Issue 81, 2019

Templating conformations with cucurbiturils

Abstract

The trans- and cis conformations of 5,5′-substituted 2,2′-dithiophenes can be stabilized when those are secured with two Cucurbit[8]uril macrocycles (CB[8]) on top of rigid 2,6- and 2,7-substituted naphthalenes, which respectively mimic the trans and cis conformations of the dithiophene. The substituents are Pt(II) terpyridyl groups bearing CB[8]-binding sites at their 4′-position, as those form dimers in the presence of the macrocycle through Pt–Pt and dispersive interactions between the terpyridyl ligands.

Graphical abstract: Templating conformations with cucurbiturils

Supplementary files

Article information

Article type
Communication
Submitted
30 ኦገስ 2019
Accepted
16 ሴፕቴ 2019
First published
16 ሴፕቴ 2019

Chem. Commun., 2019,55, 12160-12163

Author version available

Templating conformations with cucurbiturils

N. A. Thompson, H. Barbero and E. Masson, Chem. Commun., 2019, 55, 12160 DOI: 10.1039/C9CC06766C

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