Vanadium(v) arylimido alkylidene N-heterocyclic carbene complexes containing fluorinated alkoxide or halogenated phenoxide ligands for the syndiospecific ROMP of cyclic olefins

Kotohiro Nomura, Shuko Kuwahara, Jirapa Suthala, Yuta Kawamoto, Daisuke Shimoyama and Michael R. Buchmeiser

New J. Chem., 2024, 48, 14865
DOI: 10.1039/D4NJ02537G

cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(v)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

Kotohiro Nomura and Sapanna Chaimongkolkunasin

Catal. Sci. Technol., 2020, 10, 5840
DOI: 10.1039/D0CY00938E

A benzene-bridged divanadium complex-early transition metal catalyst for alkene alkylarylation with PhI(O2CR)2via decarboxylation

Lei Zhang, Hongfei Zhou, Shaokun Bai and Shaodan Li

Dalton Trans., 2021, 50, 3201
DOI: 10.1039/D0DT04295A

N-Heterocyclic carbene and cyclic (alkyl)(amino)carbene complexes of vanadium(iii) and vanadium(v)

Günther Horrer, Ivo Krummenacher, Sophie Mann, Holger Braunschweig and Udo Radius

Dalton Trans., 2022, 51, 11054
DOI: 10.1039/D2DT01250B

Facile in situ generation of highly active (arylimido)vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization (ROMP) of cyclic olefins by immediate phenoxy ligand exchange

Hitomi Hayashibara, Xiaohua Hou and Kotohiro Nomura

Chem. Commun., 2018, 54, 13559
DOI: 10.1039/C8CC07974A

Combining a ligand photogenerator and a Ru precatalyst: a photoinduced approach to cross-linked ROMP polymer films

Thi Kim Hoang Trinh, Gautier Schrodj, Séverinne Rigolet, Julien Pinaud, Patrick Lacroix-Desmazes, Loic Pichavant, Valérie Héroguez and Abraham Chemtob

RSC Adv., 2019, 9, 27789
DOI: 10.1039/C9RA05831A

Synthesis of Vanadium Oxo Alkylidene Complex and Its Reactivity in Ring-Closing Olefin Metathesis Reactions

Dmitry S. Belov, Didac A. Fenoll, Indranil Chakraborty, Xavier Solans-Monfort and Konstantin V. Bukhryakov

Organometallics, 2021, 40, 2939
DOI: 10.1021/acs.organomet.1c00425

Developments in vanadium-catalysed polymerisation reactions: A review

Hikaru Ishikura, Robin Neven, Theo Lange, Alexandra Galetová, Burgert Blom and Dario Romano

Inorganica Chimica Acta, 2021, 515, 120047
DOI: 10.1016/j.ica.2020.120047

Vanadium‐Catalyzed Decarboxylative Alkylation/Cyclization of Alkenes With PhI(O2CR)2 to Construct Alkylated Indolo[2,1‐b]quinazolinones and Isoquinoline‐1,3‐diones

Shaokun Bai, Xiafang Liu, Ping Zhang, Lei Zhang and Yanfeng Zhang

Applied Organom Chemis, 2025, 39
DOI: 10.1002/aoc.70292

Organometallic Chemistry of Group 5 Transition Metal-Alkylidene Complexes and their Catalysts for Olefin Metathesis Polymerization

Kotohiro Nomura, Akito Nishiyama and Shuko Kuwahara

J. Synth. Org. Chem. Jpn., 2025, 83, 315
DOI: 10.5059/yukigoseikyokaishi.83.315

Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes

Janis V. Musso, Mathis J. Benedikter, Dongren Wang, Wolfgang Frey, Hagen J. Altmann and Michael R. Buchmeiser

Chemistry A European J, 2020, 26, 8709
DOI: 10.1002/chem.202000840

Reactions of (Arylimido)vanadium(V)–Trialkyl Complexes with Phenols: Effects of Arylimido Ligands and Phenols for Formation of the Vanadium Phenoxides

Hitomi Hayashibara, Aurapat Ngamnithiporn and Kotohiro Nomura

ACS Omega, 2019, 4, 5818
DOI: 10.1021/acsomega.9b00531

Singlet Spin State Drives [V]-Carbene To Catalyze Olefin Metathesis: A Computational Analysis

Adenilson Sousa-Silva, Katherine Paredes-Gil, José Milton Elias de Matos and Égil Sá

Organometallics, 2022, 41, 1295
DOI: 10.1021/acs.organomet.1c00699

Reactivity of 1.1.1-Propellane with (silox)3M (M = Ti, V, Cr): Structures of (silox)3V═(cC4H4)═CH2 and [(silox)3Cr–(1.1.1-C5H6)−]2

Gregory M. George, Peter T. Wolczanski, Thomas R. Cundari and Samantha N. MacMillan

Organometallics, 2022, 41, 3356
DOI: 10.1021/acs.organomet.2c00313

High Temperature Ring Opening Metathesis Polymerization (ROMP) of Low Strained Cycloheptene and Cis-Cyclooctene by (Arylimido)Niobium(V)–Alkylidene Catalysts

Nao HAMAKAWA, Kanchana CHATCHAIPAIBOON and Kotohiro NOMURA

J. Jpn. Petrol. Inst., 2024, 67, 176
DOI: 10.1627/jpi.67.176

(Arylimido)niobium(V)–Alkylidenes, Nb(CHSiMe3)(NAr)[OC(CF3)3](PMe3)2, That Enable to Proceed Living Metathesis Polymerization of Internal Alkynes

Itsuki Izawa and Kotohiro Nomura

Macromolecules, 2020, 53, 5266
DOI: 10.1021/acs.macromol.0c00874

Effect of Phosphine, B(C₆F₅)₃ in Ring Opening Metathesis Polymerization (ROMP) of Cyclic Olefins by (Arylimido)Vanadium(V)–Alkylidene Catalysts and the Chain Transfer ROMP of Cycloheptene

Sirilak MEKCHAM, Xiaohua HOU and Kotohiro NOMURA

J. Jpn. Petrol. Inst., 2022, 65, 200
DOI: 10.1627/jpi.65.200

Ring-opening metathesis polymerization with vanadium(V) alkylidenes: Survey of initiators, density-functional theory calculations, and functional group tolerance

Wesley S. Farrell, Gabriela Tejeda, Xavier Solans-Monfort, Égil Sá and Konstantin V. Bukhryakov

Journal of Organometallic Chemistry, 2023, 996, 122753
DOI: 10.1016/j.jorganchem.2023.122753

Synthesis and Reactivity of [PCCP]-Coordinated Group 5 Alkyl and Alkylidene Complexes Featuring a Metallacyclopropene Backbone

Patrick Federmann, Tim Richter, Hubert Wadepohl and Joachim Ballmann

Organometallics, 2019, 38, 4307
DOI: 10.1021/acs.organomet.9b00577

Decomposition of Vanadium(V) Alkylidenes Relevant to Olefin Metathesis

Wesley S. Farrell, Christine Greene, Pokhraj Ghosh, Timothy H. Warren and Peter Y. Zavalij

Organometallics, 2020, 39, 3906
DOI: 10.1021/acs.organomet.0c00610

A Vanadium Methylidene

Shuruthi Senthil, Dominik Fehn, Michael R. Gau, Alexandra M. Bacon, Patrick J. Carroll, Karsten Meyer and Daniel J. Mindiola

J. Am. Chem. Soc., 2024, 146, 15666
DOI: 10.1021/jacs.4c01906

(Arylimido)niobium(V)–Alkylidenes as the Catalysts for Ring-Opening Metathesis Polymerization (ROMP) of Cyclic Olefins: Z-Specific ROMP of Cyclooctene by Nb(CHSiMe3)(NC6H5)[OC(CF3)3](PMe3)2

Kanchana Chatchaipaiboon and Kotohiro Nomura

Organometallics, 2023, 42, 1052
DOI: 10.1021/acs.organomet.2c00665

Ring Opening Metathesis Polymerization (ROMP) of Norbornenes by (Arylimido)Niobium(V)–Alkylidene Catalysts, Nb(CHSiMe₃)(NAr)[OC(CF₃)₃](PMe₃)₂

Kanchana CHATCHAIPAIBOON and Kotohiro NOMURA

J. Jpn. Petrol. Inst., 2021, 64, 238
DOI: 10.1627/jpi.64.238

Controlled Polymerization of 3-Hexyne, 4-Octyne, and 5-Decyne by Nb(CHCMe2Ph)(NC6F5)[OC(CF3)3](PMe3)2 Catalyst: Structural Analysis of Catalytically Inactive Species

Akito Nishiyama, Kanchana Chatchaipaiboon and Kotohiro Nomura

Organometallics, 2025, 44, 1633
DOI: 10.1021/acs.organomet.5c00177

Olefin Metathesis Reaction in Rubber Chemistry and Industry and Beyond

Peng Liu and Chunjin Ai

Ind. Eng. Chem. Res., 2018, 57, 3807
DOI: 10.1021/acs.iecr.7b03830

Structural Characterization of (Arylimido)vanadium(V) Compounds with 2,6‐Difluorophenoxide Ligand

Toshiyuki Moriuchi, Takashi Sakuramoto, Masafumi Nishina, Ryota Kawai and Toshikazu Hirao

Zeitschrift anorg allge chemie, 2017, 643, 1173
DOI: 10.1002/zaac.201700205

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2017

James W. Herndon

Coordination Chemistry Reviews, 2018, 377, 86
DOI: 10.1016/j.ccr.2018.08.007

Vanadium Imido NHC Complexes for Ring-Closing Olefin Metathesis Reactions

Gabriela Tejeda, Dmitry S. Belov, Didac A. Fenoll, Kelly L. Rue, Charlene Tsay, Xavier Solans-Monfort and Konstantin V. Bukhryakov

Organometallics, 2022, 41, 361
DOI: 10.1021/acs.organomet.2c00013

Metal‐Free Ring‐Opening Metathesis Polymerization with Hydrazonium Initiators**

Phong K. Quach, Jesse H. Hsu, Ivan Keresztes, Brett P. Fors and Tristan H. Lambert

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202203344

Synthesis and Activity of Vanadium Oxo NHC Alkylidenes. Remarkable Preference for Degenerate Metathesis and Application for Carbon Isotope Exchange

Dmitry S. Belov, Carlos M. Acosta, Miquel Garcia-Molina, Kelly L. Rue, Xavier Solans-Monfort and Konstantin V. Bukhryakov

Organometallics, 2022, 41, 2897
DOI: 10.1021/acs.organomet.2c00465

Oxovanadium hydrazone complex immobilized on magnetic nanoparticles: A reusable and efficient nanocatalyst for the oxidation of norbornene

Marzieh Sarkheil and Maryam Lashanizadegan

Solid State Sciences, 2020, 103, 106197
DOI: 10.1016/j.solidstatesciences.2020.106197

The Chemistry of Vanadium bis‐Phenolate NHC Complexes in Three Oxidation States

Florian R. Neururer, Daniel Leitner, Shenyu Liu, Klaus Wurst, Holger Kopacka, Michael Seidl and Stephan Hohloch

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202300180

A Robust Vanadium(V) Tris(2-pyridyl)borate Catalyst for Long-Lived High-Temperature Ethylene Polymerization

Jin Qian and Robert J. Comito

Organometallics, 2021, 40, 1817
DOI: 10.1021/acs.organomet.1c00334

Reactivity of Metal Carbenes with Olefins: Theoretical Insights on the Carbene Electronic Structure and Cyclopropanation Reaction Mechanism

E. de Brito Sá, A. Rimola, L. Rodríguez-Santiago, M. Sodupe and X. Solans-Monfort

J. Phys. Chem. A, 2018, 122, 1702
DOI: 10.1021/acs.jpca.7b11656

(Arylimido)Vanadium(V)-Alkylidenes Containing Chlorinated Phenoxy Ligands: Thermally Robust, Highly Active Catalyst in Ring-Opening Metathesis Polymerization of Cyclic Olefins

Sapanna Chaimongkolkunasin and Kotohiro Nomura

Organometallics, 2018, 37, 2064
DOI: 10.1021/acs.organomet.8b00231

Vanadium NMR Chemical Shifts of (Imido)vanadium(V) Dichloride Complexes with Imidazolin-2-iminato and Imidazolidin-2-iminato Ligands: Cooperation with Quantum-Chemical Calculations and Multiple Linear Regression Analyses

Jun Yi, Wenhong Yang, Wen-Hua Sun, Kotohiro Nomura and Masahiko Hada

J. Phys. Chem. A, 2017, 121, 9099
DOI: 10.1021/acs.jpca.7b08328

Metal‐Free Ring‐Opening Metathesis Polymerization with Hydrazonium Initiators**

Phong K. Quach, Jesse H. Hsu, Ivan Keresztes, Brett P. Fors and Tristan H. Lambert

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202203344

(Arylimido)niobium(V) Complexes Containing 2-Pyridylmethylanilido Ligand as Catalyst Precursors for Ethylene Dimerization That Proceeds via Cationic Nb(V) Species

Masaharu Kuboki and Kotohiro Nomura

Organometallics, 2019, 38, 1544
DOI: 10.1021/acs.organomet.9b00017

Hoveyda-Grubbs type complexes with ruthenium-pnictogen/halcogen/halogen coordination bond. Synthesis, catalytic activity, applications.

A. S. Antonova and F. I. Zubkov

RUSS CHEM REV, 2024, 93, RCR5132
DOI: 10.59761/RCR5132

Stereospecific Ring‐Opening Metathesis Polymerization of Norbornene Catalyzed by Iron Complexes

Dmitry S. Belov, Logesh Mathivathanan, Melanie J. Beazley, William Blake Martin and Konstantin V. Bukhryakov

Angewandte Chemie, 2021, 133, 2970
DOI: 10.1002/ange.202011150

Iron(III) porphyrin catalyzed ionic liquid mediated polymerization of methylmethacrylate

Anchal Singhal, Sohail Ahmad and Shive M.S. Chauhan

Applied Organom Chemis, 2018, 32
DOI: 10.1002/aoc.4044

Norbornene, norbornadiene and their derivatives: promising semi-products for organic synthesis and production of polymeric materials

Vitaly R. Flid, Maria L. Gringolts, Ravshan S. Shamsiev and Evgene Sh. Finkelshtein

Russ. Chem. Rev., 2018, 87, 1169
DOI: 10.1070/RCR4834

Decarboxylative alkylarylation of alkenes with PhI(O2CR)2 to access benzimidazo[2,1-a]isoquinolin-6(5H)-ones catalyzed by a low-valent divanadium complex

Lei Zhang, Peipei Chen and Shaokun Bai

Molecular Catalysis, 2022, 522, 112200
DOI: 10.1016/j.mcat.2022.112200

A partially serendipitous discovery of thermo-switchable ruthenium olefin metathesis initiator that seem to be well suited for ROMP of monomers bearing vinyl pendant groups

Katarzyna Szwaczko, Izabela Czeluśniak and Karol Grela

Journal of Organometallic Chemistry, 2017, 847, 146
DOI: 10.1016/j.jorganchem.2017.04.003

Vanadium-Catalyzed Cross Metathesis: Limitations and Implications for Future Catalyst Design

Wesley S. Farrell

Organometallics, 2019, 38, 3481
DOI: 10.1021/acs.organomet.9b00362

Influence of Ligands and Oxidation State on the Reactivity of Pentacoordinated Iron Carbenes with Olefins: Metathesis versus Cyclopropanation

Égil de Brito Sá, Luis Rodríguez-Santiago, Mariona Sodupe and Xavier Solans-Monfort

Organometallics, 2018, 37, 1229
DOI: 10.1021/acs.organomet.7b00786

Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts

Kamal M. Dawood and Kotohiro Nomura

Adv Synth Catal, 2021, 363, 1970
DOI: 10.1002/adsc.202001117

(Arylimido)vanadium(V)-Alkylidene Complexes as Catalysts for Ring-opening Metathesis Polymerization (ROMP) of Cyclic Olefins: Ligand Design for Exhibiting the High Activity

Kotohiro Nomura and Sapanna Chaimongkolkunasin

Chin J Polym Sci, 2019, 37, 943
DOI: 10.1007/s10118-019-2298-9

Stereospecific Ring‐Opening Metathesis Polymerization of Norbornene Catalyzed by Iron Complexes

Dmitry S. Belov, Logesh Mathivathanan, Melanie J. Beazley, William Blake Martin and Konstantin V. Bukhryakov

Angew Chem Int Ed, 2021, 60, 2934
DOI: 10.1002/anie.202011150

Attempts at generating metathesis-active Fe(IV) and Co(IV) complexes via the reactions of (silox)2M(THF)2, [(silox)3M][Na(THF)2] (M = Fe, Co), and related species with propellanes and triphenylboron

Gregory M. George, Peter T. Wolczanski and Samantha N. MacMillan

Polyhedron, 2022, 215, 115656
DOI: 10.1016/j.poly.2022.115656

Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Alkyl and Perhalophenoxy Alkylidenes for the Cis, Syndiospecific Ring Opening Metathesis Polymerization of Norbornene

Yuta Kawamoto, Iris Elser, Michael R. Buchmeiser and Kotohiro Nomura

Organometallics, 2021, 40, 2017
DOI: 10.1021/acs.organomet.1c00271

Synthesis of (Arylmido)niobium(V) Complexes Containing Ketimide, Phenoxide Ligands, and Some Reactions with Phenols and Alcohols

Natta Srisupap, Kritdikul Wised, Ken Tsutsumi and Kotohiro Nomura

ACS Omega, 2018, 3, 6166
DOI: 10.1021/acsomega.8b01065

Synthesis of (Arylimido)niobium(V) Bis(diethylamide) Complexes Containing Phenoxide Ligands

Nonoka Nakashima, Sirichok Paosopa and Kotohiro Nomura

Zeitschrift anorg allge chemie, 2024, 650
DOI: 10.1002/zaac.202300255

Use of Vanadium Complexes Bearing Naphthalene-Bridged Nitrogen-Sulfonate Ligands as Catalysts for Copolymerization of Ethylene and Propylene

Xiufeng Hao, Chundi Zhang, Lin Li, Hexin Zhang, Yanming Hu, Daifeng Hao and Xuequan Zhang

Polymers, 2017, 9, 325
DOI: 10.3390/polym9080325

Catalytic Applications of Vanadium: A Mechanistic Perspective

Ryan R. Langeslay, David M. Kaphan, Christopher L. Marshall, Peter C. Stair, Alfred P. Sattelberger and Massimiliano Delferro

Chem. Rev., 2019, 119, 2128
DOI: 10.1021/acs.chemrev.8b00245

Efficient Ring Closing Metathesis by NHC-Supported (Arylimido)vanadium(V)-Alkylidene Catalysts Containing Perhalophenoxide Ligands: Exclusive RCM under High Substrate Concentration

Jirapa Suthala, Moe Unoki, Michael R. Buchmeiser and Kotohiro Nomura

Organometallics, 2025, 44, 1870
DOI: 10.1021/acs.organomet.5c00224

(Imido)Vanadium Complex Catalysts for Efficient Ring-Opening Metathesis Polymerization of Cyclic Olefins

Kotohiro NOMURA and Hitomi HAYASHIBARA

KOBUNSHI RONBUNSHU, 2018, 75, 543
DOI: 10.1295/koron.2018-0034

Olefin Metathesis by First‐Row Transition Metals

Dmitry S. Belov, Gabriela Tejeda and Konstantin V. Bukhryakov

ChemPlusChem, 2021, 86, 924
DOI: 10.1002/cplu.202100192

Pushing the Bounds of Olefin Metathesis with Vanadium

Wesley S. Farrell

Zeitschrift anorg allge chemie, 2021, 647, 584
DOI: 10.1002/zaac.202000403

Ring‐Closing Olefin Metathesis Catalyzed by Well‐Defined Vanadium Alkylidene Complexes

Dmitry S. Belov, Gabriela Tejeda, Charlene Tsay and Konstantin V. Bukhryakov

Chemistry A European J, 2021, 27, 4578
DOI: 10.1002/chem.202005438

Olefin metathesis polymerization: Some recent developments in the precise polymerizations for synthesis of advanced materials (by ROMP, ADMET)

Yanjun Chen, Mohamed Mehawed Abdellatif and Kotohiro Nomura

Tetrahedron, 2018, 74, 619
DOI: 10.1016/j.tet.2017.12.041

Ring opening metathesis polymerization of norbornene and tetracyclododecene with cyclooctene by using (arylimido)vanadium(V)–alkylidene catalyst

Sapanna Chaimongkolkunasin, Xiaohua Hou and Kotohiro Nomura

J. Polym. Sci. Part A: Polym. Chem., 2017, 55, 3067
DOI: 10.1002/pola.28622