Issue 36, 2022

Recent advances of crosslinkable organic semiconductors in achieving solution-processed and stable optoelectronic devices

Abstract

High-efficiency optoelectronic devices are attracting extensive attention nowadays. Besides efficiency, cost and long-term stability are also crucial parameters for judging the performance and application of optoelectronic devices. Multilayer solution processing technology has been proved to be an ideal and low-cost strategy. However, one of the key factors restricting this strategy is solvent erosion during subsequent solution-based device processing. Besides, the long-term stability is of vital significance for the lifetime of optoelectronic devices. Therefore, exploiting solvent-resistant and durable materials is urgently needed. Promisingly, crosslinkable organic semiconductors (COSs) can be crosslinked into an insoluble and stable network structure to achieve solvent resistance and improve long-term stability. In this review, the recent advances in COSs used in optoelectronic devices (organic photovoltaics (OPVs), perovskite solar cells (PerSCs), and organic light-emitting diodes (OLEDs)) are systematically summarized, in which the basic considerations and key challenges to realize solvent resistance and enhance long-term stability are presented first. Then, the significance, strategies, and disadvantages of COSs are introduced. Finally, typical applications of COSs in OPVs, OLEDs, and PerSCs and their prospects are discussed and highlighted. This review is expected to attract further considerable interest in COSs and promote further progress in optoelectronic devices.

Graphical abstract: Recent advances of crosslinkable organic semiconductors in achieving solution-processed and stable optoelectronic devices

Article information

Article type
Review Article
Submitted
05 ጁላይ 2022
Accepted
23 ኦገስ 2022
First published
24 ኦገስ 2022

J. Mater. Chem. A, 2022,10, 18542-18576

Recent advances of crosslinkable organic semiconductors in achieving solution-processed and stable optoelectronic devices

Z. Ma, B. Zhao, H. Gao, Y. Gong, R. Yu and Z. Tan, J. Mater. Chem. A, 2022, 10, 18542 DOI: 10.1039/D2TA05358F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements