Reaction of the stable silylene Si[(NCH2But)2C6H4-1,2] with lithium amides

Barbara Gehrhus, Peter B. Hitchcock and Massimo Parruci

Dalton Trans., 2005, 2720
DOI: 10.1039/b506610g

Reactions of a stable silylene with halocarbons

Mahmood Delawar, Barbara Gehrhus and Peter B. Hitchcock

Dalton Trans., 2005, 2945
DOI: 10.1039/b507462b

The mechanism and energetics of insertion reactions of silylenes

Kinga Nyíri, Tibor Szilvási and Tamás Veszprémi

Dalton Trans., 2010, 39, 9347
DOI: 10.1039/c0dt00197j

Metal free and selective activation of one C–F bond in a bound CF3 group

Ramachandran Azhakar, Herbert W. Roesky, Hilke Wolf and Dietmar Stalke

Chem. Commun., 2013, 49, 1841
DOI: 10.1039/c3cc38669d

Reactivity Studies of Heteroleptic Silylenes PhC(NtBu)2SiX (X = NPh2, NMe2) toward Selected Azides

Ramachandran Azhakar, Herbert W. Roesky, Julian J. Holstein, Kevin Pröpper and Birger Dittrich

Organometallics, 2013, 32, 358
DOI: 10.1021/om301149q

Isolable Silyl and Germyl Radicals Lacking Conjugation with π-Bonds: Synthesis, Characterization, and Reactivity

Akira Sekiguchi, Tomohide Fukawa, Masaaki Nakamoto, Vladimir Ya. Lee and Masaaki Ichinohe

J. Am. Chem. Soc., 2002, 124, 9865
DOI: 10.1021/ja0126780

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Hilke Wolf and Dietmar Stalke

Organometallics, 2012, 31, 4588
DOI: 10.1021/om3003762

Reactions of Stable Amidinate Chlorosilylene and [1+4]‐Oxidative Addition of N‐Heterocyclic Silylene with N‐Benzylideneaniline

Anukul Jana, Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Prinson P. Samuel, Herbert W. Roesky, Carola Schulzke and Debasis Koley

Eur J Inorg Chem, 2011, 2011, 5006
DOI: 10.1002/ejic.201100661

Reactivity of a Silylsilylene Bearing a Functionalized Diaminochlorosilyl Substituent

Shu‐Hua Zhang, Hui‐Xian Yeong and Cheuk‐Wai So

Chemistry A European J, 2011, 17, 3490
DOI: 10.1002/chem.201002611

Reactivity Studies of Heteroleptic Silylenes with N2O

Ramachandran Azhakar, Kevin Pröpper, Birger Dittrich and Herbert W. Roesky

Organometallics, 2012, 31, 7586
DOI: 10.1021/om3008794

Reaction of the Silylene PhC(NtBu)2SitBu with 4,4′‐Bis(dimethylamino)thiobenzophenone and Treatment of the Silylene PhC(NtBu)2SiC(SiMe3)3 with 3,5‐Di‐tert‐butyl‐o‐benzoquinone

Ramachandran Azhakar, Herbert W. Roesky, Julian J. Holstein and Birger Dittrich

Eur J Inorg Chem, 2013, 2013, 2777
DOI: 10.1002/ejic.201300085

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

Anukul Jana, Prinson P. Samuel, Gašper Tavčar, Herbert W. Roesky and Carola Schulzke

J. Am. Chem. Soc., 2010, 132, 10164
DOI: 10.1021/ja103988d

Synthetic and Structural Studies on the Cyclic Bis(amino)stannylenes Sn[(NR)2C10H6‐1, 8] and their Reactions with SnCl2 or Si[(NCH2But)2C6H4‐1, 2] (R = SiMe3 or CH2But)

Anthony G. Avent, Christian Drost, Barbara Gehrhus, Peter B. Hitchcock and Michael F. Lappert

Zeitschrift anorg allge chemie, 2004, 630, 2090
DOI: 10.1002/zaac.200400319

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

Yun Xiong, Shenglai Yao and Matthias Driess

Organometallics, 2009, 28, 1927
DOI: 10.1021/om801157u

Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide

Ramachandran Azhakar, Sankaranarayana Pillai Sarish, Herbert W. Roesky, Jakob Hey and Dietmar Stalke

Organometallics, 2011, 30, 2897
DOI: 10.1021/om200308u

Synthesis and Structure of an Azatrisilacyclobutane and Its Precursor, a Novel Lithium Enamide Having a Tricyclic (LiNSiO)2 Skeleton

Floria Antolini, Barbara Gehrhus, Peter B. Hitchcock and Michael F. Lappert

Angew. Chem. Int. Ed., 2002, 41, 2568
DOI: 10.1002/1521-3773(20020715)41:14<2568::AID-ANIE2568>3.0.CO;2-Z

The stable silylene Si[(NCH2Bu)2C6H4-1,2]: insertion into LiC or LiSi bonds of lithium alkyls LiR or [Li{Si(SiMe3)3}(THF)3] [R=Me, Bu or CH(SiMe3)2]

Xiaoping Cai, Barbara Gehrhus, Peter B. Hitchcock, Michael F. Lappert and J.Chris Slootweg

Journal of Organometallic Chemistry, 2002, 651, 150
DOI: 10.1016/S0022-328X(02)01315-3

The stable silylene Si[(NCH2But)2C6H4-1,2]: Reactions with Group 14 element halides

Barbara Gehrhus, Peter B. Hitchcock and Helen Jansen

Journal of Organometallic Chemistry, 2006, 691, 811
DOI: 10.1016/j.jorganchem.2005.10.027

The stable silylene Si[(NCH2tBu)2C6H4-1,2]: insertion into LiC or LiSi bonds of lithium alkyls LiR or [LiSi(SiMe3)3(THF)3] [R=Me, tBu or CH(SiMe3)2]

Xiaoping Cai, Barbara Gehrhus, Peter B. Hitchcock, Michael F. Lappert and J.Chris Slootweg

Journal of Organometallic Chemistry, 2002, 643-644, 272
DOI: 10.1016/S0022-328X(01)01273-6

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands

Matthew Asay, Cameron Jones and Matthias Driess

Chem. Rev., 2011, 111, 354
DOI: 10.1021/cr100216y

Reaction of N‐Heterocyclic Silylenes with Thioketone: Formation of Silicon–Sulfur Three (Si‐C‐S)‐ and Five (Si‐C‐C‐C‐S)‐Membered Ring Systems

Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Ricardo A. Mata, Hilke Wolf, Regine Herbst‐Irmer and Dietmar Stalke

Chemistry A European J, 2013, 19, 3715
DOI: 10.1002/chem.201203242

Chemistry of thermally stable bis(amino)silylenes

Barbara Gehrhus and Michael F. Lappert

Journal of Organometallic Chemistry, 2001, 617-618, 209
DOI: 10.1016/S0022-328X(00)00729-4

Syntheses and Reactivities of Stable Halosilylenoids, (Tsi)X2SiLi (Tsi=C(SiMe3)3, X=Br, Cl)

Myong Euy Lee, Hyeon Mo Cho, Young Mook Lim, Jin Kyong Choi, Chang Hee Park, Seong Eun Jeong and Uk Lee

Chemistry A European J, 2004, 10, 377
DOI: 10.1002/chem.200305151

Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol

Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Markus Granitzka and Dietmar Stalke

Organometallics, 2012, 31, 5506
DOI: 10.1021/om300476q

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon‐Mediated, Regio‐ and Stereoselective CH Activation

Yun Xiong, Shenglai Yao and Matthias Driess

Chemistry A European J, 2009, 15, 5545
DOI: 10.1002/chem.200900318

Preparation, Structure and Reactivity of Et2N(Me3Si)2SiK

Michaela Zirngast, Judith Baumgartner and Christoph Marschner

Eur J Inorg Chem, 2008, 2008, 1078
DOI: 10.1002/ejic.200701143

Configurational Stability of [Di(amino)silyl]lithiums Having Cyclic Structures

Atsushi Kawachi, Hirofumi Maeda and Kohei Tamao

Organometallics, 2002, 21, 1319
DOI: 10.1021/om010963m

Reactivity of Stable Heteroleptic Silylene PhC(NtBu)2SiNPh2 toward Diazobenzene and N-Benzylidineaniline

Ramachandran Azhakar, Herbert W. Roesky, Hilke Wolf and Dietmar Stalke

Organometallics, 2012, 31, 8608
DOI: 10.1021/om300999e

Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

Ramachandran Azhakar, Rajendra S. Ghadwal, Herbert W. Roesky, Jakob Hey and Dietmar Stalke

Organometallics, 2011, 30, 3853
DOI: 10.1021/om200388a