Quinolinylazo-6-aminouracil acts as an excellent potential precursor to form bioactive atropisomers of 8-azaxanthine and an axially elongated distorted square pyramidal Cu(II) complex.
Mononuclear nonheme Cu(II) compounds 1 and 2 were synthesized and characterized by elemental analysis, ESI-MS, EPR, and single-crystal X-ray diffractrometry.
We demonstrate that reaction temperature has a significant impact on the structures of two 1D CuII chain enantiomeric pairs and subsequently results in their completely distinct magnetic properties and large difference in NLO responses.
A comparative study of isostructural Zn(II) and Fe(II) compounds for their reactivity with nitrite, transfer of the coordinated thiolate/selenolate and generation and transfer of reactive sulfur/selenium species is presented.
Ball milling, as an efficient material processing technique, has been widely applied in the preparation and modification of sodium-ion battery anode materials in recent years.