Silver nanomaterials: synthesis and (electro/photo) catalytic applications

Rakesh Kumar Sharma, Sneha Yadav, Sriparna Dutta, Hanumant B. Kale, Indrajeet R. Warkad, Radek Zbořil, Rajender S. Varma and Manoj B. Gawande

Chem. Soc. Rev., 2021, 50, 11293
DOI: 10.1039/D0CS00912A

Hydrogen production from complete dehydrogenation of hydrazine borane on carbon-doped TiO2-supported NiCr catalysts

Xiaolei Zhang, Qilu Yao, Yuzhao Wang, Mengying Liu and Zhang-Hui Lu

Inorg. Chem. Front., 2024, 11, 1683
DOI: 10.1039/D3QI02633G

Recent developments of nanocatalyzed liquid-phase hydrogen generation

Changlong Wang and Didier Astruc

Chem. Soc. Rev., 2021, 50, 3437
DOI: 10.1039/D0CS00515K

Efficient and controlled H2 release from sodium formate

Fuhua Xu, Wenkai Huang, Yanlan Wang, Didier Astruc and Xiang Liu

Inorg. Chem. Front., 2022, 9, 3514
DOI: 10.1039/D2QI00774F

Bimetallic palladium nickel nanoparticles loaded on ammonia-alkalized multi-walled carbon nanotubes for efficient dehydrogenation of formic acid

Yanqiu Yang, LinLin Xu and Tong Liu

New J. Chem., 2024, 48, 6771
DOI: 10.1039/D4NJ00481G

Facile synthesis of PdAg nanocatalysts on CeO2/C composite supports as high-performance catalysts toward alkaline ethanol electro-oxidation

Ayong Xie, Qing Zhang, Huiqing He and Cheng Peng

New J. Chem., 2020, 44, 17761
DOI: 10.1039/D0NJ03757E

Ultrafine PdAg nanoparticles immobilized on nitrogen-doped carbon/cerium oxide for superior dehydrogenation of formic acid

Bing Yin, Erfa Zhao, Xianle Hua, Kai Wang, Wenqi Wang, Guicun Li and Tong Liu

New J. Chem., 2020, 44, 2011
DOI: 10.1039/C9NJ05661K

Enhanced H2 production from dehydrogenation of sodium borohydride over the ternary Co0.97Pt0.03/CeOx nanocomposite grown on CGO catalytic support

Abhay Vijay Kotkondawar and Sadhana Rayalu

RSC Adv., 2020, 10, 38184
DOI: 10.1039/C9RA10742H

Ru–Fe nanoalloys supported on N-doped carbon as efficient catalysts for hydrogen generation from ammonia borane

Daijuan Zhou, Xiaoyan Huang, Hao Wen, Ruofan Shen, Yanyan Liu, Xianji Guo and Baojun Li

Sustainable Energy Fuels, 2020, 4, 3677
DOI: 10.1039/D0SE00660B

Noble-metal-free nanocatalysts for hydrogen generation from boron- and nitrogen-based hydrides

Qilu Yao, Yiyue Ding and Zhang-Hui Lu

Inorg. Chem. Front., 2020, 7, 3837
DOI: 10.1039/D0QI00766H

Boosting the catalytic performance of Al2O3-supported Pd catalysts by introducing CeO2 promoters

Xiaoxiao Han, Lingling Zhang, Rui Zhang, Ke Wang, Xiao Wang, Bo Li, Zhiping Tao, Shuyan Song and Hongjie Zhang

Dalton Trans., 2024, 53, 3290
DOI: 10.1039/D3DT03676F

An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid

Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao and Zhang-Hui Lu

Inorg. Chem. Front., 2020, 7, 709
DOI: 10.1039/C9QI01375J

Efficient dehydrogenation of high-concentration formic acid over PdAu/AC-NH2 catalysts without additives under ambient conditions

Shuchao Jiang, Guoqing Ren and Tie Yu

New J. Chem., 2023, 47, 1081
DOI: 10.1039/D2NJ04891D

Combining surface chemical functionalization with introducing reactive oxygen species boosts ethanol electrooxidation

Jinjuan Zhao, Junhao Shu, Jiaxiao Wang, Honglei Yang, Zhengping Dong and Shuwen Li

Nanoscale, 2022, 14, 17392
DOI: 10.1039/D2NR04600H

Collaborative reconstruction of FeOOH/FeNiCo-LDH heterogeneous nanosheets for enhancing anion exchange membrane seawater electrolysis

Yixing Luo, Yang Yang, Yakun Tian, Qingsheng Wu, Wen-Feng Lin and Ming Wen

J. Mater. Chem. A, 2025, 13, 7136
DOI: 10.1039/D4TA08586H

Formic acid decomposition over supported Pd alloy catalysts: role of oxygen in hydrogen production

Nandam Hemanth Kumar, Ankit Kumar, Riya Javiya, Mukesh Kumar, Sudhanshu Sharma and Abinaya Sampath

Catal. Sci. Technol., 2025, 15, 2809
DOI: 10.1039/D4CY01379D

Co-CeOx nanoparticles anchored on a nitrogen-doped carbon nanosheet: a synergistic effect for highly efficient hydrolysis of sodium borohydride

Longhua Yao, Xiugang Li, Wenfang Peng, Qilu Yao, Jianhui Xia and Zhang-Hui Lu

Inorg. Chem. Front., 2021, 8, 1056
DOI: 10.1039/D0QI01244K

Asymmetric CoN3P1 single-atom catalytic sites for enhanced transfer hydrodehalogenation

Wendi Guo, Zehui Sun, Mengjiao Xu, Kaizhi Wang, Mugeng Chen, Conglin Zhu, Heyong He, Yongmei Liu and Yong Cao

Green Chem., 2024, 26, 4860
DOI: 10.1039/D3GC04739C

Piezoelectric Metal‐Organic Frameworks Mediated Mechanoredox Borylation and Arylation Reactions by Ball Milling

Rundong Ding, Qing Liu and Lifei Zheng

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203792

Strong Electronic Interaction between Amorphous MnO2 Nanosheets and Ultrafine Pd Nanoparticles toward Enhanced Oxygen Reduction and Ethylene Glycol Oxidation Reactions

Ying Wang, Jiali Liu, Hongjie Yuan, Fan Liu, Tianjun Hu and Benqun Yang

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202211909

Fast hydrogen evolution by formic acid decomposition over AuPd/TiO2-NC with enhanced stability

Xue Sun, Fang Li, Zhimiao Wang, Hualiang An, Wei Xue, Xinqiang Zhao and Yanji Wang

International Journal of Hydrogen Energy, 2023, 48, 13000
DOI: 10.1016/j.ijhydene.2022.12.254

Methanolysis of ammonia borane catalyzed by NiO–CuO heterostructured nanosheets: cooperation of visible light and oxygen vacancy

You‐Xiang Shao, Yuan‐Zhong Li, Xue‐Qi Lian, Xiao‐Ting Che, Qian‐Yi Li, Yu‐Fa Feng, Hui‐Ze Wang, Jin‐Yun Liao, Quan‐Bing Liu and Hao Li

Rare Metals, 2025, 44, 389
DOI: 10.1007/s12598-024-02949-6

Mechanochemically assisted fabrication of ultrafine Pd nanoparticles on natural waste-derived nitrogen-doped porous carbon for the efficient formic acid decomposition

Chenqian Qiu, Qian Chen, Chunlin Chang, Weidong Jiang and Guangyin Fan

International Journal of Hydrogen Energy, 2021, 46, 656
DOI: 10.1016/j.ijhydene.2020.10.014

Elucidating the Role of Oxide–Oxide/Carbon Interfaces of CuOx–CeO2/C in Boosting Electrocatalytic Performance

Chiranjita Goswami, Yusuke Yamada, Ekaterina V. Matus, Ilyas Z. Ismagilov, Mikhail Kerzhentsev and Pankaj Bharali

Langmuir, 2020, 36, 15141
DOI: 10.1021/acs.langmuir.0c02754

Recent Progress on Catalysts for Hydrogen Evolution from Decomposition of Hydrous Hydrazine

Anqi Zhang, Qilu Yao and Zhang-Hui Lu

Acta Chimica Sinica, 2021, 79, 885
DOI: 10.6023/A21030126

Ultrafine palladium nanoparticles supported on mesoporous silica: An outstanding catalytic activity for hydrogen production from dodecahydro-N-ethylcarbazole

Yindong Wang, Zhaolu Feng and Xuefeng Bai

Fuel, 2022, 315, 123236
DOI: 10.1016/j.fuel.2022.123236

Construction of ruthenium catalysts based on Ce-Al composite supports for hydrogen production from ammonia decomposition: Mechanism exploration via DFT calculations

Ranlei Shao, Lu Zhang, Luyuan Wang, Jianmei Wang, Xingyu Zhang, Shiwang Han, Xingxing Cheng and Zhiqiang Wang

Fuel, 2025, 384, 134043
DOI: 10.1016/j.fuel.2024.134043

An evaluation of activation energy, surface area, and catalytic activity relationship of the developed nonmetal alloy decorated Schiff's base based conjugated conductive polymer composite electrodes for fuel cell applications

Vaithilingam Selvaraj, Krishnan Arunkumar and Muthukaruppan Alagar

Intl J of Energy Research, 2022, 46, 4630
DOI: 10.1002/er.7456

Chromic hydroxide-decorated palladium nanoparticles confined by amine-functionalized mesoporous silica for rapid dehydrogenation of formic acid

Yiyue Ding, Wenfang Peng, Lei Zhang, Jianhui Xia, Gang Feng and Zhang-Hui Lu

Journal of Colloid and Interface Science, 2023, 630, 879
DOI: 10.1016/j.jcis.2022.10.048

Alkaline ultrasonic irradiation-mediated boosted H2 production over O/N-rich porous carbon anchored Ru nanoclusters

Siming Wang, An Guo, Yumei Peng, Yi Wang, Yan Long and Guangyin Fan

Journal of Colloid and Interface Science, 2022, 612, 57
DOI: 10.1016/j.jcis.2021.12.127

Efficient production of hydrogen from a valuable CO2-derived molecule: Formic acid dehydrogenation boosted by biomass waste-derived catalysts

Jessica Chaparro-Garnica, Miriam Navlani-García, David Salinas-Torres, Ángel Berenguer-Murcia, Emilia Morallón and Diego Cazorla-Amorós

Fuel, 2022, 320, 123900
DOI: 10.1016/j.fuel.2022.123900

Oxygen vacancy of CeO2 enhanced Pd catalysts supported on carbon nitride sphere for hydrogen generation from formic acid

Qingfang Deng, Qi Wang, Miao Yu, Bing Ju, Zijia Liu, Siwen Lv, Shangkun Ma, Jianjiao Xin, Fengjuan Cui and Zhenlong Zhao

International Journal of Hydrogen Energy, 2025, 145, 882
DOI: 10.1016/j.ijhydene.2025.06.051

Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution

Feng Guo, Hongtao Zou, Qilu Yao, Bin Huang and Zhang-Hui Lu

Renewable Energy, 2020, 155, 1293
DOI: 10.1016/j.renene.2020.04.047

Exploring the Effects Behind the Outstanding Catalytic Performance of PdAg Catalysts Supported on Almond Shell‐Derived Activated Carbon Towards the Dehydrogenation of Formic Acid

Paula Riquelme‐García, Jessica Chaparro‐Garnica, Miriam Navlani‐García and Diego Cazorla‐Amorós

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400160

Tailoring the interfacial electron redistribution of ball-in-ball structured CuO-Co3O4 nanocomposites for synergistic enhancement in hydrolytic dehydrogenation of ammonia borane

Yufa Feng, Jingjing Tian, Xuexian Wu, Meifang Ye, Youxiang Shao, Qingyu Liao, Wengang Guo, Jinyun Liao, Hongyan Chen and Hao Li

Journal of Alloys and Compounds, 2024, 1002, 175407
DOI: 10.1016/j.jallcom.2024.175407

Regulation of Electronic Structures of the Urchin‐Like NiCoP/CoP Nanocatalysts for Fast Hydrogen Evolution

Xiaodong Chen, Xiaoling Luo, Xuefeng Zhang, Huize Wang, Yongcheng Li, Lifang Ye, Jiahua Zheng and Hao Li

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304266

Strong metal-support interaction of Pd/CeO2 enhances hydrogen production from formic acid decomposition

Jialu Song, Shuxing Bai and Qi Sun

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 658, 130645
DOI: 10.1016/j.colsurfa.2022.130645

Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid

Yiyue Ding, Qiuxiang Zhang, Lei Zhang, Qilu Yao, Gang Feng and Zhang-Hui Lu

Chinese Chemical Letters, 2024, 35, 109593
DOI: 10.1016/j.cclet.2024.109593

Palladium‐Silver Alloys Deposited on Different Carriers for Dehydrogenation of Formic Acid

Siyi Zeng, Haonan Li, Qian Zhang, Xiangyi Gong, Shaohua Jin, Chongchong She, Junfeng Wang, Lijie Li, Kun Chen and Guanghui Wang

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202402023

Ultrafine Ni−MoOx Nanoparticles Anchored on Nitrogen‐Doped Carbon Nanosheets: A Highly Efficient Noble‐Metal‐Free Catalyst for Ammonia Borane Hydrolysis

Weihong Liu, Longhua Yao, Xiongfei Sun, Wei Wang, Gang Feng, Qilu Yao, Lei Zhang and Zhang‐Hui Lu

ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202400415

Development of Co–Nb–CeO2 Catalyst for Hydrogen Production from Waste-Derived Synthesis Gas Using Techno-Economic and Environmental Assessment

Kyung-Won Jeon, Hui-Ju Byeon, Hak-Min Kim, Bomin Choe, Chang-Hoon Jeong, Tae-Yeol Choi, Wangyun Won and Dae-Woon Jeong

ACS Sustainable Chem. Eng., 2022, 10, 6289
DOI: 10.1021/acssuschemeng.2c00614

Architecture of urchin-like TiO2 integrated ultrasmall Rh nanoparticles with oxygen vacancy-reinforced electronic metal-support interaction for boosting hydrogen production from ammonia borane hydrolysis

Meng Yuan, Siting Zhong, Guo Li, Guangyin Fan and Xiaojun Yu

Fuel, 2024, 358, 130200
DOI: 10.1016/j.fuel.2023.130200

Interface engineering of three-phase NiO-CuO/Fe3O4 heterostructured catalyst for quick hydrogen release from ammonia borane methanolysis

Liling Li, Haidong Jiang, Yufa Feng, Jinyun Liao and Hao Li

Journal of Alloys and Compounds, 2025, 1010, 177642
DOI: 10.1016/j.jallcom.2024.177642

Nitrogen-phosphorus co-functionalized reduced graphene oxide supported NiCoPd-CeOx nanoparticles as a highly efficient and stable catalyst for formic acid dehydrogenation

Jia-Yun Wang, He-Nan Shang, Di Liu, Si-Jia Li, Ya-Xuan Bai, Yu-Bo Liu and Jin-Sheng Liang

International Journal of Hydrogen Energy, 2022, 47, 10891
DOI: 10.1016/j.ijhydene.2022.01.149

Pd–WO heterostructures immobilized by MOFs-derived carbon cage for formic acid dehydrogenation

Anqi Zhang, Jianhui Xia, Qilu Yao and Zhang-Hui Lu

Applied Catalysis B: Environmental, 2022, 309, 121278
DOI: 10.1016/j.apcatb.2022.121278

Elucidating the alloying effect of PdAg/CNT catalysts on formic acid dehydrogenation with kinetic isotope effect

Yongwoo Kim and Do Heui Kim

Molecular Catalysis, 2023, 547, 113343
DOI: 10.1016/j.mcat.2023.113343

Critical upstream technologies for hydrogen energy industry: Research progress on ammonia decomposition catalysts

Xinshu Li, Qing Wang, Shuang Wu, Zhongyuan Hu and Jingru Bai

Sustainable Chemistry and Pharmacy, 2024, 38, 101492
DOI: 10.1016/j.scp.2024.101492

Bimetallic Palladium Chromium Nanoparticles Loaded on Amino-Modified Mullite-Type SmMn2O5 to Effectively Improve the Efficiency of Formic Acid Dehydrogenation

Yanqiu Yang, LinLin Xu, Xiaoping Hu and Tong Liu

Energy Fuels, 2024, 38, 10225
DOI: 10.1021/acs.energyfuels.4c00541

Development of Mo-Modified Pseudoboehmite Supported Ni Catalysts for Efficient Hydrogen Production from Formic Acid

Liang Zheng, Zhiyu Li, Peng Fu, Fazhe Sun, Mingyang Liu, Tianyang Guo and Qingwen Fan

ACS Omega, 2022, 7, 27172
DOI: 10.1021/acsomega.2c01742

Multi-site Co2P catalyst derived from soybean biomass for dehydrogenation of formic acid

Bixi WANG, Zeyu LIU, Yabei WU, Yanyan YANG, Song YANG, Xun WANG, Zi YE, Hongliang DONG, Feng ZHU, Huanhuan YU, Yingying LÜ and Zhongliang YU

Journal of Fuel Chemistry and Technology, 2024, 52, 883
DOI: 10.1016/S1872-5813(23)60410-4

Activating the Pd-Based catalysts via tailoring reaction interface towards formic acid dehydrogenation

Nanxing Gao, Rongpeng Ma, Xian Wang, Zhao Jin, Shuai Hou, Weilin Xu, Qinglei Meng, Junjie Ge, Changpeng Liu and Wei Xing

International Journal of Hydrogen Energy, 2020, 45, 17575
DOI: 10.1016/j.ijhydene.2020.04.289

Anchoring PdAu nanoclusters inside aminated metal-organic framework for fast dehydrogenation of formic acid

Yiyue Ding, Peng Liu, Xiaoyun Huang, Caili Hu, Zubiao Wen and Zhang-Hui Lu

Fuel, 2024, 359, 130459
DOI: 10.1016/j.fuel.2023.130459

Synergistic catalysis of Pd–Ni(OH)2 hybrid anchored on porous carbon for hydrogen evolution from the dehydrogenation of formic acid

Yaqiong Dong, Qian Chen, Chenqian Qiu, Xiaoyan Ma, Yi Wang, Ting Sun and Guangyin Fan

International Journal of Hydrogen Energy, 2020, 45, 12849
DOI: 10.1016/j.ijhydene.2020.03.016

Cr dopants and S vacancies in ZnS to trigger efficient photocatalytic H2 evolution and CO2 reduction

Linping Bao, Yushuai Jia, Xiaohui Ren, Xin Liu, Chunhui Dai, Sajjad Ali, Mohamed Bououdina, Zhanghui Lu and Chao Zeng

Journal of Materials Science & Technology, 2024, 199, 75
DOI: 10.1016/j.jmst.2024.01.094

Robust Hydrogen Production from Additive-Free Formic Acid via Mesoporous Silica-Confined Pd-ZrO2 Nanoparticles at Room Temperature

Yi-Xing Luo, Wendan Nie, Yiyue Ding, Qilu Yao, Gang Feng and Zhang-Hui Lu

ACS Appl. Energy Mater., 2021, 4, 4945
DOI: 10.1021/acsaem.1c00520

“On–Off” Control for On-Demand Hydrogen Production from the Dehydrogenation of Formic Acid

Fuhua Xu and Xiang Liu

ACS Catal., 2021, 11, 13913
DOI: 10.1021/acscatal.1c03923

The Fast Formation of a Highly Active Homogeneous Catalytic System upon the Soft Leaching of Pd Species from a Heterogeneous Pd/C Precursor

Alexey S. Galushko, Valentina V. Ilyushenkova, Julia V. Burykina, Ruslan R. Shaydullin, Evgeniy O. Pentsak and Valentine P. Ananikov

Inorganics, 2023, 11, 260
DOI: 10.3390/inorganics11060260

Anchoring Pd nanoparticles on MOF-303-derived N-doped carbon for enhanced H2 production from formic acid dehydrogenation

Hao Chai, Chunhui Zhou, Song Li, Rongmei Zhang, Junjie Yuan, Jinsong Hu, Zhentao Liu, Aijun Duan, Chunming Xu and Xilong Wang

Fuel, 2024, 371, 131908
DOI: 10.1016/j.fuel.2024.131908

Carbon-doped TiO2 supported with NiCr particles: a significant boost to MgH2 for hydrogen storage

Zhenghao Deng, Ren Zhou, Daifen Chen, Fuying Wu, Hong Li and Liuting Zhang

Journal of Energy Storage, 2025, 136, 118530
DOI: 10.1016/j.est.2025.118530

Understanding the Conversion Routes of Butanol in Steam Reforming Over Nix/MgO Catalyst

Yajing Wang, Tingting Ji, Bo Qu, Jingze Wu, Qingshan Yang and Jianmin Chen

Chemistry An Asian Journal, 2026, 21
DOI: 10.1002/asia.70712

Robust hydrogen production from HCOOH over amino-modified KIT-6-confined PdIr alloy nanoparticles

Wenfang Peng, Shiwen Liu, Xiugang Li, Gang Feng, Jianhui Xia and Zhang-Hui Lu

Chinese Chemical Letters, 2022, 33, 1403
DOI: 10.1016/j.cclet.2021.08.033

Defect engineered mesoporous graphitic carbon nitride modified with AgPd nanoparticles for enhanced photocatalytic hydrogen evolution from formic acid

Chao Wan, Liu Zhou, Shuman Xu, Biyu Jin, Xin Ge, Xing Qian, Lixin Xu, Fengqiu Chen, Xiaoli Zhan, Yongrong Yang and Dang-guo Cheng

Chemical Engineering Journal, 2022, 429, 132388
DOI: 10.1016/j.cej.2021.132388

Activating Pd nanoparticles via the Mott-Schottky effect in Ni doped CeO2 nanotubes for enhanced catalytic Suzuki reaction

Bo Liu, Tong Xu, Chunping Li and Jie Bai

Molecular Catalysis, 2022, 528, 112452
DOI: 10.1016/j.mcat.2022.112452

Boosting visible-light-driven hydrogen evolution from formic acid over AgPd/2D g-C3N4 nanosheets Mott-Schottky photocatalyst

Chao Wan, Liu Zhou, Lin Sun, Lixin Xu, Dang-guo Cheng, Fengqiu Chen, Xiaoli Zhan and Yongrong Yang

Chemical Engineering Journal, 2020, 396, 125229
DOI: 10.1016/j.cej.2020.125229

Aluminum fluoride induced PdAu nanoparticles on layered g-C3N4 nanosheets for efficient dehydrogenation of formic acid at room temperature

Hong Zhou, Guang Yang, Manyu Chen, Youlin Liu, Zhongyuan Zhang, Yongji Hu, Sasa Gu, Jianhai Wang and Yuesong Shen

International Journal of Hydrogen Energy, 2022, 47, 30440
DOI: 10.1016/j.ijhydene.2022.06.293

Pd Nanoparticles Supported on N- and P-Co-doped Carbon as Catalysts for Reversible Formate-Based Chemical Hydrogen Storage

Xianzhao Shao, Xinyi Miao, Tianlei Zhang, Wei Wang, Junhong Wang and Xiaohui Ji

ACS Appl. Nano Mater., 2020, 3, 9209
DOI: 10.1021/acsanm.0c01830

Surface defect-engineered silver silicate/ceria p-n heterojunctions with a flower-like structure for boosting visible light photocatalysis with mechanistic insight

Changfeng Chen, Mengru Li, Yushuai Jia, Ruifeng Chong, Liping Xu and Xin Liu

Journal of Colloid and Interface Science, 2020, 564, 442
DOI: 10.1016/j.jcis.2019.12.128

Pt/CeO2 catalyst synthesized by combustion method for dehydrogenation of perhydro-dibenzyltoluene as liquid organic hydrogen carrier: Effect of pore size and metal dispersion

Sanghun Lee, Jaemyung Lee, Taehong Kim, Gwangwoo Han, Jaeseok Lee, Kangyong Lee and Joongmyeon Bae

International Journal of Hydrogen Energy, 2021, 46, 5520
DOI: 10.1016/j.ijhydene.2020.11.038

Anchoring PdAg nanoparticles on ZIF-67-derived Co@NC composite as a catalyst for efficient hydrogen evolution from formic acid

Zhongcheng Zhao, Yuchao Yao, Dongyan Xu and Xiaojin Li

Molecular Catalysis, 2023, 545, 113204
DOI: 10.1016/j.mcat.2023.113204

Morphology engineering of hollow core@shell structured Co3O4@CuO-NiO for fast hydrogen release from ammonia borane methanolysis

Jinyun Liao, Yuanzhong Li, Jingjing Tian, Yufa Feng, Quanbing Liu and Hao Li

Journal of Colloid and Interface Science, 2025, 680, 78
DOI: 10.1016/j.jcis.2024.10.177

An Effective Strategy to Boost Formic Acid Dehydrogenation over Pd/AC-NH2 Catalyst through Pd Size Control

Shuchao Jiang, Hongqi Shi, Yuzhe Xu, Jiaojiao Liu, Tie Yu and Guoqing Ren

ACS Appl. Mater. Interfaces, 2024
DOI: 10.1021/acsami.4c10391

PdCuZn Nanoparticle-Decorated Ultrathin Amorphous CeO2 Nanowires for Ethylene Glycol Electrooxidation

Jinyu Zheng, Zihao Wang, Xin Xiang and Dongdong Xu

ACS Appl. Nano Mater., 2024, 7, 17996
DOI: 10.1021/acsanm.4c03377

Latest avenues on solar light-driven photocatalytic hydrogen generation using surface modified nanomaterials towards sustainable environment and circular bioeconomy

S. Sathish, J. Aravind kumar, D. Prabu, A. Annam Renita, Karthikeyan Murugesan, M. Rajasimman, Sang-Woo Joo, Yasser Vasseghian and Chongqing Wang

Fuel, 2023, 340, 127398
DOI: 10.1016/j.fuel.2023.127398

Bis-imidazolium Pd(0) based supported catalyst for the selective dehydrogenation of formic acid

Parvin Holakooei, Federica Valentini, Filippo Campana and Luigi Vaccaro

Molecular Catalysis, 2024, 563, 114235
DOI: 10.1016/j.mcat.2024.114235

Improved Charge Separation and CO2 Affinity of In2O3 by K Doping with Accompanying Oxygen Vacancies for Boosted CO2 Photoreduction

Jiayang Huang, Tao Wu, Chunhui Dai, Yunchang Xie and Chao Zeng

Langmuir, 2024
DOI: 10.1021/acs.langmuir.3c03854

CuNi/La2O2CO3/rGO Nanocomposites: An Efficient Noble-Metal-Free Catalyst for Hydrogen Evolution from N2H4·H2O

Xiaoling Hong, Qilu Yao, Jianjun Long, Xiugang Li, Xiangshu Chen and Zhang-Hui Lu

Ind. Eng. Chem. Res., 2021, 60, 16224
DOI: 10.1021/acs.iecr.1c03303

Ultrasmall PdAu alloy nanoparticles anchored on amine-functionalized hierarchically porous carbon as additive-free catalysts for highly efficient dehydrogenation of formic acid

Zhenzhen Wang, Shipan Liang, Xiaoyan Meng, Shanjun Mao, Xu Lian and Yong Wang

Applied Catalysis B: Environmental, 2021, 291, 120140
DOI: 10.1016/j.apcatb.2021.120140

Universal low-temperature oxidative thermal redispersion strategy for green and sustainable fabrication of oxygen-rich carbons anchored metal nanoparticles for hydrogen evolution reactions

Yumei Peng, Yiwen Zhang, An Guo, Mingyue Mao, Yi Wang, Yan Long and Guangyin Fan

Chemical Engineering Journal, 2022, 433, 133648
DOI: 10.1016/j.cej.2021.133648

Ultrafine Pd nanoparticles on amine-functionalized carbon nanotubes for hydrogen production from formic acid

Yongwoo Kim, Hwangho Lee, Seungdo Yang, Jaeha Lee, Hyungjoo Kim, Sungha Hwang, Se Won Jeon and Do Heui Kim

Journal of Catalysis, 2021, 404, 324
DOI: 10.1016/j.jcat.2021.10.007

Electronic engineering induced ultrafine non-noble nanoparticles for high-performance hydrogen evolution from ammonia borane hydrolysis

Siyuan Tang, Linlin Xu, Xiang Ding, Quanjiang Lv, Haotian Qin, Aosong Li, Xinchun Yang, Jian Han and Fuzhan Song

Fuel, 2025, 381, 133424
DOI: 10.1016/j.fuel.2024.133424

Hydrogen generation over Ni@Pd NCs through an active H-exchange from formic acid-water system

Qu Tang, Xiaobo Zhou, JinXia Liu, Mingmin Wu, Haiwei Ji, Qi Wang, Guo Li, Hui Cong and Yuling Qin

International Journal of Hydrogen Energy, 2022, 47, 21745
DOI: 10.1016/j.ijhydene.2022.05.020

Dual optimization strategy assisted m-phenylenediamine-based hypercrosslinked polymer loaded ultrafine bimetallic nanoparticles for efficient formic acid dehydrogenation

Hongtan Cai, Qiaoyi Zhang, Xin Liu, Yulin Li, Meiyan Wang, Ge Gao, Zeshuo Meng, Haoteng Sun and Xiufeng Hao

Chemical Engineering Journal, 2024, 499, 156261
DOI: 10.1016/j.cej.2024.156261

Performance and mechanistic insight of formic acid decomposition via heterogeneous catalysts of noble metals: DFT and experimental studies

Dongxu Song, Haojie Li, Hexuan Wang, Xuetao Wang and Yilin Zhu

International Journal of Green Energy, 2026, 1
DOI: 10.1080/15435075.2026.2655004

Metal-support interactions in heterogeneous catalytic hydrogen production of formic acid

Shuxing Bai, Ankang Jia, Jialu Song, Shuang Cao, Ning Wang and Xia Liu

Chemical Engineering Journal, 2023, 474, 145612
DOI: 10.1016/j.cej.2023.145612

Immobilization of palladium silver nanoparticles on NH2-functional metal-organic framework for fast dehydrogenation of formic acid

Jian Han, Zongji Zhang, Zongrui Hao, Guicun Li and Tong Liu

Journal of Colloid and Interface Science, 2021, 587, 736
DOI: 10.1016/j.jcis.2020.11.033

Hydrothermal synthesis of CuO and CeO2/CuO nanostructures: spectroscopic and temperature dependent electrical properties

Romang Bosigo, Lucia M. Lepodise, Alex Kuvarega and Cosmas Muiva

J Mater Sci: Mater Electron, 2021, 32, 7136
DOI: 10.1007/s10854-021-05423-6

Anchoring IrPdAu Nanoparticles on NH2-SBA-15 for Fast Hydrogen Production from Formic Acid at Room Temperature

Yixing Luo, Qifeng Yang, Wendan Nie, Qilu Yao, Zhujun Zhang and Zhang-Hui Lu

ACS Appl. Mater. Interfaces, 2020, 12, 8082
DOI: 10.1021/acsami.9b16981

Boosting the electrocatalytic activity of Pd/C by Cu alloying: Insight on Pd/Cu composition and reaction pathway

Chiranjita Goswami, Himadri Saikia, Biraj Jyoti Borah, Manash Jyoti Kalita, Kohei Tada, Shingo Tanaka and Pankaj Bharali

Journal of Colloid and Interface Science, 2021, 587, 446
DOI: 10.1016/j.jcis.2020.11.104

A Review on Cu‐Based Catalysts for Dehydrogenation of Chemical Hydrides

Yixing Luo, Qilu Yao, Jianhui Xia, Yongjin Zou, Lixin Chen, Ashish K. Singh and Zhang‐Hui Lu

Rare Metals, 2026, 45
DOI: 10.1002/rar2.70232

Hydrogen production from chemical hydrogen storage materials over copper‐based catalysts

Jian‐Jun Long, Hao‐Chong Wu, Yuan‐Ting Liu, Yi‐Yue Ding, Qi‐Lu Yao, Onder Metin and Zhang‐Hui Lu

cMat, 2024, 1
DOI: 10.1002/cmt2.10

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

Qiming Sun, Ning Wang, Qiang Xu and Jihong Yu

Advanced Materials, 2020, 32
DOI: 10.1002/adma.202001818

Fluorine lattice-doped ZnS with accompanying sulfur vacancies for high activity and selectivity of CO2 conversion to CO

Linping Bao, Chunhui Dai, Chengyin Liu, Yushuai Jia, Xin Liu, Xiaohui Ren, Sajjad Ali, Mohamed Bououdina and Chao Zeng

Ceramics International, 2024, 50, 19769
DOI: 10.1016/j.ceramint.2024.03.100

Ag nanocomposites in biomass utilization: From tailored catalytic materials to chemical conversions

Yao-Bing Huang, Fei-Yan Jiang, Jin-Yue Luo and Yi-Han Zhou

Chem Catalysis, 2023, 3, 100676
DOI: 10.1016/j.checat.2023.100676

Highly active and stable CeO2 supported nickel-complex catalyst in hydrogen generation

Dilek Kilinc and Omer Sahin

International Journal of Hydrogen Energy, 2021, 46, 499
DOI: 10.1016/j.ijhydene.2020.09.201

Development of highly efficient and reusable Ruthenium complex catalyst for hydrogen evolution

Dilek Kilinc and Omer Sahin

International Journal of Hydrogen Energy, 2022, 47, 3876
DOI: 10.1016/j.ijhydene.2021.11.051

Ultrafine PdCo nanoparticles on amine-functionalized CeZrSBA-15 with short channels for efficient H2 production from formic acid dehydrogenation

Chunhui Zhou, Song Li, Hao Chai, Jinsong Hu, Zhentao Liu, Ke Yu, Chunya Wang, Aijun Duan, Chunming Xu and Xilong Wang

Fuel, 2024, 365, 131170
DOI: 10.1016/j.fuel.2024.131170

Surface property and spatial confinement engineering for achieving Ru nanoclusters on O/N-doped hollow carbon towards enhanced hydrogen production

An Guo, Yumei Peng, Mingyue Mao, Yi Wang, Yan Long, Qianggen Li and Guangyin Fan

Fuel, 2021, 306, 121722
DOI: 10.1016/j.fuel.2021.121722

Immobilizing Pd nanoparticles on amine-functionalized yolk-shell mesoporous silica nanospheres for efficient H2 production from formic acid dehydrogenation

Chunhui Zhou, Song Li, Hao Chai, Quan Liu, Jinsong Hu, Zhentao Liu, Ke Yu, Fei Fan, Wenwu Zhou, Aijun Duan, Chunming Xu and Xilong Wang

Applied Catalysis B: Environment and Energy, 2024, 346, 123750
DOI: 10.1016/j.apcatb.2024.123750

Built‐in Electric Field in Yolk Shell CuO‐Co3O4@Co3O4 with Modulated Interfacial Charge to Facilitate Hydrogen Production from Ammonia Borane Methanolysis Under Visible Light

Yuanzhong Li, Jinyun Liao, Yufa Feng, Junhao Li, Quanbing Liu, Weiyou Zhou, Mingyang He and Hao Li

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202405361

Recent progresses on carbon supported palladium-based heterogeneous catalysts for efficient dehydrogenation of formic acid

Shan Zhong, Longyun Dai, Xiaojun Zheng and Shuang Wang

Inorganic Chemistry Communications, 2025, 182, 115646
DOI: 10.1016/j.inoche.2025.115646

Coupling Interaction between Precisely Located Pt Single‐Atoms/Clusters and NiCo‐Layered Double Oxide to Boost Hydrogen Evolution Reaction

Yakun Tian, Yixing Luo, Tong Wu, Xinglei Quan, Weiying Li, Guangfeng Wei, Maryam Bayati, Qingsheng Wu, Yongqing Fu and Ming Wen

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202405919

Pd Nanoalloys for H2 Generation from Formic Acid

Esmail Doustkhah, Morteza Hasani, Yusuke Ide and M. Hussein N. Assadi

ACS Appl. Nano Mater., 2020, 3, 22
DOI: 10.1021/acsanm.9b02004

Ultrafast joule-heating-assisted O, N dual-doping of unfunctionalized carbon enhances Ru nanoparticle-catalyzed hydrogen production

Yihan Zhang, Song Wu, Ting Sun, Qianggen Li and Guangyin Fan

Journal of Colloid and Interface Science, 2025, 681, 71
DOI: 10.1016/j.jcis.2024.11.141

Synthesis of Bimetallic Pd-Based/Activated Carbon Catalyst by Biomass-Reduction Method for Highly Efficient Hydrogen Storage System Based on CO2/Formate

Liangyu Zou, Qi Liu, Qiaoyu Zhang, Zhiqing Zhu, Yangqiang Huang and Zhiwu Liang

Ind. Eng. Chem. Res., 2022, 61, 2455
DOI: 10.1021/acs.iecr.1c04423

Amine-Functionalized Carbon Bowl-Supported Pd-La(OH)3 for Formic Acid Dehydrogenation

Xiongfei Sun, Guiyuan Zhang, Qilu Yao, Hongbo Li, Gang Feng and Zhang-Hui Lu

Inorg. Chem., 2022, 61, 18102
DOI: 10.1021/acs.inorgchem.2c02672

Palladium nanocrystals coupled with quasi-cuboid ceria embedded nitrogen-doped graphene aerogel boosts ethanol electrocatalytic oxidation

Sizhuo Ma, Jinjuan Zhao, Hui Zhang, Mengjie Li, Jie Wu, Zheng Liu, Honglei Yang, Limin Zhao and Shuwen Li

International Journal of Hydrogen Energy, 2025, 106, 16
DOI: 10.1016/j.ijhydene.2025.01.449

Mechanistic insight into efficient H2 generation upon HCOONa hydrolysis

Fuhua Xu, Jiaying Yan, Yanlan Wang and Xiang Liu

iScience, 2023, 26, 106504
DOI: 10.1016/j.isci.2023.106504

Enhanced Activity of WOx-Promoted PdNi Nanoclusters Confined by Amino-Modified KIT-6 for Dehydrogenation of Additive-Free Formic Acid

Wen-Fang Peng, Xiongfei Sun, Yiyue Ding, Peng Liu, Qilu Yao and Zhang-Hui Lu

ACS Sustainable Chem. Eng., 2023, 11, 1898
DOI: 10.1021/acssuschemeng.2c06538

A comparative study on carbon neutral hydrogen carrier production: Formic acid from CO2 vs. ammonia

Arti Mishra, Donghyun Kim, Talal Altahtamouni, Peter Kasak, Anton Popelka, Hyunwoong Park and Dong Suk Han

Journal of CO2 Utilization, 2024, 82, 102756
DOI: 10.1016/j.jcou.2024.102756

Unraveling the role of pyridyl sites in UiO-67 type MOFs supported Pd NPs for boosting formic acid dehydrogenation

Jiewei Rong, Rongmei Zhang, Mai Xu, Xu Chen, Xinyue Yang, Jinsong Hu, Xiru Cao, Zhentao Liu, Chunming Xu, Chunhui Zhou and Xilong Wang

Chemical Engineering Journal, 2025, 525, 170275
DOI: 10.1016/j.cej.2025.170275

Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid

Huipeng Zhao and Xiaoqiang Du

Chinese Journal of Structural Chemistry, 2024, 43, 100246
DOI: 10.1016/j.cjsc.2024.100246

Co-Cu nanoparticles uniformly embedded in the intra-crystalline mesoporous Silicalite-1 for catalytic ammonia borane hydrolysis

Huijuan Wei, Yanan Cui, Huinan Hou, Xiaoguang Zheng, Peng Jin, Yiqiang Wen, Xiangyu Wang, Yanyan Liu and Baojun Li

iScience, 2024, 27, 109745
DOI: 10.1016/j.isci.2024.109745

Durable built-in electric field in CoSe2-FeSe2@NC on N-doped honeycomb carbon for long-term efficient oxygen electrocatalysis toward zinc-air battery

Yixing Luo, Qingsheng Wu, Yongqing Fu and Ming Wen

Chemical Engineering Journal, 2025, 512, 162739
DOI: 10.1016/j.cej.2025.162739

Highly‐Exposed Co‐CoO Derived from Nanosized ZIF‐67 on N‐Doped Porous Carbon Foam as Efficient Electrocatalyst for Zinc‐Air Battery

Yixing Luo, Ming Wen, Jian Zhou, Qingsheng Wu, Guangfeng Wei and Yongqing Fu

Small, 2023, 19
DOI: 10.1002/smll.202302925

Improving the adsorption capacity of tetracycline and O3 on partially reduced Cu-MnCO3-Mn3O4/C with abundant oxygen vacancy for highly efficient oxidation-mineralization

Jianmin Chen, Tianjian Ji, Zuyi Lu, Yawei Xie, Zhaowei Jia, Liqin Zhou, Zhongfeng Shi, Zhenxia Zhao and Zhongxing Zhao

Applied Catalysis B: Environment and Energy, 2025, 361, 124624
DOI: 10.1016/j.apcatb.2024.124624

Highly Efficient Dehydrogenation of Formic Acid over Binary Palladium–Phosphorous Alloy Nanoclusters on N-Doped Carbon

Luyu Zhu, Yanli Liang, Lizhi Sun, Jianli Wang and Dongdong Xu

Inorg. Chem., 2021, 60, 10707
DOI: 10.1021/acs.inorgchem.1c01403

MOF-derived high oxygen vacancies CuO/CeO2 catalysts for low-temperature CO preferential oxidation

Fen Liu, Xiaohua Chen, Weiwei Jie, Yumeng Liu, Claudia Li, Guoqiang Song, Xia Gong, Qian Liu, Mei Qiu, Shunmin Ding, Feiyang Hu, Lei Gong and Sibudjing Kawi

Journal of Colloid and Interface Science, 2024, 674, 778
DOI: 10.1016/j.jcis.2024.06.110

Facile synthesis of agglomerated Ag–Pd bimetallic dendrites with performance for hydrogen generation from formic acid

Jun Liu, Lixin Lan, Xuanyan Liu, Xiaohui Yang and Xinhua Wu

International Journal of Hydrogen Energy, 2021, 46, 6395
DOI: 10.1016/j.ijhydene.2020.11.115

P-bridged Fe-X-Co coupled sites in hollow carbon spheres for efficient hydrogen generation

Wenjing Xu, Wei Li, Mei Liu, Xianji Guo, Hao Wen and Baojun Li

Journal of Colloid and Interface Science, 2024, 660, 792
DOI: 10.1016/j.jcis.2024.01.145

Hydrogen Production from Formic Acid Attained by Bimetallic Heterogeneous PdAg Catalytic Systems

Miriam Navlani-García, David Salinas-Torres and Diego Cazorla-Amorós

Energies, 2019, 12, 4027
DOI: 10.3390/en12214027

Hydrogen Production via Cerium-Promoted Dehydrogenation of Formic Acid Catalyzed by Carbon-Supported Palladium Nanoparticles

Yongwoo Kim, Gyeonghun Jang and Do Heui Kim

ACS Appl. Nano Mater., 2023, 6, 6929
DOI: 10.1021/acsanm.3c00668

Metal-organic framework-based catalysts for hydrogen production from liquid-phase chemical hydrides

Qilu Yao, Xiaolei Zhang, Zhang-Hui Lu and Qiang Xu

Coordination Chemistry Reviews, 2023, 493, 215302
DOI: 10.1016/j.ccr.2023.215302

Bimetallic Palladium–Nickel Nanoparticles Anchored on Carbon as High-Performance Electrocatalysts for Oxygen Reduction and Formic Acid Oxidation Reactions

Chiranjita Goswami, Himadri Saikia, Kohei Tada, Shingo Tanaka, Putla Sudarsanam, Suresh K. Bhargava and Pankaj Bharali

ACS Appl. Energy Mater., 2020, 3, 9285
DOI: 10.1021/acsaem.0c01622

Oxygen deficient interfacial effect in CeO2-modified Fe2O3/C for oxygen reduction reaction in alkaline electrolyte

Bhugendra Chutia and Pankaj Bharali

Catalysis Communications, 2022, 164, 106432
DOI: 10.1016/j.catcom.2022.106432

Carbon nitride-supported CuCeO2 composites derived from bimetal MOF for efficiently electrocatalytic nitrogen fixation

Kang Ye, Ziye He, Fengxi Wu, Yumin Wang, Lu Wang, Yong Cheng and Ying-Hua Zhou

International Journal of Hydrogen Energy, 2021, 46, 35319
DOI: 10.1016/j.ijhydene.2021.08.097

Bimetallic palladium chromium nanoparticles anchored on amine-functionalized titanium carbides for remarkably catalytic dehydrogenation of formic acid at mild conditions

Zongji Zhang, Dawei He, Zhou Wang, Shaobo Wu and Tong Liu

Journal of Catalysis, 2022, 410, 121
DOI: 10.1016/j.jcat.2022.04.021

Amine-functionalized carbon nanotubes supported NiAuPd nanoparticles as an efficient in-situ prepared catalyst for formic acid dehydrogenation

Shi-Lei Zhang, Si-Jia Li, Jia-Yun Wang, He-Nan Shang, Ya-Xuan Bai and Jin-Sheng Liang

International Journal of Hydrogen Energy, 2021, 46, 34727
DOI: 10.1016/j.ijhydene.2021.08.063

In-situ nitrogen and Cr2O3 co-doped MOF-derived porous carbon supported palladium nanoparticles: A highly effective catalyst towards formic acid dehydrogenation

Jiachao Duan, Qingyang Li, Yan Fu and Jie Chang

International Journal of Hydrogen Energy, 2021, 46, 39768
DOI: 10.1016/j.ijhydene.2021.09.191

Amine-functionalized Schiff base covalent organic frameworks supported PdAuIr nanoparticles as high-performance catalysts for formic acid dehydrogenation and hexavalent chromium reduction

Xiaosha Guo, Xixi Di, Tian Tang, Yixuan Shi, Dong Liu, Wei Wang, Zhifeng Liu, Xiaohui Ji and Xianzhao Shao

Journal of Colloid and Interface Science, 2024, 658, 362
DOI: 10.1016/j.jcis.2023.12.085

Unveiling the CeO2 morphology effect in Pd-CeO2/C heterostructures catalysts for formic acid dehydrogenation

Zhongchun Yuan, Tingting Cao, Min Deng, Jun Ma, Shuo Geng, Chunliang Yang, Yuan Ren, Mengqin Yao, Fei Liu and Xiaodan Wang

Fuel, 2023, 346, 128333
DOI: 10.1016/j.fuel.2023.128333

Efficient catalytic hydrogen storage of N-ethylcarbazole over RuNi alloy nanoparticles loaded on SBA-15 prepared by electrostatic adsorption

Yindong Wang and Xuefeng Bai

Fuel, 2023, 331, 125709
DOI: 10.1016/j.fuel.2022.125709

Support effect in Cu‐based catalysts for vapor phase dehydrogenation of 1‐decanol to decanal using CO 2 as a soft oxidant

Prathap Challa, Siva Sankar Enumula, Gidyonu Paleti, Mallesh Dosali, David Raju Burri and Seetha Rama Rao Kamaraju

Intl J of Energy Research, 2022, 46, 9166
DOI: 10.1002/er.7793

Recent progress on heterogeneous catalytic formic acid decomposition for hydrogen production

Haojie Li, Dongxu Song, Xuetao Wang, Xiuquan Li and Gaoyang Lei

Fuel, 2025, 383, 133824
DOI: 10.1016/j.fuel.2024.133824