Issue 22, 2021

AIE ligand-based silver clusters used for ethion detection

Abstract

Silver clusters usually have intriguing aesthetic structures and multiple application prospects in optical materials, chemocatalysis, bioimaging and chemosensors. However, these practical applications usually suffer from the instability of silver clusters. How to transform this disadvantage into an advantage for meaningful applications of silver clusters remains challenging. In this work, we judiciously prepared a silver cluster of Ag24 using an aggregation-induced emission (AIE) ligand. Due to the argyrophilia of sulfur, Ag24 can be easily destroyed by sulfur-containing pesticides such as ethion, releasing the AIE fragments. As a result, a “turn-on” emission change was observed, making Ag24 a potential chemosensor for detecting ethion in water dominated solutions. This work provides new thoughts for the design of silver cluster-based luminescent chemosensors, and broadens the application range of silver clusters.

Graphical abstract: AIE ligand-based silver clusters used for ethion detection

Supplementary files

Article information

Article type
Research Article
Submitted
21 ኦገስ 2021
Accepted
28 ሴፕቴ 2021
First published
29 ሴፕቴ 2021

Mater. Chem. Front., 2021,5, 7982-7986

AIE ligand-based silver clusters used for ethion detection

Y. Liu, Y. Li, X. Luo, P. Luo, Z. Han, Q. Peng, K. Li, H. Hou and S. Q. Zang, Mater. Chem. Front., 2021, 5, 7982 DOI: 10.1039/D1QM01181B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements