cas systems.
Chem. Commun., 2024,60, 3098-3117
https://doi.org/10.1039/D4CC00290C
Spectrometric Monitoring of CO2 Electrolysis on Molecularly Modified Copper Surface
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03973D
Recent advances in metal carbene-induced semipinacol rearrangements
This review provides a complete overview of the advances in the semipinacol rearrangement-mediated 1,2-group migration onto metal carbene centers which were reported in the past decades.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03252G
Transition metal oxide clusters: advanced electrocatalysts for a sustainable energy future
This article summarizes small-sized transition metal oxide (TMO) clusters for electrocatalysis. The synergistic actions between TMO and TM–Nx sites and mechanisms by DFT studies are comprehensively highlighted.
Chem. Commun., 2024,60, 9918-9929
https://doi.org/10.1039/D4CC02722A
Recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters
This feature article comprehensively summarizes the recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03788J
Recent progress in electrochemical C–N coupling: metal catalyst strategies and applications
This paper's innovation lies in systematically summarizing and evaluating the latest metal catalyst design strategies and exploring their application in nitrogen sources.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03256J
Supramolecular chemical biology: designed receptors and dynamic chemical systems
Supramolecular approaches to face chemical biology problems targeting different types of species are illustrated with selected representative examples, using conventional receptor design or dynamic covalent chemistry.
Chem. Commun., 2024,60, 9692-9703
https://doi.org/10.1039/D4CC03163F
Europium(II/III) coordination chemistry toward applications
This article describes applications of Eu, including MRI, luminescence, catalysis, and separation science.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03080J
New insights into coordination-cage based catalysis
Recent work on catalysed reactions using coordination cage hosts, including new mechanistic insights and reactions types, is reviewed.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03678F
Recent progress in transition metal complexes featuring silylene as ligands
This review highlights recent advances in transition metal complexes of silylene, showcasing their efficacy in hydroboration, hydrosilylation, hydrogenation, hydrogen isotope exchange, and small molecule activation chemistry.
Chem. Commun., 2024,60, 9483-9512
https://doi.org/10.1039/D4CC01930J
Organoboron catalysis for direct amide/peptide bond formation
This review explores studies on the development of direct dehydrative amide/peptide bond formation from carboxylic acids using organoboron catalysis.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC02994A
DNA-modulated dimerization and oligomerization of cell membrane receptors
Versatile DNA nanodevices that modulate membrane receptor aggregation and reprogram cell signaling with high precision and programmability.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03077J
Strategies in photochemical alcohol oxidation on noble-metal free nanomaterials as heterogeneous catalysts
We highlight the challenges and recent progress in using semiconductors to harvest solar energy for carrying out alcohol oxidation.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC01204F
Unveiling the potential of triphenylphosphine salts in tuning organic room temperature phosphorescence
This article summarizes the potential of TPP salts in tuning RTP properties and their applications in multi-level information encryption, high-level anticounterfeiting tags, and X-ray scintillators.
Chem. Commun., 2024,60, 9328-9339
https://doi.org/10.1039/D4CC03156C
Productive chemistry induced by mechanochemically generated macroradicals
Mechanochemical backbone fracture by homolysis of covalent bonds generates highly reactive macroradicals, providing potential strategy to form new load-bearing bonds enabling new synthetic applications and development of stress-responsive polymers.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03206C
Cascading responses of stimuli-responsive materials
Cascading responses are a new concept for integrating stimulus-responsive materials to obtain output responses from the original input stimulus through successive conversions of the stimuli in a system.
Chem. Commun., 2024,60, 9163-9176
https://doi.org/10.1039/D4CC02827A
Spin characteristics in conjugated stable diradicals
The burgeoning interest in stable conjugated diradicals is attributed to their distinctive spin characteristics. In this review, we emphasize how to precisely control these spin characteristics to understand their role in the molecules and as functional radical materials.
Chem. Commun., 2024,60, 8997-9006
https://doi.org/10.1039/D4CC03067B
Progress on critical cell fabrication parameters and designs for advanced lithium–sulfur batteries
This feature article examines recent lithium–sulfur studies, with a focus on high-loading sulfur cathodes in lean-electrolyte and solid state-electrolyte cells, and highlights recent achievements, challenges, and strategies for future research.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03085K
Zirconium-based metal–organic frameworks and their roles in electrocatalysis
This article discusses the roles of Zr-MOFs in electrocatalysis, and the challenges and opportunities in using Zr-MOFs in electrocatalytic applications.
Chem. Commun., 2024,60, 8360-8374
https://doi.org/10.1039/D4CC02793K
Advances and challenges in molecular engineering of 2D/3D perovskite heterostructures
Advances in the understanding and applications of perovskite 2D/3D heterostructures were overviewed with a focus on ligand design principles.
Chem. Commun., 2024,60, 7824-7842
https://doi.org/10.1039/D4CC02299H
Organocatalysis as an enabling tool for enantioselective ring-opening reactions of cyclopropanes
In this article we disclose our contributions to use of cyclopropanes as unconventional reagents for the development of enantioselective transformations under different organocatalytic activation manifolds for the synthesis of chiral building blocks.
Chem. Commun., 2024,60, 7288-7298
https://doi.org/10.1039/D4CC01933D
Uncovering tetrazoles as building blocks for constructing discrete and polymeric assemblies
This review introduces tetrazoles as the building blocks. The tetrazole ring offers four nitrogens, thereby assisting in multiple binding sites. The consequence is usually polymeric networks, but meticulous stratagem can form discrete cages as well.
Chem. Commun., 2024,60, 5573-5585
https://doi.org/10.1039/D4CC01616E
Transition metal-based electrocatalysts for alkaline overall water splitting: advancements, challenges, and perspectives
This review has examined the advancements and challenges in the development of transition metal-based electrocatalysts for the alkaline water splitting reaction in the last decade.
Chem. Commun., 2024,60, 5104-5135
https://doi.org/10.1039/D3CC06015B
Carbene and photocatalyst-catalyzed 3-acylation of indoles for facile access to indole-3-yl aryl ketones
A carbene and photocatalyst-catalyzed 3-acylation of indoles was disclosed, providing access to indole-3-yl aryl ketones, which play important roles in both organic synthesis and diverse types of functional molecules.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03257H
From Li2NiO3 to High-Performance LiNiO2 Cathodes for Application in Li-Ion and All-Solid-State Batteries
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03873H
Direct Electron Transfer in Covalent Triazine Framework for Enhanced Photocatalytic Hydrogen Evolution
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03240C
Privileged zeolitic sites for humid CO2 adsorption: K+ in double eight-membered rings
A proficient site for humid CO2 adsorption in zeolites: K+-D8R structures can selectively adsorb CO2 over H2O.
Chem. Commun., 2024,60, 10140-10143
https://doi.org/10.1039/D4CC03267E
Enhancing CO2 electroreduction to ethylene via microenvironment regulation in boron–imidazolate frameworks
The surrounding microenvironment regulation enhances the activity and selectivity towards C2H4 in electrochemical CO2 reduction reaction.
Chem. Commun., 2024,60, 10204-10207
https://doi.org/10.1039/D4CC02928C
Through thickness anisotropy in all inorganic perovskite thin films via two-step synthesis: implications for voltaic devices
Stoichiometry anisotropy through the thickness of the promising photovoltaic material Cesium-lead-bromide (CsPbBr3) is observed, impacting the energy band levels and work function across the thin film.
Chem. Commun., 2024,60, 10184-10187
https://doi.org/10.1039/D4CC03152K
Enhancing the performance of organic phototransistors using a sandwich-heterostructure
A sandwich heterostructure improves organic phototransistor performance by enhancing mobility, photoresponsivity, and reducing dark current, weakening the adverse effects of traditional planar heterojunctions.
Chem. Commun., 2024,60, 10132-10135
https://doi.org/10.1039/D4CC03227F
Divergent synthesis of δ-valerolactones and furanones via palladium or copper-catalyzed α-hydroxycyclopropanol ring opening cyclizations
Divergent approaches were developed to synthesize δ-valerolactones or furanones via a palladium or copper-catalyzed α-hydroxycyclopropanol ring opening cyclizations, respectively.
Chem. Commun., 2024,60, 10112-10115
https://doi.org/10.1039/D4CC03255A
Hypervalent Zinc(I) Complexes with an N,N,N,N-Macrocycle: C-H Bond Activation Across the Zinc(I)-Zinc(I) Bond
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC04266B
Glycosyl oxazolines serve as active donors for iterative synthesis of type I oligosaccharides
Oxazoline-based iterative glycosylation to synthesize hexa- and octasaccharides in an expeditious manner.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03247K
Biosynthesis of multifunctional transformable peptides for downregulation of PD-L1
A biosynthesized material could realize morphological transformation from globular to fibrous for exposing GO203 peptides, and bind to mucin 1 for immune checkpoint blocking therapy.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03146F
Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures
Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bond-accepting or -donating properties are reported.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03613A
Polyoxometalate-incorporated NiFe-based oxyhydroxides for enhanced oxygen evolution reaction in alkaline media
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03874F
Bismuth-based electrocatalytic scheme enabling efficient and selective electrosynthesis of 4-aminophenol in acidic media
A simple and efficient electrocatalytic scheme based on Bi3+/Bi0 was developed for the first time for the efficient electrosynthesis of 4-aminophenol with high selectivity (∼100%) at an ultra-low overpotential in acidic media.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03493G
Quantifying effects of second-sphere cationic groups on redox properties of dimolybdenum quadruple bonds
Placing cationic groups in the secondary coordination sphere of dimolybdenum paddlewheel complexes has allowed for quantification of electrostatic field effects on the MoMo quadruple bond.
Chem. Commun., 2024,60, 9966-9969
https://doi.org/10.1039/D4CC02759K
Reactivity of a triamidoamine terminal uranium(VI)-nitride with 3d-transition metal metallocenes
The reactions of a uranium(VI)-nitride with 3d-transition metal metallocenes have been examined.
Chem. Commun., 2024,60, 9990-9993
https://doi.org/10.1039/D4CC03846K
Organo-cation catalyzed enantioselective α-hydroxylation of pyridinone-fused lactones: asymmetric synthesis of SN-38 and irinotecan
A catalytic asymmetric α-hydroxylation of pyridinone-fused lactones has been developed, enabling the highly enantioselective formation of oxa-quaternary stereogenic centre of this tricyclic scaffold.
Chem. Commun., 2024,60, 9954-9957
https://doi.org/10.1039/D4CC03580A
Efficient multicolour and white circularly polarized luminescence from liquid crystalline polymer networks
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC02966F
Borane-catalysed C2-selective indole reductive functionalisation
Transborylation catalysis enabled the C2-selective allylation of indoles with excellent control of chemo-, regio- and stereoselectivity.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03880K
Zr-hydroxamate metal-organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki-Miyaura catalysis
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03895A
Nitrogen fixation by alkali and alkaline earth metal hydrides assisted by plasma
The chemical behaviors of alkali and alkaline earth metal hydrides under nitrogen plasma differ significantly from one another, exhibiting an ammonia production trend that contrasts with that observed under thermal conditions.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03866E
Direct C–H amidation of 1,3-azoles: light-mediated, photosensitiser-free vs. thermal
Direct C–H amidation of the four most important 1,3-azoles in medicinal chemistry has been developed and applied to late-stage functionalisation.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC02742F
Controlling and predicting alkyl-onium electronic structure
X-ray photoelectron spectroscopy (XPS) and ab initio calculations show that fully alkylated onium cation electronic structure can be tuned using both the alkyl chains (methyl versus longer alkyl chains) and the central onium atom.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03388D
Unusual defect properties of the one-dimensional photovoltaic semiconductor selenium
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC03174A
Covalently grafting a covalent organic framework onto carbon nanotubes as a bifunctional electrocatalyst for overall water splitting
A combined nanoscale and molecular-level strategy was developed to coat Ni(II) modified bipyridine-based COF on amino-functionalized CNTs through covalent bonding as a bifunctional electrocatalyst for water splitting in alkaline solution.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03117B
Cyclically conjugated porphyrin trimers linked through benzo[4,5]imidazo[2,1-a]isoindole bridges
Cyclically conjugated porphyrin trimers that display interesting photophysical properties were synthesized.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03102D
Binaphthyl-based chiral covalent organic frameworks for chiral drug separation
A novel binaphthyl-based chiral (R)-BHTP-COF was synthesized that can serve as an efficient CSP for HPLC. The COF-packed HPLC columns provide high resolution, selectivity, and durability for the chiral separation of six racemic drugs.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC02028F
A povarov-type reaction to access tetrahydroquinolines from N-benzylhydroxylamines and alkenes in HFIP
Here, we report the synthesis of tetrahydroquinolines between newly developed N-benzylhydroxylamine reagents and alkenes using HFIP as a solvent.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04014G
Rh(III)-catalyzed aldehydic and aryl C–H alkylation with cyclopropanols via C–H/C–C bond activation
Herein, we developed an efficient C–H alkylation of 2-aminobenzaldehydes and anilines employing cyclopropanol as an alkylating agent under Rh(III)-catalysis for accessing a wide range of 1,4-diketones and β-aryl ketones in good to excellent yields.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03797A
Impacts of trace level chromium on formation of superoxide within uranyl triperoxide complexes
U(VI) triperoxide solids oxidize to superoxide forms in the presence of trace-level chromium. In solution, the U(VI) superoxide grows in after 48 h and can be detected by EPR spectroscopy without the use of a spin-trap.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC03194F
Modelling the activity trend of the hydrogen oxidation reaction under constant potential conditions
A microkinetic model is constructed for the electrocatalytic alkaline hydrogen oxidation reaction, using which the activity trend suitable for efficient catalyst screening has been identified.
Chem. Commun., 2024,60, 9829-9832
https://doi.org/10.1039/D4CC01825G
Aldoximes enable proton-relayed NMR hyperpolarisation
Oximes are powerful hyperpolarisation agents, able to act both as ligands and proton exchange catalysts with other target molecules simultaneously.
Chem. Commun., 2024,60, 9761-9764
https://doi.org/10.1039/D4CC03231D
Diversity-oriented synthesis of chromone inden-1-one-fused cyclopentadienylides and C-acylated chromone adducts via allylic phosphorus ylides
Ambident reactivity of allylic phosphorus ylides has been realized in a DOS manner while using various phosphines, delivering a series of chromone adducts in good to high yields.
Chem. Commun., 2024,60, 9817-9820
https://doi.org/10.1039/D4CC03210A
About this collection
ChemComm is publishing its 60th volume in 2024. Over the past 60 years, ChemComm has been the RSC’s most cited journal, and one of the most trusted venues for rapid publication of short communications. In our anniversary year, we recognise the important contributions ChemComm has made, and continues to make, in advancing the chemical sciences.
This collection brings together the latest research from some of our most loyal and dedicated authors, who have taken this journey with us. From those marking the beginning of their independent academic career by publishing their first article with us, to the rising stars and established leaders publishing in our yearly ‘Emerging Investigators’ and ‘Pioneering Investigators’ collections, this collection champions the contributions of our worldwide author community.
We are proud many authors choose to support our journal by regularly publishing their best work with us. This collection also features papers from our ChemComm Emerging Investigator Lectureship winners, and our Outstanding Reviewer awardees, whose invaluable feedback has shaped our published content through the years.