Nitrogen-rich porous organic cages with high acetylene storage and separation performance

Lijuan Feng, Yifei Xie, Wenjing Wang, Kongzhao Su and Daqiang Yuan

J. Mater. Chem. A, 2023, 11, 25316
DOI: 10.1039/D3TA04154A

Synthesis and chiral self-sorting of spirobifluorene-containing boronate ester cages

Natalie Schäfer, Lukas Glanz, Arne Lützen and Florian Beuerle

Org. Chem. Front., 2025, 12, 1763
DOI: 10.1039/D4QO02012J

Conversion of CO2 into cyclic carbonates using an ionic porous organic cage

Qianqian Mao, Jinjin Zhang and Ming Liu

Chem. Commun., 2025, 61, 9055
DOI: 10.1039/D5CC01691F

Copper(ii)-catalyzed enantioselective decarboxylative Mannich reaction coordinated by supramolecular organic amine cages

Yuanli Zhu, Houting Wang, Rui Liu, Kaihong Liu, Xiaodong Hu, Jian Huang, Cheng Wang, Leyi Wang, Yan Liu, Guohua Liu and Chunxia Tan

Chem. Sci., 2025, 16, 4374
DOI: 10.1039/D4SC07212J

From individuals to families: design and application of self-similar chiral nanomaterials

Tingting Hong, Qi Zhou, Yilian Liu, Jiaqi Guan, Wenhu Zhou, Songwen Tan and Zhiqiang Cai

Mater. Horiz., 2024, 11, 3975
DOI: 10.1039/D4MH00496E

Recent advances in the applications of porous organic cages

Dingyue Hu, Jinjin Zhang and Ming Liu

Chem. Commun., 2022, 58, 11333
DOI: 10.1039/D2CC03692D

Porous organic cages: a unified platform for homogeneous and heterogeneous nanocatalysis

Ming Shi, Hangkong Yuan and Wei David Wang

Chem. Commun., 2026, 62, 2536
DOI: 10.1039/D5CC06810J

Heterogeneous organocatalysis: the proline case

Gustavo Senra G. de Carvalho, Douglas C. Alcântara Pinto, Robson Corrêa da Silva and Fernando de Carvalho da Silva

RSC Adv., 2025, 15, 22469
DOI: 10.1039/D5RA02331A

Chiral ionic organic single-crystal and its exfoliated two-dimensional nanosheets with enhanced enantioseparation

Huifeng Liu, Yongrui He, Jia Chen, Xiaoqing Qu, Jing He, Xuwei Chen, Jianhua Wang and Hongdeng Qiu

Chem. Sci., 2024, 15, 18818
DOI: 10.1039/D4SC04990J

Ultrafast sonochemical synthesis of imine-linked porous organic cages with high surface area for gas adsorption

Yilian Liu, Zhaoqin Han, Mao Yi, Zhiyuan Zhang, Zifeng You, Xiongli Liu, Qiao Zhao and Baiyan Li

Mater. Horiz., 2025, 12, 8147
DOI: 10.1039/D5MH00754B

Anl-proline-modified chiral porous hyper-crosslinkedl-phenylalanine dipeptide—increased reaction rate and selectivity in asymmetric catalysis

Yaodong Wang, Lijia Liu, Yudan Wang, Kexiao Sang, Chunhong Zhang and Toshifumi Satoh

Polym. Chem., 2023, 14, 1124
DOI: 10.1039/D3PY00045A

Supramolecular catalysis with emerging, functional organic macrocycles and cages

Rui Ning and Qi-Qiang Wang

Chem. Soc. Rev., 2025, 54, 11105
DOI: 10.1039/D5CS00835B

Asymmetric Aldol Reaction Catalyzed by a Chiral Proline-Substituted Porous Organic Cage

Synfacts, 2022, 18, 0777
DOI: 10.1055/s-0041-1737638

Bioinspired “Intermolecular Pocket” in Soft Molecular Crystal of Porous Organic Cage Exhibiting Reversible Guest Recognition

Laiyu Zhang, Qiong Lei, Mao Yi, Zhiyuan Zhang, Xin Lian, Jian Xu, Shuo Zhang, Lin Li, Baiyan Li and Xian‐He Bu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202421753

Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages

Keith G Andrews

Beilstein J. Org. Chem., 2025, 21, 421
DOI: 10.3762/bjoc.21.30

Organocatalysts as Enzyme Mimetics: A Review

I. V. Komarov, A. M. Hurieva, V. I. Davydov, A. Yu. Ishchenko and O. O. Grygorenko

Theor Exp Chem, 2025, 61, 1
DOI: 10.1007/s11237-025-09848-6

The promise of porous organic cages: Bridging fundamental insights and real-world impact in energy and beyond

Hamid Ali, Yasin Orooji, Basem Al Alwan, Atef E.L. Jery, Mosa Alsehli, Ahmed M. Abu-Dief, Sheng-Rong Guo, Yongbo Song and Asif Hayat

Coordination Chemistry Reviews, 2026, 548, 217212
DOI: 10.1016/j.ccr.2025.217212

Disulfide-Functionalized Porous Organic Cage for Efficient Adsorptive Removal of Hg(II) from Aqueous Solutions

Xun Chen, Xinting Zhang, Miao Yang, Guoshi Zhang, Wenjing Wang, Kongzhao Su and Daqiang Yuan

Crystal Growth & Design, 2025, 25, 3715
DOI: 10.1021/acs.cgd.5c00074

Breaking Metal‐Organic Cage Symmetry Enhances Diels–Alder Catalytic Specificity and Proficiency

Ayesha Maheshwari, Tomasz K. Piskorz, Patrick J. Boaler, Fernanda Duarte and Paul J. Lusby

Angew Chem Int Ed, 2026
DOI: 10.1002/anie.202524427

Attractive Noncovalent Interactions versus Steric Confinement in Asymmetric Supramolecular Catalysis

Cristina V. Craescu, Colton D. David, Elizabeth D. Heafner, Kenneth N. Raymond, Robert G. Bergman and F. Dean Toste

J. Am. Chem. Soc., 2026, 148, 1306
DOI: 10.1021/jacs.5c17872

Ionic organic cage as a versatile platform for immobilizing chemical and enzymatic sites for chemoenzymatic catalysis

Ke Zhao, Liang-Xiao Tan, Ning Gao and Jian-Ke Sun

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-60292-5

Porous organic cages as a novel platform for second harmonic generation

Feng Shui, Yunqin Zhang, Mao Yi, Xiongli Liu, Lin Li, Shuo Zhang, Yongshen Zheng, Yongtao Yao, Qiao Zhao, Baiyan Li and Xianhe Bu

Sci. China Chem., 2024, 67, 3669
DOI: 10.1007/s11426-024-2162-5

Cationic Foldamer‐Catalyzed Asymmetric Synthesis of Inherently Chiral Cages

Siqiang Fang, Zhaowei Bao, Zanjiao Liu, Zhengdong Wu, Jian‐Ping Tan, Xin Wei, Bo Li and Tianli Wang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202411889

A general large-scale synthesis approach for crystalline porous materials

Xiongli Liu, An Wang, Chunping Wang, Jinli Li, Zhiyuan Zhang, Abdullah M. Al-Enizi, Ayman Nafady, Feng Shui, Zifeng You, Baiyan Li, Yangbing Wen and Shengqian Ma

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-42833-y

Phenol[4]arenes: Excellent Macrocyclic Precursors for Constructing Chiral Porous Organic Cages

Fenglei Qiu, Xinting Zhang, Wenjing Wang, Kongzhao Su and Daqiang Yuan

J. Am. Chem. Soc., 2025, 147, 8500
DOI: 10.1021/jacs.4c16508

Serendipitous Assembly of Chiral Face-Rotating Molecular Boxes Directed by Non-Covalent Templation

Mingyu Cui, Xue Dong, Guoqiang Jiang, Wei Zeng, Hang Qu, Andrew C.-H. Sue and Xiaoyu Cao

Org. Lett., 2025, 27, 13745
DOI: 10.1021/acs.orglett.5c04171

Chiral Amine Covalent Organic Cage Lingated with Copper for Asymmetric Decarboxylative Mannich Reaction

Kaihong Liu, Chunxia Tan and Lingli Yuan

Inorganics, 2025, 13, 245
DOI: 10.3390/inorganics13070245

Nanocrystalline Porous Materials for Chiral Separation: Synthesis, Mechanisms, and Applications

Qixuan Mu, Wanting Tian, Jiale Zhang, Ruijun Li and Yibing Ji

Anal. Chem., 2024, 96, 7864
DOI: 10.1021/acs.analchem.3c01178

Porous Organic Cage as an Efficient Platform for Industrial Radioactive Iodine Capture

Xiongli Liu, Zhiyuan Zhang, Feng Shui, Shuo Zhang, Lin Li, Junhua Wang, Mao Yi, Zifeng You, Shiqi Yang, Rufeng Yang, Shan Wang, Yilian Liu, Qiao Zhao, Baiyan Li, Xian‐He Bu and Shengqian Ma

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202411342

Electroenzymatic cascade reaction on a biohybrid boosts the chiral epoxidation reaction

Xuefang Zhu, Yu Ding, Shuni Li, Yucheng Jiang and Yu Chen

Science Bulletin, 2024, 69, 483
DOI: 10.1016/j.scib.2023.12.025

Adsorptive Separation of Methylfuran and Dimethylfuran by a Robust Porous Organic Cage

Fenglei Qiu, Ning Xu, Wenjing Wang, Kongzhao Su and Daqiang Yuan

Chem Bio Eng., 2024, 1, 171
DOI: 10.1021/cbe.3c00099

Multifold Post‐Modification of Macrocycles and Cages by Isocyanate‐Induced Azadefluorination Cyclisation

Tobias Pausch, Tim David, Tom Fleck‐Kunde, Hendrik Pols, Johannes Gurke and Bernd M. Schmidt

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202318362

Different-shaped ligand mediating efficient structurally similar cage-to-cage transformation

Jinkang Zhu, Chunhui Li, Xiuqin Li, Qiaochun Wang and Lei Zou

Chinese Chemical Letters, 2023, 34, 107693
DOI: 10.1016/j.cclet.2022.07.036

Bioinspired “Intermolecular Pocket” in Soft Molecular Crystal of Porous Organic Cage Exhibiting Reversible Guest Recognition

Laiyu Zhang, Qiong Lei, Mao Yi, Zhiyuan Zhang, Xin Lian, Jian Xu, Shuo Zhang, Lin Li, Baiyan Li and Xian‐He Bu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202421753

Chiral Covalent Organic Cages: Structural Isomerism and Enantioselective Catalysis

Kaixuan Wang, Xianhui Tang, Bai Amutha Anjali, Jinqiao Dong, Jianwen Jiang, Yan Liu and Yong Cui

J. Am. Chem. Soc., 2024, 146, 6638
DOI: 10.1021/jacs.3c12555

Cationic Foldamer‐Catalyzed Asymmetric Synthesis of Inherently Chiral Cages

Siqiang Fang, Zhaowei Bao, Zanjiao Liu, Zhengdong Wu, Jian‐Ping Tan, Xin Wei, Bo Li and Tianli Wang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202411889

Exploring the potential of porous organic cage membranes: Recent advances and applications

Tiantian Chen, Yizhuo Li, Yuhan Wei, Yatao Zhang, Junyong Zhu and Bart Van der Bruggen

Separation and Purification Technology, 2024, 330, 125440
DOI: 10.1016/j.seppur.2023.125440

Controlled Assembly of [3+6] and [4+8] Porous Organic Cages for Rapid Removal of Iodide from Water

Guoshi Zhang, Jiajia Sheng, Wenjing Wang, Kongzhao Su and Daqiang Yuan

Chin. J. Chem., 2025, 43, 1855
DOI: 10.1002/cjoc.70053

Porous Organic Cage as an Efficient Platform for Industrial Radioactive Iodine Capture

Xiongli Liu, Zhiyuan Zhang, Feng Shui, Shuo Zhang, Lin Li, Junhua Wang, Mao Yi, Zifeng You, Shiqi Yang, Rufeng Yang, Shan Wang, Yilian Liu, Qiao Zhao, Baiyan Li, Xian‐He Bu and Shengqian Ma

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202411342

Chiral covalent organic cages: Construction and chiral functions

Si‐Dan Guo, Tianyu Jiao, Dong‐Sheng Guo and Kang Cai

Smart Molecules, 2025, 3
DOI: 10.1002/smo.20240038

Superhydrophobic porous organic cage decorated melamine sponge for efficient oil-water separation

Rui Li, Qinghua Zhang, Zhanao Lv, Ning Xu and Kongzhao Su

J Porous Mater, 2025, 32, 843
DOI: 10.1007/s10934-025-01751-8

Post-synthetic metalation of organic cage for enhanced porosity and catalytic performance

Miao Yang, Xun Chen, Yifei Xie, El-Sayed M. El-Sayed, Ning Xu, Wenjing Wang, Kongzhao Su and Daqiang Yuan

Sci. China Chem., 2023, 66, 1763
DOI: 10.1007/s11426-022-1562-8

Construction of a spherical chiral covalent organic framework for efficient asymmetric aldol catalysis

Yu Wang, Yuexing Zheng, Hong Chen, Xiang Chen, Kai Zhang, Wanwen Liang, Yuwei Zhang, Shengrun Zheng, Jun Fan and Songliang Cai

Journal of Solid State Chemistry, 2025, 348, 125350
DOI: 10.1016/j.jssc.2025.125350

Organic imine cage-mediated photocatalytic enantioselective Minisci addition of N-heteroarenes

Yongjin Zhang, Yanwen Gong, Donghua He, Rui Liu, Chunxia Tan and Guohua Liu

Journal of Catalysis, 2026, 453, 116536
DOI: 10.1016/j.jcat.2025.116536

Emergent induced circularly polarized luminescence in host–guest crystalline porous assemblies

Chong Zhang, Shuai Zhao, Miao-Miao Zhang, Bo Li, Xi-Yan Dong and Shuang-Quan Zang

Coordination Chemistry Reviews, 2024, 514, 215859
DOI: 10.1016/j.ccr.2024.215859

Reversibly photoswitchable catalysts for the aldol reaction based on azobenzene-bearing organocatalysts

Miao Pei, Li-Jun Zhang, Jin-Bao Han, Li-Juan Xing, Cai-Cai Zhang, He-Lue Sun and Haitao Yu

Journal of Molecular Structure, 2024, 1303, 137617
DOI: 10.1016/j.molstruc.2024.137617

Mehrfache Postmodifizierung von Makrozyklen und Käfigen durch Isocyanat‐induzierte Azadefluorierungszyklisierung

Tobias Pausch, Tim David, Tom Fleck‐Kunde, Hendrik Pols, Johannes Gurke and Bernd M. Schmidt

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202318362

Breaking Metal‐Organic Cage Symmetry Enhances Diels–Alder Catalytic Specificity and Proficiency

Ayesha Maheshwari, Tomasz K. Piskorz, Patrick J. Boaler, Fernanda Duarte and Paul J. Lusby

Angewandte Chemie, 2026
DOI: 10.1002/ange.202524427

Covalent Organic Cages in Catalysis

Pallab Bhandari and Partha Sarathi Mukherjee

ACS Catal., 2023, 13, 6126
DOI: 10.1021/acscatal.3c01080