Issue 45, 2023

Annulation of enaminones with quinonediimides/quinoneimides for selective synthesis of indoles and 2-aminobenzofurans

Abstract

The annulation reactions of enaminones with quinonediimides/quinoneimides for the selective synthesis of indoles and 2-aminobenzofurans have been realized. With Zn(II) catalysis, quinonediimides reacted with enaminones to give indoles via HNMe2-elimination-based aromatization. With Fe(III) catalysis, the reactions of quinoneimides with enaminones provided 2-aminobenzofurans via a key dehydrogenative aromatization.

Graphical abstract: Annulation of enaminones with quinonediimides/quinoneimides for selective synthesis of indoles and 2-aminobenzofurans

Supplementary files

Article information

Article type
Communication
Submitted
06 ኤፕሪ 2023
Accepted
11 ሜይ 2023
First published
11 ሜይ 2023

Chem. Commun., 2023,59, 6885-6888

Annulation of enaminones with quinonediimides/quinoneimides for selective synthesis of indoles and 2-aminobenzofurans

Z. Zhong, L. Liao, Y. Liu, M. Zhang and J. Wan, Chem. Commun., 2023, 59, 6885 DOI: 10.1039/D3CC01687K

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