Ke Xiao, Yongxin Hu, Yongyong Wan, XinXin Li, Qin Nie, Hao Yan, Liming Wang, Jinxi Liao, Deyong Liu, Yuanhong Tu, Jiansong Sun, Jeroen D. C. Codée and Qingju Zhang

Chem. Sci., 2022, 13, 1600
DOI: 10.1039/D1SC05772C

1,2-trans and regioselective glycosylation of multihydroxy sugars via a simple yet synergistic combination of BF3·Et2O in THF

Zhimei Wang, Longwei Gao, Yingjie Wang, Fuzhu Yang, Jinpeng Sang, Shuheng Pan, Xin Huang, Pan Zhang, Weijia Xie, Xiaoxing Wu, Biao Yu, Peng Xu, Xiaheng Zhang, Zhaolun Zhang and Wei Li

Green Chem., 2025, 27, 2331
DOI: 10.1039/D4GC04572F

Palladium(ii)-assisted activation of thioglycosides

Samira Escopy, Yashapal Singh and Alexei V. Demchenko

Org. Biomol. Chem., 2021, 19, 2044
DOI: 10.1039/D1OB00004G

(C6F5)3B·(HF)n-catalyzed glycosylation of disarmed glycosyl fluorides and reverse glycosyl fluorides

Qing Long, Jingru Gao, Ningjie Yan, Peng Wang and Ming Li

Org. Chem. Front., 2021, 8, 3332
DOI: 10.1039/D1QO00211B

Electrochemical α-glycosylation of exo-glycals

Jing Zhang, Chen-Fei Gao, Xin-Shan Ye and De-Cai Xiong

Chinese Chemical Letters, 2026, 37, 112200
DOI: 10.1016/j.cclet.2025.112200

Direct β-Mannosylation of Primary Alcohol Acceptors: Trisaccharide Iteration Assembly of β-1,6-Oligomannosides Corresponding to Kakelokelose

Peng Wang, Junlin Wang, Wenjun Yin, Xianyang Wang, Ni Song, Sumei Ren and Ming Li

Org. Lett., 2022, 24, 971
DOI: 10.1021/acs.orglett.1c04363

Efficient and versatile formation of glycosidic bonds via catalytic strain-release glycosylation with glycosyl ortho−2,2-dimethoxycarbonylcyclopropylbenzoate donors

Han Ding, Jian Lyu, Xiao-Lin Zhang, Xiong Xiao and Xue-Wei Liu

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-39619-7

Saponins of Selected Triterpenoids as Potential Therapeutic Agents: A Review

Uladzimir Bildziukevich, Martina Wimmerová and Zdeněk Wimmer

Pharmaceuticals, 2023, 16, 386
DOI: 10.3390/ph16030386

2‐Diphenylphosphinoyl‐acetyl as a Remote Directing Group for the Highly Stereoselective Synthesis of β‐Glycosides

Xianglai Liu, Yetong Lin, Ao Liu, Qianhui Sun, Huiyong Sun, Peng Xu, Guolong Li, Yingying Song, Weijia Xie, Haopeng Sun, Biao Yu and Wei Li

Chin. J. Chem., 2022, 40, 443
DOI: 10.1002/cjoc.202100865

Indium Bromide-catalyzed Unprecedented Hydrogenolysis: A Novel One-Pot Synthesis of Per-O-Acetylated β-carboxymethyl O and S-glycosides

Ram Naresh Yadav, Amrendra K Singh and Bimal Banik

COC, 2020, 24, 900
DOI: 10.2174/1385272824999200407093625

Recent Advances in Chemical Synthesis of Structural Domains of Lipopolysaccharides from the Commensal Gut‐Associated Microbiota

Xiufang Wang and Guozhi Xiao

ChemBioChem, 2023, 24
DOI: 10.1002/cbic.202300552

2,4-Dinitrobenzenesulfonamide-Directed SN2-Type Displacement Reaction Enables Synthesis of β-d-Glycosaminosides

Xianyang Wang, Peng Wang, Dongwei Li and Ming Li

Org. Lett., 2019, 21, 2402
DOI: 10.1021/acs.orglett.9b00688

Exploring the Glycosylation Reaction Inside the Resorcin[4]arene Capsule

Dario Schmid, Tian-Ren Li, Bernd Goldfuss and Konrad Tiefenbacher

J. Org. Chem., 2023, 88, 14515
DOI: 10.1021/acs.joc.3c01547

Tri(N-carbazolyl)phosphine Gold(I) Complexes: Structural and Catalytic Activity Studies

Chang Zheng, Yu Tang and Biao Yu

Inorg. Chem., 2022, 61, 16874
DOI: 10.1021/acs.inorgchem.2c02902

Total Synthesis of the Monomeric Unit of Lomaiviticin A

K. C. Nicolaou, Qifeng Chen, Ruofan Li, Yasuaki Anami and Kyoji Tsuchikama

J. Am. Chem. Soc., 2020, 142, 20201
DOI: 10.1021/jacs.0c10660

Triflamides and Triflimides: Synthesis and Applications

Mikhail Y. Moskalik and Vera V. Astakhova

Molecules, 2022, 27, 5201
DOI: 10.3390/molecules27165201

Chemical synthesis of rhynchosporosides

Xiufang Wang and Guozhi Xiao

Journal of Carbohydrate Chemistry, 2024, 43, 115
DOI: 10.1080/07328303.2024.2410798

Synthesis of Campylobacter jejuni capsular oligosaccharides and identification of a potential O -antigen against campylobacteriosis

Jianjun Wang, Xuemei Yang, Zirong Huang, Yong Su, Xinxin Zhang, Ni Song, Peng Wang, Chen Yang, Hongzhi Cao, Xue-Wei Liu, Xuechen Li, Sheng Chen and Ming Li

Sci. Adv., 2025, 11
DOI: 10.1126/sciadv.adu2318

Synthesis of spirostanol saponins via gold(I)‐catalyzed glycosylation in the presence of Ga(OTf)3, In(OTf)3, or HOTf

Teddy Stephen Ehianeta, Dacheng Shen, Peng Xu and Biao Yu

Chin. J. Chem., 2019, 37, 827
DOI: 10.1002/cjoc.201900126

Stereoselective gold(I)-catalyzed approach to the synthesis of complex α-glycosyl phosphosaccharides

Xiaojuan Zhang, Yutong Yang, Jiahao Ding, Yun Zhao, Hongbin Zhang and Yugen Zhu

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-28025-0

An Anomeric Base‐Tolerant Ester of 8‐Alkynyl‐1‐naphthoate for Gold(I)‐Catalyzed Glycosylation Reaction

Xiaojuan Zhang, Peng Xu, Zhengbing Zhou, Yazhou Zhang, Biao Yu and Yugen Zhu

Chin. J. Chem., 2023, 41, 1305
DOI: 10.1002/cjoc.202300005

Asymmetric Total Synthesis of the Complex Polycyclic Xanthone FD‐594

Tao Xie, Chaoying Zheng, Kuanwei Chen, Haibing He and Shuanhu Gao

Angew Chem Int Ed, 2020, 59, 4360
DOI: 10.1002/anie.201915787

Synthesis and Antiproliferative Activities of OSW‐1 Analogues Bearing 2”‐O‐p‐Acylaminobenzoyl Residues†

Lijun Sun, Di Zhu, Laura Olde Groote Beverborg, Ruina Wang, Yongjun Dang, Mingming Ma, Wei Li and Biao Yu

Chin. J. Chem., 2020, 38, 1091
DOI: 10.1002/cjoc.202000110

Insight into gold-catalyzed glycosylation of glycosyl ynenoates

Lvfeng Zhang, Youling Liang, Xiaona Li, Rongkun Liu, Jibin Zheng, Peng Xu, Biao Yu and You Yang

Journal of Carbohydrate Chemistry, 2024, 43, 21
DOI: 10.1080/07328303.2024.2366774

Recent Advances in Gold(III) Chemistry: Structure, Bonding, Reactivity, and Role in Homogeneous Catalysis

Luca Rocchigiani and Manfred Bochmann

Chem. Rev., 2021, 121, 8364
DOI: 10.1021/acs.chemrev.0c00552

Catalytic Gold Chemistry: From Simple Salts to Complexes for Regioselective C−H Bond Functionalization

Chandrasekar Praveen, Aurélien Dupeux and Véronique Michelet

Chemistry A European J, 2021, 27, 10495
DOI: 10.1002/chem.202100785

Total Synthesis of the Glycoside Antibiotic Paulomycin A

Jie Chen, Yi Ai, Hailin Wang, Yang Xu, Ziwen Li, Jinqu Li, Niu Huang and Chao Li

J. Am. Chem. Soc., 2026, 148, 10124
DOI: 10.1021/jacs.6c00331

Homogeneous Gold Catalysis for Regioselective Carbocyclization of Alkynyl Precursors

Chandrasekar Praveen and Sławomir Szafert

ChemPlusChem, 2023, 88
DOI: 10.1002/cplu.202300202

Direct Synthesis of 2,6‐Dideoxy‐β‐glycosides and β‐Rhamnosides with a Stereodirecting 2‐(Diphenylphosphinoyl)acetyl Group

Xianglai Liu, Yetong Lin, Wenyi Peng, Zhaolun Zhang, Longwei Gao, Yueer Zhou, Zhe Song, Yingjie Wang, Peng Xu, Biao Yu, Haopeng Sun, Weijia Xie and Wei Li

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202206128

Establishing the Comprehensive Structure−Activity Relationship of the Natural Antibiotic Kibdelomycin/Amycolamicin

Chenglong Chen, Yuyao Yin, Panrui Lu, Ting Han, Hui Wang and Chao Li

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202415439

Total Synthesis of Phellinus ribis Glycans with Immunostimulating Activities by an Orthogonal One-Pot Glycosylation Strategy

Jie Wan, Leilei Wang and Guozhi Xiao

Synlett, 2023, 34, 288
DOI: 10.1055/a-1969-3992

Chemical Synthesis of a Key Precursor Relevant to the Tetrasaccharide Repeating Unit from Treponema mediumATCC 700293

Wenbin Sun, Guangzong Tian, Meiru Ding, Chunjun Qin, Xiaopeng Zou, Jing Hu and Jian Yin

Chin. J. Chem., 2024, 42, 1615
DOI: 10.1002/cjoc.202400145

A Photoacid-Assisted Ag(I)-Catalyzed Glycosylation Based on ortho-Methoxycarbonylethynylphenyl Thioglycosides

Jing-dong Zhang, Yu-peng Yuan, Jiang-cheng Wu, Zi-kang Fu, Jia-qing Jiang, Hui Zhang, Jia-meng Chen, Guang-jian Liu and Guo-wen Xing

Org. Lett., 2026
DOI: 10.1021/acs.orglett.6c02219

Total Synthesis of Cordyceps militaris Glycans via Stereoselective Orthogonal One-Pot Glycosylation and α-Glycosylation Strategies

Yuxin Ma, Qiong Jiang, Xiufang Wang and Guozhi Xiao

Org. Lett., 2022, 24, 7950
DOI: 10.1021/acs.orglett.2c03081

Total synthesis of scutellarin and apigenin 7-O-β-d-glucuronide

Xin Liu, Guo-En Wen, Jian-Chao Liu, Jin-Xi Liao and Jian-Song Sun

Carbohydrate Research, 2019, 475, 69
DOI: 10.1016/j.carres.2019.02.005

Expedient synthesis of mucin-type oligosaccharide analogues using alkynyl glycosyl carbonate donors

Boddu Venkateswara Rao, Jennifer Johns and M. Carmen Galan

Carbohydrate Research, 2025, 553, 109497
DOI: 10.1016/j.carres.2025.109497

Synthesis of L‐Hexopyranosyl Fluorides Enabled by Radical Decarboxylative Fluorination: Assembly of a Pentasaccharide Repeating Unit Corresponding to Extracellular Polysaccharide S‐88

Zhi Qiao, Dongwei Li, Jingru Gao, Zijiao Hou, Ningjie Yan, Ni Song, Peng Wang and Ming Li

Chin. J. Chem., 2023, 41, 3037
DOI: 10.1002/cjoc.202300392

Overview of the current procedures in synthesis of heparin saccharides

Siran Zhao, Tianji Zhang, Ying Kan, Hongmei Li and Jin-ping Li

Carbohydrate Polymers, 2024, 339, 122220
DOI: 10.1016/j.carbpol.2024.122220

Precise Synthesis of Highly Branched Angelica dahurica Polysaccharides up to 66 Units Reveals a Minimal Motif for Wound Repair

Jialin Wang, Yang Ruan, Na Zhao, Sixu Lu, Rui Ge, Jing Ling, Chandler K. Wells, Wenbin Shen, Guizhong Xin, Chaofeng Zhang, Lian‐Wen Qi, Xin‐Shan Ye and Xianjin Qin

Angew Chem Int Ed, 2026
DOI: 10.1002/anie.5220143

A Mild Glycosylation Protocol with Glycosyl 1‐Methylimidazole‐2‐carboxylates as Donors

Jianpeng Chen, Yu Tang and Biao Yu

Eur J Org Chem, 2021, 2021, 4333
DOI: 10.1002/ejoc.202100677

Gold(I)-catalyzed rearrangement of glycosyl ortho-allenylbenzoates leading to the formation of C-glycosides

Jianpeng Chen, Yu Tang and Biao Yu

Tetrahedron, 2022, 129, 133145
DOI: 10.1016/j.tet.2022.133145

NIS/TMSOTf-Promoted Glycosidation of Glycosyl ortho-Hexynylbenzoates for Versatile Synthesis of O-Glycosides and Nucleosides

Rongkun Liu, Qingting Hua, Qixin Lou, Jiazhe Wang, Xiaona Li, Zhi Ma and You Yang

J. Org. Chem., 2021, 86, 4763
DOI: 10.1021/acs.joc.1c00151

Intramolecular activation of imidate with cationic gold(I) catalyst: A new benzylation reaction of alcohols

Shintaro Ban, Tomotake Endo, Rikako Matsui, Nobuyoshi Morita, Yoshimitsu Hashimoto, Kosaku Tanaka and Osamu Tamura

Tetrahedron Letters, 2020, 61, 152233
DOI: 10.1016/j.tetlet.2020.152233

Development of Glycosylation Protocols Using Glycosyl N-Phenylethynyl Pyrrole-2-carboxylates as Donors

Mengyu Li, Li Song, Liya Yang, Yitian Zhao, Meifang Yang and Houchao Tao

Org. Lett., 2024, 26, 9926
DOI: 10.1021/acs.orglett.4c03768

An environmentally benign protocol for the synthesis of sugar 1,2-orthoesters in poly(ethylene glycol) dimethyl ether (DMPE)

Jian Yang, Shanqiao Wei, Jinzhong Zhao, Wei Zeng, Huawu Shao and Xiaofeng Ma

Carbohydrate Research, 2023, 534, 108902
DOI: 10.1016/j.carres.2023.108902

Modular Synthesis of Nona‐Decasaccharide Motif from Psidium guajava Polysaccharides: Orthogonal One‐Pot Glycosylation Strategy

Yunqin Zhang, Zixi Chen, Yingying Huang, Shaojun He, Xingkuan Yang, Zhibing Wu, Xiufang Wang and Guozhi Xiao

Angewandte Chemie, 2020, 132, 7646
DOI: 10.1002/ange.202000992

Modular Synthesis of a Tridecasaccharide Motif of Bacteroides vulgatus Lipopolysaccharides against Inflammatory Bowel Diseases through an Orthogonal One‐Pot Glycosylation Strategy

Yunqin Zhang, Leilei Wang, Qingli Zhou, Zuoshan Li, Dan Li, Caixia Yin, Xiufang Wang and Guozhi Xiao

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301351

Merging Reagent Modulation and Remote Anchimeric Assistance for Glycosylation: Highly Stereoselective Synthesis of α‐Glycans up to a 30‐mer

Yunqin Zhang, Haiqing He, Zixi Chen, Yingying Huang, Guisheng Xiang, Penghua Li, Xingkuan Yang, Gang Lu and Guozhi Xiao

Angew Chem Int Ed, 2021, 60, 12597
DOI: 10.1002/anie.202103826

In(OTf)3-Only-Catalyzed Glycosylation via Activation of an Alkyne Appended with an Amide Auxiliary Group

Liya Yang, Yanli Qiu, Lingyun Pan, Zijie Zhou, Yan Tan, Menghan Li, Yulong Zhu, Xiaodi Yang, Xiangwei Zheng, Weiliang Gu, Yan Ren and Houchao Tao

Org. Lett., 2025, 27, 1735
DOI: 10.1021/acs.orglett.5c00219

Activation of 1-methylimidazole group-installed glycosyl ester donors with hydrogen-bond-forming (thio)urea catalysts

Mohan Lal, Himanshu Gangwar, Ariza Khanam, Ashwani Tiwari and Pintu Kumar Mandal

Carbohydrate Research, 2026, 565, 109911
DOI: 10.1016/j.carres.2026.109911

Precise Synthesis of Highly Branched Angelica dahurica Polysaccharides up to 66 Units Reveals a Minimal Motif for Wound Repair

Jialin Wang, Yang Ruan, Na Zhao, Sixu Lu, Rui Ge, Jing Ling, Chandler K. Wells, Wenbin Shen, Guizhong Xin, Chaofeng Zhang, Lian‐Wen Qi, Xin‐Shan Ye and Xianjin Qin

Angewandte Chemie, 2026
DOI: 10.1002/ange.5220143

Direct Synthesis of α- and β-2′-Deoxynucleosides with Stereodirecting Phosphine Oxide via Remote Participation

Xintong Tang, Yueer Zhou, Yingjie Wang, Yetong Lin, Shuheng Pan, Qianwei Che, Jinpeng Sang, Ziming Gao, Weiting Zhang, Yuanyuan Wang, Guolong Li, Longwei Gao, Zhimei Wang, Xudong Yang, Ao Liu, Suyu Wang, Biao Yu, Peng Xu, Zhe Wang, Zhaolun Zhang, Peng Yang, Weijia Xie, Haopeng Sun and Wei Li

J. Am. Chem. Soc., 2024, 146, 8768
DOI: 10.1021/jacs.4c01780

Catalytic and highly stereoselective β-mannopyranosylation using a 2,6-lactone-bridged mannopyranosyl ortho-hexynylbenzoate as donor

Yingle Feng, Jie Yang, Chenglin Cai, Taotao Sun, Qi Zhang and Yonghai Chai

Chinese Chemical Letters, 2022, 33, 4878
DOI: 10.1016/j.cclet.2022.02.071

Chemical Synthesis Creates Single Glycoforms of the Ectodomain of Herpes Simplex Virus-1 Glycoprotein D

Jie Zhao, Xinliang Liu, Jialin Liu, Farong Ye, Bingcheng Wei, Minggang Deng, Tiehai Li, Ping Huang and Ping Wang

J. Am. Chem. Soc., 2024, 146, 2615
DOI: 10.1021/jacs.3c11543

Expeditious Synthesis of 2‐Deoxy‐2‐perfluoroalkyl Glycosides

Shen Cao, Haobo Zhang, Niming Zhu, Peng Xu, Xiaoping Chen, Biao Yu and Xiaheng Zhang

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.1824435

Expeditious Synthesis of 2‐Deoxy‐2‐perfluoroalkyl Glycosides

Shen Cao, Haobo Zhang, Niming Zhu, Peng Xu, Xiaoping Chen, Biao Yu and Xiaheng Zhang

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.1824435

A Strain-Promoted Divergent Chemical Steroidation Unveils Potent Anti-Inflammatory Pseudo-Steroidal Glycosides

Han Ding, Xiao-Lin Zhang, Aoxin Guo, Qian Ping Lee, Chao Cai, Ming Li, Hongzhi Cao and Xue-Wei Liu

J. Am. Chem. Soc., 2024, 146, 11811
DOI: 10.1021/jacs.4c00537

Glycosylation with 3,5-Dimethyl-4-(2′-phenylethynylphenyl)phenyl (EPP) Glycosides via a Dearomative Activation Mechanism

Zhifei Hu, Yu Tang and Biao Yu

J. Am. Chem. Soc., 2019, 141, 4806
DOI: 10.1021/jacs.9b00210

Total Synthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin

Shaoqiang Yang, Chenglong Chen, Jie Chen and Chao Li

J. Am. Chem. Soc., 2021, 143, 21258
DOI: 10.1021/jacs.1c11477

Glycosylation of 2-(2-Propylsulfinyl)benzyl 1,2-Orthoester Glycosides Initiated by Sulfoxide Activation

Pinru Wu, Xiong Xiao, Sicheng Zhou, Lingkui Meng, Jing Zeng and Qian Wan

Org. Lett., 2024, 26, 6053
DOI: 10.1021/acs.orglett.4c02210

Gold(I)-Catalyzed Intermolecular Rearrangement Reaction of Glycosyl Alkynoic β-Ketoesters for the Synthesis of 4-O-Glycosylated 2-Pyrones

Rongkun Liu, Xiaoqian Li, Xiaona Li, Jiazhe Wang and You Yang

J. Org. Chem., 2019, 84, 14141
DOI: 10.1021/acs.joc.9b01582

Stereoselective synthesis of α-glucosides with glucosyl (Z)-Ynenoates as donors

Zhi Ma, Yi Hu, Xiaona Li, Rongkun Liu, E Xia, Peng Xu and You Yang

Carbohydrate Research, 2023, 523, 108710
DOI: 10.1016/j.carres.2022.108710

5,7‐Membered Cyclometallated Gold(III) Complexes with Pyridine‐Phenyl‐Oxazoline N^C^N Ligands as Catalysts for Organic Transformation Reactions Under Silver‐Free Conditions

Yosephine Tania Limanto, Karen Ka‐Yan Kung, Aries Kwok‐Heung Chan, Nathanael Chun‐Him Lai and Man‐Kin Wong

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70038

Total Synthesis of Nucleoside Antibiotics Amicetin, Plicacetin, and Cytosaminomycin A—D

Jiqiang Fu, Peng Xu and Biao Yu

Chin. J. Chem., 2021, 39, 2679
DOI: 10.1002/cjoc.202100284

Glycan Assembly Strategy: From Concept to Application

Mingli Liu, Xianjin Qin and Xin‐Shan Ye

The Chemical Record, 2021, 21, 3256
DOI: 10.1002/tcr.202100183

Reactivity Tuning by Ring Size: A Glycosylation Protocol Using Thiophene-Scaffolded Glycosyl Donors

Jingyu Tian, Yan Tan, Liya Yang, Mengyu Li, Yanli Qiu, Zijie Zhou, Xin Zhou, Shusheng Lai, Ming Chen, Xiangwei Zheng, Meifang Yang and Houchao Tao

Org. Lett., 2025, 27, 14310
DOI: 10.1021/acs.orglett.5c04703

Merging Reagent Modulation and Remote Anchimeric Assistance for Glycosylation: Highly Stereoselective Synthesis of α‐Glycans up to a 30‐mer

Yunqin Zhang, Haiqing He, Zixi Chen, Yingying Huang, Guisheng Xiang, Penghua Li, Xingkuan Yang, Gang Lu and Guozhi Xiao

Angewandte Chemie, 2021, 133, 12705
DOI: 10.1002/ange.202103826

A One-Pot Synthesis of Glycans and Nucleosides Based on ortho-(1-Phenylvinyl)benzyl Glycosides

Rui Yang, Haiqing He, Zixi Chen, Yingying Huang and Guozhi Xiao

Org. Lett., 2021, 23, 8257
DOI: 10.1021/acs.orglett.1c02998

Cycloisomerization of π‐Coupled Heteroatom Nucleophiles by Gold Catalysis: En Route to Regiochemically Defined Heterocycles

Chandrasekar Praveen

The Chemical Record, 2021, 21, 1697
DOI: 10.1002/tcr.202100105

Modular Synthesis of a Tridecasaccharide Motif of Bacteroides vulgatus Lipopolysaccharides against Inflammatory Bowel Diseases through an Orthogonal One‐Pot Glycosylation Strategy

Yunqin Zhang, Leilei Wang, Qingli Zhou, Zuoshan Li, Dan Li, Caixia Yin, Xiufang Wang and Guozhi Xiao

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301351

AuCl3-Catalyzed Hemiacetal Activation for the Stereoselective Synthesis of 2-Deoxy Trehalose Derivatives

Robin Jeanneret, Carlo Walz, Maarten van Meerbeek, Sarah Coppock and M. Carmen Galan

Org. Lett., 2022, 24, 6304
DOI: 10.1021/acs.orglett.2c02530

Gold(I)-Catalyzed Tandem Intramolecular Methoxylation/Double Aldol Condensation Strategy Yielding 2,2′-Spirobi[indene] Derivatives

Jingfu Zhang, Sen Zhang, Zhixing Ding, Anbin Hou, Jiayue Fu, Hongwei Su, Maosheng Cheng, Bin Lin, Lu Yang and Yongxiang Liu

Org. Lett., 2022, 24, 6777
DOI: 10.1021/acs.orglett.2c02653

Gold(I)-Catalyzed Glycosylation with Glycosyl Ynenoates as Donors

Xiaona Li, Chenyu Li, Rongkun Liu, Jiazhe Wang, Zixuan Wang, Yan Chen and You Yang

Org. Lett., 2019, 21, 9693
DOI: 10.1021/acs.orglett.9b03851

Tuning Glycosyl Donor Reactivity via Nitroarene Protecting Groups: A Semiarmed Strategy for Selective Glycosylation

Yuji Otsuka and Toshihiro Yamamoto

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202500537

Alkenyl Glycosyl Donors as Versatile Tools for Carbohydrate Synthesis

Zhiwen Liao, Jing Zeng, Lingkui Meng and Qian Wan

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500888

Glycosylation Enabled by Successive Rhodium(II) and Brønsted Acid Catalysis

Lingkui Meng, Peng Wu, Jing Fang, Ying Xiao, Xiong Xiao, Guangsheng Tu, Xiang Ma, Shuang Teng, Jing Zeng and Qian Wan

J. Am. Chem. Soc., 2019, 141, 11775
DOI: 10.1021/jacs.9b04619

Direct Synthesis of 2,6‐Dideoxy‐β‐glycosides and β‐Rhamnosides with a Stereodirecting 2‐(Diphenylphosphinoyl)acetyl Group

Xianglai Liu, Yetong Lin, Wenyi Peng, Zhaolun Zhang, Longwei Gao, Yueer Zhou, Zhe Song, Yingjie Wang, Peng Xu, Biao Yu, Haopeng Sun, Weijia Xie and Wei Li

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202206128

Mimicry of the proton wire mechanism of enzymes inside a supramolecular capsule enables β-selective O-glycosylations

Tian-Ren Li, Fabian Huck, GiovanniMaria Piccini and Konrad Tiefenbacher

Nat. Chem., 2022, 14, 985
DOI: 10.1038/s41557-022-00981-6

Total Synthesis and Structural Revision of Mangrolide D

Hiromu Hattori, Lukas V. Hoff and Karl Gademann

Org. Lett., 2019, 21, 3456
DOI: 10.1021/acs.orglett.9b01256

Asymmetric Total Synthesis of the Complex Polycyclic Xanthone FD‐594

Tao Xie, Chaoying Zheng, Kuanwei Chen, Haibing He and Shuanhu Gao

Angewandte Chemie, 2020, 132, 4390
DOI: 10.1002/ange.201915787

Modular Synthesis of Nona‐Decasaccharide Motif from Psidium guajava Polysaccharides: Orthogonal One‐Pot Glycosylation Strategy

Yunqin Zhang, Zixi Chen, Yingying Huang, Shaojun He, Xingkuan Yang, Zhibing Wu, Xiufang Wang and Guozhi Xiao

Angew Chem Int Ed, 2020, 59, 7576
DOI: 10.1002/anie.202000992

Development of gold catalysts supported by unreducible materials: Design and promotions

Jingjie Luo, Yanan Dong, Corinne Petit and Changhai Liang

Chinese Journal of Catalysis, 2021, 42, 670
DOI: 10.1016/S1872-2067(20)63743-3

Transition‐Metal‐Free Cascade Enyne Rearrangement and Cyclopropanation of Allenylphosphine Oxides with N‐Tosylhydrazones Accessing Alkynylcyclopropane Derivatives

Kai Luo, Yuan Li, Zitong Fu, Ling Zhang, Zhipeng Wang, Jiangyan Xu, Bingjun Yu and Lei Wu

Adv Synth Catal, 2021, 363, 4222
DOI: 10.1002/adsc.202100392

Copper-Catalyzed Glycosylation Protocol Based on 1,4-Naphthoquinone-Derived Thioglycosides

Mengyu Li, Xi Xiang, Zijie Zhou, Xin Zhou, Meifang Yang, Yitian Zhao, Xiangwei Zheng and Houchao Tao

Org. Lett., 2025, 27, 2262
DOI: 10.1021/acs.orglett.5c00473

Glycosylation and Protecting Group Strategies Towards the Synthesis of Saponins and Bacterial Oligosaccharides: A Personal Account

Kevin Muru and Charles Gauthier

The Chemical Record, 2021, 21, 2990
DOI: 10.1002/tcr.202000181

Para -(3-phenylpropiolamido)phenyl (PPAP) glycosides: Harnessing ipso -cyclization–driven glycosylation for strategic flexibility

Meifang Yang, Yanli Qiu, Yan Tan, Li Song, Xi Xiang, Yitian Zhao, Xing Zheng, Xiangwei Zheng, Weiliang Gu, Guoqiang Lin and Houchao Tao

Sci. Adv., 2025, 11
DOI: 10.1126/sciadv.ady4274

Gold‐Catalysed Nitroalkyne Cycloisomerization – Synthetic Utility

Pawan S. Dhote, Swapnil V. Halnor and Chepuri V. Ramana

The Chemical Record, 2021, 21, 3546
DOI: 10.1002/tcr.202100111

Recent Advances in Gold(I)-Catalyzed Approaches to Three-Type Small-Molecule Scaffolds via Arylalkyne Activation

Lu Yang, Hongwei Su, Yue Sun, Sen Zhang, Maosheng Cheng and Yongxiang Liu

Molecules, 2022, 27, 8956
DOI: 10.3390/molecules27248956

Reaction Rate and Stereoselectivity Enhancement in Glycosidations with O-Glycosyl Trihaloacetimidate Donors due to Catalysis by a Lewis Acid–Nitrile Cooperative Effect

Tianlu Li, Tong Li, Yue Yang, Yongshun Qiu, Yingguo Liu, Miaomiao Zhang, Haoru Zhuang, Richard R. Schmidt and Peng Peng

J. Org. Chem., 2024, 89, 7865
DOI: 10.1021/acs.joc.4c00554

Direct N-Glycosylation of Amides/Amines with Glycal Donors

Ying Wang, Hui Yao, Min Hua, Yang Jiao, Haibo He, Mingguo Liu, Nianyu Huang and Kun Zou

J. Org. Chem., 2020, 85, 7485
DOI: 10.1021/acs.joc.0c00975

Chemical Synthesis of the Nucleoside Antibiotic Capuramycin

Guozhi Xiao and Haiqing He

Eur J Org Chem, 2021, 2021, 3681
DOI: 10.1002/ejoc.202100613

Gold(I)-Catalyzed 2-Deoxy-β-glycosylation via 1,2-Alkyl/Arylthio Migration: Synthesis of Velutinoside A Pentasaccharide

Xianyang Wang, Han Ding, Aoxin Guo, Xiaofei Song, Peng Wang, Ni Song, Biao Yu, Peng Xu, Xue-Wei Liu and Ming Li

J. Am. Chem. Soc., 2025, 147, 4469
DOI: 10.1021/jacs.4c15805

Stereoselective Synthesis and Immunological Evaluation of Common O‐antigen of P. mirabilisOE and P. vulgarisTG103

Xiaopei Wu, Jinsheng Lai, Kexin Yang, Yunxia Xue, Jinxi Liao, Liming Wang, Jian‐song Sun, Jing Hu, Jian Yin and Qingju Zhang

Chin. J. Chem., 2023, 41, 535
DOI: 10.1002/cjoc.202200638

Orthogonal One-Pot Synthesis of Oligosaccharides Based on Glycosyl ortho-Alkynylbenzoates

Yunqin Zhang, Guisheng Xiang, Shaojun He, Yikao Hu, Yanjun Liu, Lili Xu and Guozhi Xiao

Org. Lett., 2019, 21, 2335
DOI: 10.1021/acs.orglett.9b00617

Glycosyl Esters as Stable Donors in Chemical Glycosylation

Sumit Pareek, Pavan Mandadi and Someswara Rao Sanapala

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401330

Dinuclear gold(I)‐N‐heterocyclic carbene complexes: Synthesis, characterization, and catalytic application for hydrohydrazidation of terminal alkynes

Seema Yadav, Sriparna Ray, Ajeet Singh, Shaikh M. Mobin, Tapta Kanchan Roy and Chandrakanta Dash

Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5942

Establishing the Comprehensive Structure−Activity Relationship of the Natural Antibiotic Kibdelomycin/Amycolamicin

Chenglong Chen, Yuyao Yin, Panrui Lu, Ting Han, Hui Wang and Chao Li

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202415439

Phyllanthus Engleri and other Species: Traditional and Medicinal Values

Anita Maddheshiya, Syed Salman Ali and Vandana Arora Sethi

ijnrph, 2024, 235
DOI: 10.61554/ijnrph.v2i1.2024.69

Triflic Imide‐Catalyzed Glycosylation of Disarmed Glycosyl ortho‐Isopropenylphenylacetates and ortho‐Isopropenylbenzyl Thioglycosides

Zhi Qiao, Peng Wang, Jingxuan Ni, Dongwei Li, Yao Sun, Tiantian Li and Ming Li

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202101367

Gold(I)-Catalyzed 6-exo-dig Hydroamination/7-endo-dig Cycloisomerization Domino Approach to 3,7a-Diazacyclohepta[jk]fluorene Derivatives

Lu Yang, Fukai Xie, Lianjie Zhang, Jipeng Wei, Jiaji Li, Xiang Li, Jiayue Fu, Bin Lin, Maosheng Cheng and Yongxiang Liu

Org. Lett., 2024, 26, 10030
DOI: 10.1021/acs.orglett.4c03926

Influence of Nitrogen Atom on Alkynyl Benzoate Donor Reactivity: 3-(Phenyl Ethynyl) Picolinates as Stable and Reactive Glycosyl Donors Toward Stereoselective Glycoside Bond Formation

Rajesh Lenka, Sangay Moktan, Mahendra K. Rotta and Pavan K. Kancharla

Synlett, 2026, 37, 663
DOI: 10.1055/a-2744-2097

Stereoselective Synthesis of Glycosyl Phosphonates from Saccharides Via Selenium-Catalyzed Dehydrogenations

Dang-Wei Qian, Lan Ma and Shang-Dong Yang

Org. Lett., 2026, 28, 7111
DOI: 10.1021/acs.orglett.6c01453

Chemical synthesis of TMG-chitotriomycin

Yunqin Zhang and Guozhi Xiao

Journal of Carbohydrate Chemistry, 2021, 40, 327
DOI: 10.1080/07328303.2021.2009504

Tf2O/TfOH catalytic glycosylation using o-(p-methoxyphenylethynyl)benzyl glycosides as donors and its application in synthesis of oligosaccharides

Xinguang Lan, Chenglin Cai, Jincai Wang, Qi Zhang, Yingle Feng and Yonghai Chai

Tetrahedron Letters, 2023, 116, 154342
DOI: 10.1016/j.tetlet.2023.154342