Assisted deprotonation of formic acid on Cu(111) and self-assembly of 1D chains

Ashleigh E. Baber, Kumudu Mudiyanselage, Sanjaya D. Senanayake, Alba Beatriz-Vidal, Kyle A. Luck, E. Charles H. Sykes, Ping Liu, José A. Rodriguez and Darío J. Stacchiola

Phys. Chem. Chem. Phys., 2013, 15, 12291
DOI: 10.1039/c3cp51533h

New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions

Francisco Zaera

Chem. Soc. Rev., 2014, 43, 7624
DOI: 10.1039/C3CS60374A

Investigation of trimethylacetic acid adsorption on stoichiometric and oxygen-deficient CeO2(111) surfaces

Shail Sanghavi, Weina Wang, Manjula I. Nandasiri, Ajay S. Karakoti, Wenliang Wang, Ping Yang and S. Thevuthasan

Phys. Chem. Chem. Phys., 2016, 18, 15625
DOI: 10.1039/C6CP00855K

The surface structure matters: thermal stability of phthalic acid anchored to atomically-defined cobalt oxide films

Tao Xu, Matthias Schwarz, Kristin Werner, Susanne Mohr, Max Amende and Jörg Libuda

Phys. Chem. Chem. Phys., 2016, 18, 10419
DOI: 10.1039/C6CP00296J

CO2 electrochemical reduction at thiolate-modified bulk Au electrodes

Yuxin Fang, Xun Cheng, John C. Flake and Ye Xu

Catal. Sci. Technol., 2019, 9, 2689
DOI: 10.1039/C9CY00506D

Refining the mechanism of CO2 and H2 activation over gold-ceria catalysts by IR modulation excitation spectroscopy

Jakob Weyel and Christian Hess

Phys. Chem. Chem. Phys., 2024, 26, 6608
DOI: 10.1039/D3CP05102A

Selectivity switching resulting in the formation of benzene by surface carbonates on ceria in catalytic gas-phase oxidation of benzyl alcohol

Yihu Dai, Xin-Ping Wu, Yu Tang, Yanhui Yang, Xue-Qing Gong and Jie Fan

Chem. Commun., 2016, 52, 2827
DOI: 10.1039/C5CC08904B

Nonthermal Catalytic Origin in DC-Enhanced Dry Reforming of Methane Unveiled by Multimodal Operando Analyses

Harunobu Tedzuka, Hikaru Saito, Nobuki Matsumoto, Masanari Nagasaka, Hiromasa Sato, Yasushi Sekine and Toshiki Sugimoto

J. Phys. Chem. Lett., 2025, 16, 12973
DOI: 10.1021/acs.jpclett.5c03159

Analysis and characterization of coordination compounds by resonance Raman spectroscopy

Maria Wächtler, Julien Guthmuller, Leticia González and Benjamin Dietzek

Coordination Chemistry Reviews, 2012, 256, 1479
DOI: 10.1016/j.ccr.2012.02.004

Chemical Functionalization of ZnS: A Perspective from the Ligand–ZnS Bond Character

Hongbiao Tao, Phillip Choi, Qi Liu and Zhenghe Xu

J. Phys. Chem. C, 2019, 123, 6054
DOI: 10.1021/acs.jpcc.8b12227

Formic acid adsorption and decomposition on clean and atomic oxygen pre-covered Cu(100) surfaces

Guihang Li, Weijun Guo, Xiong Zhou, Xin Yu and Junfa Zhu

The Journal of Chemical Physics, 2020, 152
DOI: 10.1063/1.5142586

Oxygen Vacancy-Assisted Coupling and Enolization of Acetaldehyde on CeO2(111)

Florencia C. Calaza, Ye Xu, David R. Mullins and Steven H. Overbury

J. Am. Chem. Soc., 2012, 134, 18034
DOI: 10.1021/ja3074243

CO2 hydrogenation to lower olefins over Mn2O3-ZnO/SAPO-34 tandem catalysts

Jun Mou, Xingqi Fan, Fei Liu, Xiaodan Wang, Tianxiang Zhao, Peng Chen, Ziwei Li, Chunliang Yang and Jianxin Cao

Chemical Engineering Journal, 2021, 421, 129978
DOI: 10.1016/j.cej.2021.129978

A dual promotional effect of doping tantalum (Ta) in atomically dispersed Ru/CeO2 catalyst toward CO2 methanation: Enhanced associative adsorption of CO2 and activation of H2

Deboshree Mukherjee, Supriya Swain, Steven L. Farrell, Kim Kisslinger, Sounak Roy, Benjaram M. Reddy and José A. Rodriguez

Applied Catalysis O: Open, 2025, 209, 207077
DOI: 10.1016/j.apcato.2025.207077

Understanding of Au-CeO2 interface and its role in catalytic oxidation of formaldehyde

Yibin Bu, Yafeng Chen, Guiming Jiang, Xinmei Hou, Shun Li and Zuotai Zhang

Applied Catalysis B: Environmental, 2020, 260, 118138
DOI: 10.1016/j.apcatb.2019.118138

Mechanism of the Periodic Unsteady-State Water–Gas Shift Reaction on Highly Dispersed Cu-Loaded CeO2 Catalysts

Ningqiang Zhang, Shinta Miyazaki, Yucheng Qian, Yuan Jing, Takashi Toyao and Ken-ichi Shimizu

ACS Catal., 2023, 13, 8503
DOI: 10.1021/acscatal.3c02240

Surface structure dependence of selective oxidation of ethanol on faceted CeO2 nanocrystals

Meijun Li, Zili Wu and S.H. Overbury

Journal of Catalysis, 2013, 306, 164
DOI: 10.1016/j.jcat.2013.06.019

Theoretical Study of Trimethylacetic Acid Adsorption on CeO2(111) Surface

Weina Wang, S. Thevuthasan, Wenliang Wang and Ping Yang

J. Phys. Chem. C, 2016, 120, 2655
DOI: 10.1021/acs.jpcc.5b09790

Simulated Temperature Programmed Desorption of Acetaldehyde on CeO2(111): Evidence for the Role of Oxygen Vacancy and Hydrogen Transfer

Chuanlin Zhao and Ye Xu

Top Catal, 2017, 60, 446
DOI: 10.1007/s11244-016-0703-y

Dissociative Adsorption of Benzoic Acid on Well-Ordered Cobalt Oxide Surfaces: Role of the Protons

Matthias Schwarz, Chantal Hohner, Susanne Mohr and Jörg Libuda

J. Phys. Chem. C, 2017, 121, 28317
DOI: 10.1021/acs.jpcc.7b09426

Adsorption, Desorption, and Decomposition of Formic Acid on Cu(977): The Importance of Facet of the Step

Wataru Osada, Shunsuke Tanaka, Kozo Mukai, Young Hyun Choi and Jun Yoshinobu

J. Phys. Chem. C, 2022, 126, 8354
DOI: 10.1021/acs.jpcc.2c01948

Surface ligand assisted valence change in ceria nanocrystals

J. Zhang, T. Naka, S. Ohara, K. Kaneko, T. Trevethan, A. Shluger and T. Adschiri

Phys. Rev. B, 2011, 84
DOI: 10.1103/PhysRevB.84.045411

Elucidating the mechanism of the reverse water–gas shift reaction over Au/CeO2 catalysts using operando and transient spectroscopies

Marc Ziemba, Jakob Weyel and Christian Hess

Applied Catalysis B: Environmental, 2022, 301, 120825
DOI: 10.1016/j.apcatb.2021.120825

H2 production by formic acid decomposition on ceria-modified Ru/TiO2 catalysts under dual photonic/thermal excitation

José M. Montes-Monroy, Ramón Manzorro, Laura Valenzuela, Javier Ivanez, José A. Pérez-Omil and Nicolas Keller

Catalysis Today, 2024, 441, 114852
DOI: 10.1016/j.cattod.2024.114852

Enhanced methanol decomposition via metal-support interaction on Ni/CeO2(111) surface

Yi Tu, Xingwang Cheng, Luchao Huang, Dongling Zhang, Jun Hu, Qian Xu, Honghe Ding and Junfa Zhu

Chinese Journal of Chemical Physics, 2025, 38, 259
DOI: 10.1063/1674-0068/cjcp2409130

Carboxylic acid induced restructuring of the Fe3O4(001) surface

José J. Ortiz-Garcia, Benjamin A. Jackson, Marcus A. Sharp, Peter S. Rice, Mal-Soon Lee, Zbynek Novotny and Zdenek Dohnálek

The Journal of Chemical Physics, 2025, 163
DOI: 10.1063/5.0303965

The Role of Surface Hydroxyls in Dehydration and Dehydrogenation of Formic Acid on Fe3O4(001)

Marcus A. Sharp, Hoan K. K. Nguyen, Christopher J. Lee, Eric Sauter, Yuemin Wang, Christof Wöll, Benjamin A. Jackson, Mal-Soon Lee, Bruce D. Kay, Simone Raugei, Líney Árnadóttir and Zdenek Dohnálek

J. Phys. Chem. C, 2025, 129, 2988
DOI: 10.1021/acs.jpcc.4c07537

Effect of strain on the adsorption of carboxylic acids on the surfaces of cerium oxide

Sidra Munir, Craig J. Neal, Lisa J. Gillie, David J. Cooke, Sudipta Seal and Marco Molinari

Surfaces and Interfaces, 2025, 76, 107836
DOI: 10.1016/j.surfin.2025.107836

Anchoring of a Carboxyl-Functionalized Norbornadiene Derivative to an Atomically Defined Cobalt Oxide Surface

Matthias Schwarz, Susanne Mohr, Tao Xu, Tibor Döpper, Cornelius Weiß, Katharina Civale, Andreas Hirsch, Andreas Görling and Jörg Libuda

J. Phys. Chem. C, 2017, 121, 11508
DOI: 10.1021/acs.jpcc.7b02620

Atomically Dispersed Cobalt/Copper Dual‐Metal Catalysts for Synergistically Boosting Hydrogen Generation from Formic Acid

Yanzhe Shi, Bingcheng Luo, Runqi Liu, Rui Sang, Dandan Cui, Henrik Junge, Yi Du, Tianle Zhu, Matthias Beller and Xiang Li

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202313099

In situ FTIR and Raman study on the distribution and reactivity of surface vanadia species in V2O5/CeO2 catalysts

Marta V. Bosco, Miguel A. Bañares, María V. Martínez-Huerta, Adrian L. Bonivardi and Sebastián E. Collins

Journal of Molecular Catalysis A: Chemical, 2015, 408, 75
DOI: 10.1016/j.molcata.2015.07.012

Dissociative Binding of Carboxylic Acid Ligand on Nanoceria Surface in Aqueous Solution: A Joint In Situ Spectroscopic Characterization and First-Principles Study

Zhou Lu, Ajay Karakoti, Luis Velarde, Weina Wang, Ping Yang, Suntharampillai Thevuthasan and Hong-fei Wang

J. Phys. Chem. C, 2013, 117, 24329
DOI: 10.1021/jp4068747

Pd nanoparticles confined in pure Silicalite-2 zeolite with enhanced catalytic performance for the dehydrogenation of formic acid at room temperature

Min Deng, Jun Ma, Yuantong Liu, Yongkang Pang, Chunliang Yang, Tingting Cao, Zhongchun Yuan, Mengqin Yao, Fei Liu and Xiaodan Wang

Fuel, 2023, 333, 126466
DOI: 10.1016/j.fuel.2022.126466

Catalytic roles of In2O3 in ZrO2-based binary oxides for CO2 hydrogenation to methanol

Yanling Wei, Fei Liu, Jun Ma, Chunliang Yang, Xiaodan Wang and Jianxin Cao

Molecular Catalysis, 2022, 525, 112354
DOI: 10.1016/j.mcat.2022.112354

Insights into the Nature of Formate Species in the Decomposition and Reaction of Methanol over Cerium Oxide Surfaces: A Combined Infrared Spectroscopy and Density Functional Theory Study

P. G. Lustemberg, M. V. Bosco, A. Bonivardi, H. F. Busnengo and M. V. Ganduglia-Pirovano

J. Phys. Chem. C, 2015, 119, 21452
DOI: 10.1021/acs.jpcc.5b05070

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts

Florencia C. Calaza, Tsung-Liang Chen, David R. Mullins and Steven H. Overbury

Top Catal, 2011, 54, 56
DOI: 10.1007/s11244-011-9648-3

First-principles characterization of formate and carboxyl adsorption on stoichiometric CeO2(111) and CeO2(110) surfaces

Donghai Mei

Journal of Energy Chemistry, 2013, 22, 524
DOI: 10.1016/S2095-4956(13)60069-8

Adsorption and Decomposition of Formic Acid on Model Ceria and Pt/Ceria Catalysts

Yaroslava Lykhach, Markus Happel, Viktor Johánek, Tomáš Skála, Fabian Kollhoff, Nataliya Tsud, Filip Dvořák, Kevin C. Prince, Vladimír Matolín and Jörg Libuda

J. Phys. Chem. C, 2013, 117, 12483
DOI: 10.1021/jp311008v

Bifunctional catalyst consisting of In-modified GaZrOx ternary solid solution oxide and SAPO-34 for efficiently converting CO2 into light olefins

Shike Liu, Fei Liu, Mengqin Yao, Jun Ma, Shuo Geng and Jianxin Cao

Applied Catalysis A: General, 2023, 667, 119464
DOI: 10.1016/j.apcata.2023.119464

Oxidation of a Tb2O3(111) Thin Film on Pt(111) by Gas-Phase Oxygen Atoms

William Cartas, Rahul Rai, Ajinkya Sathe, Andreas Schaefer and Jason F. Weaver

J. Phys. Chem. C, 2014, 118, 20916
DOI: 10.1021/jp505310y

Structure‐Dependent Anchoring of Organic Molecules to Atomically Defined Oxide Surfaces: Phthalic Acid on Co3O4(111), CoO(100), and CoO(111)

Tao Xu, Matthias Schwarz, Kristin Werner, Susanne Mohr, Max Amende and Jörg Libuda

Chemistry A European J, 2016, 22, 5384
DOI: 10.1002/chem.201504810

Cu-Enhanced Surface Defects and Lattice Mobility of Pr-CeO2 Mixed Oxides

Anita M. D’Angelo, Zili Wu, Steven H. Overbury and Alan L. Chaffee

J. Phys. Chem. C, 2016, 120, 27996
DOI: 10.1021/acs.jpcc.6b08947

Epitaxial Cubic Ce2O3 Films via Ce–CeO2 Interfacial Reaction

Vitalii Stetsovych, Federico Pagliuca, Filip Dvořák, Tomáš Duchoň, Mykhailo Vorokhta, Marie Aulická, Jan Lachnitt, Stefan Schernich, Iva Matolínová, Kateřina Veltruská, Tomáš Skála, Daniel Mazur, Josef Mysliveček, Jörg Libuda and Vladimír Matolín

J. Phys. Chem. Lett., 2013, 4, 866
DOI: 10.1021/jz400187j

Efficient Sensitization of Dye-Sensitized Solar Cells by Novel Triazine-Bridged Porphyrin–Porphyrin Dyads

Galateia E. Zervaki, Mahesh S. Roy, Manas K. Panda, Panagiotis A. Angaridis, Emmanouel Chrissos, Ganesh D. Sharma and Athanassios G. Coutsolelos

Inorg. Chem., 2013, 52, 9813
DOI: 10.1021/ic400774p

The surface chemistry of cerium oxide

David R. Mullins

Surface Science Reports, 2015, 70, 42
DOI: 10.1016/j.surfrep.2014.12.001

Hydrogen activation, diffusion, and clustering on CeO2(111): A DFT+U study

Delia Fernández-Torre, Javier Carrasco, M. Verónica Ganduglia-Pirovano and Rubén Pérez

The Journal of Chemical Physics, 2014, 141
DOI: 10.1063/1.4885546

Atomically Dispersed Cobalt/Copper Dual‐Metal Catalysts for Synergistically Boosting Hydrogen Generation from Formic Acid

Yanzhe Shi, Bingcheng Luo, Runqi Liu, Rui Sang, Dandan Cui, Henrik Junge, Yi Du, Tianle Zhu, Matthias Beller and Xiang Li

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202313099

Insights into hydrogen generation from formic acid on PtRuBiOx in aqueous solution at room temperature

Chaoquan Hu, Siu-Wa Ting, Kwong-Yu Chan and Wei Huang

International Journal of Hydrogen Energy, 2013, 38, 8720
DOI: 10.1016/j.ijhydene.2013.04.151

Metal-support interface configuration dictates the CO2 hydrogenation pathway on nickel-based catalysts

Jingqi Li, Shuke Li, Xu Wang, Wei Chu, Luming Li, Hongmei Li and Hui Kang

Journal of Colloid and Interface Science, 2026, 713, 140138
DOI: 10.1016/j.jcis.2026.140138

Isolation and characterization of formates on CeO –Cu O/Cu(1 1 1)

Kumudu Mudiyanselage, Ashleigh E. Baber, Zongyuan Liu, Sanjaya D. Senanayake and Darío J. Stacchiola

Catalysis Today, 2015, 240, 190
DOI: 10.1016/j.cattod.2014.06.001

Reassignment of the Vibrational Spectra of Carbonates, Formates, and Related Surface Species on Ceria: A Combined Density Functional and Infrared Spectroscopy Investigation

Georgi N. Vayssilov, Mihail Mihaylov, Petko St. Petkov, Konstantin I. Hadjiivanov and Konstantin M. Neyman

J. Phys. Chem. C, 2011, 115, 23435
DOI: 10.1021/jp208050a

H2 Dissociation and Oxygen Vacancy Formation on Ce2O3 Surfaces

O. Matz and M. Calatayud

Top Catal, 2019, 62, 956
DOI: 10.1007/s11244-019-01183-0

CO‐Tolerant Heterogeneous Ruthenium Catalysts for Efficient Formic Acid Dehydrogenation

Guangxin Xue, Yueyue Jiao, Xiang Li, Tian Lin, Caoyu Yang, Sihan Chen, Zupeng Chen, Haifeng Qi, Stephan Bartling, Haijun Jiao, Henrik Junge and Matthias Beller

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202416530

CeO 2 nanopowders as solid sorbents for efficient CO 2 capture/release processes

Cedric Slostowski, Samuel Marre, Philippe Dagault, Odile Babot, Thierry Toupance and Cyril Aymonier

Journal of CO2 Utilization, 2017, 20, 52
DOI: 10.1016/j.jcou.2017.03.023

Site Requirements for the Adsorption and Reaction of Oxygenates on Metal Oxide Surfaces

John M. Vohs

Chem. Rev., 2013, 113, 4136
DOI: 10.1021/cr300328u

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2

Jesús Graciani, Kumudu Mudiyanselage, Fang Xu, Ashleigh E. Baber, Jaime Evans, Sanjaya D. Senanayake, Darío J. Stacchiola, Ping Liu, Jan Hrbek, Javier Fernández Sanz and José A. Rodriguez

Science, 2014, 345, 546
DOI: 10.1126/science.1253057

Activation of dimethyl carbonate on CeO2 surface: A combined experimental and theoretical study

Fang-Yi Tu, Hou-Jen Lai, Te-An Chiu, Jyh-Chiang Jiang and Wen-Yueh Yu

Surfaces and Interfaces, 2023, 43, 103597
DOI: 10.1016/j.surfin.2023.103597

Interplay of Structural Properties and Redox Behavior in CeO2 Nanoparticles: Impact on Reactivity and Bioavailability

Bei Liu, Yu Pan, Zixin Han, Yufei Shu, Xun Liu, Meng Zhang, Aling Wan, Mengxia Wang, Yixin Tan and Zhongying Wang

Environ. Sci. Technol., 2025, 59, 4641
DOI: 10.1021/acs.est.4c10490

Organic linkers on oxide surfaces: Adsorption and chemical bonding of phthalic anhydride on MgO(100)

Susanne Mohr, Tibor Doepper, Tao Xu, Quratulain Tariq, Ole Lytken, Mathias Laurin, Hans-Peter Steinrueck, Andreas Goerling and Joerg Libuda

Surface Science, 2016, 646, 90
DOI: 10.1016/j.susc.2015.06.027

Adjusting Morphology and Surface Reduction of CeO2(111) Thin Films on Cu(111)

F. Dvořák, O. Stetsovych, M. Steger, E. Cherradi, I. Matolínová, N. Tsud, M. Škoda, T. Skála, J. Mysliveček and V. Matolín

J. Phys. Chem. C, 2011, 115, 7496
DOI: 10.1021/jp1121646

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide

David R. Mullins, Peter M. Albrecht and Florencia Calaza

Top Catal, 2013, 56, 1345
DOI: 10.1007/s11244-013-0146-7

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1)

Florencia C. Calaza, Tsung-Liang Chen, David R. Mullins, Ye Xu and Steven H. Overbury

Catalysis Today, 2015, 253, 65
DOI: 10.1016/j.cattod.2015.03.033

Adsorption structure of adenine on cerium oxide

Sofiia Bercha, Suman Bhasker-Ranganath, Xiaohui Zheng, Klára Beranová, Mykhailo Vorokhta, Robert G. Acres, Tomáš Skála, Vladimír Matolín, Kevin C. Prince, Ye Xu and Nataliya Tsud

Applied Surface Science, 2020, 530, 147257
DOI: 10.1016/j.apsusc.2020.147257

Highly‐Efficient Low‐Loading Co Atom Sites Catalyst for Hydrogen Generation From Formic Acid

Xingmian Zhang, Junmin Wang, Yunhui Hao, Mingzhu Gao, Xiaogeng Zhao, Wenli Ma, Decai Wang, Yanling Ren, Yixuanfei Gao, Jiajia Li, Zihan Wen, Zheng Wang, Chun Wang and Cheng Feng

Carbon Energy, 2025, 7
DOI: 10.1002/cey2.70092

Ceria Nanocatalysts: Shape Dependent Reactivity and Formation of OH

Shilpa Agarwal, Leon Lefferts and Barbara L. Mojet

ChemCatChem, 2013, 5, 479
DOI: 10.1002/cctc.201200491

Investigation of the Ligand–Nanoparticle Interface: A Cryogenic Approach for Preserving Surface Chemistry

Ajay S. Karakoti, Ping Yang, Weina Wang, Vaishwik Patel, Abraham Martinez, Vaithiyalingam Shutthanandan, Sudipta Seal and Suntharampillai Thevuthasan

J. Phys. Chem. C, 2018, 122, 3582
DOI: 10.1021/acs.jpcc.7b09930

Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment

Joachim Paier, Christopher Penschke and Joachim Sauer

Chem. Rev., 2013, 113, 3949
DOI: 10.1021/cr3004949

CO‐Tolerant Heterogeneous Ruthenium Catalysts for Efficient Formic Acid Dehydrogenation

Guangxin Xue, Yueyue Jiao, Xiang Li, Tian Lin, Caoyu Yang, Sihan Chen, Zupeng Chen, Haifeng Qi, Stephan Bartling, Haijun Jiao, Henrik Junge and Matthias Beller

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202416530