Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage

Yaofeng Wang; Roser Morales-Martínez; Wenting Cai; Jiaxin Zhuang; Wei Yang; Luis Echegoyen; Josep M. Poblet; Antonio Rodríguez-Fortea; Ning Chen

doi:10.1039/C9CC04613E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Th@C₁(11)-C₈₆: an actinide encapsulated in an unexpected C₈₆ fullerene cage†

Yaofeng Wang,‡^a Roser Morales-Martínez,

‡^b Wenting Cai,

‡^c Jiaxin Zhuang,

^a Wei Yang,^a Luis Echegoyen,

^c Josep M. Poblet,

^b Antonio Rodríguez-Fortea

*^b and Ning Chen

*^a

Author affiliations

* Corresponding authors

^a Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, P. R. China
E-mail: chenning@suda.edu.cn

^b Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, c/Marcel·lí Domingo 1, 43007 Tarragona, Spain
E-mail: antonio.rodriguezf@urv.cat

^c Department of Chemistry, University of Texas at El Paso, 500 W University Avenue, El Paso, Texas 79968, USA

Abstract

A novel actinide endohedral fullerene with an unexpected chiral cage, Th@C₁(11)-C₈₆, was synthesized and characterized. DFT calculations suggest that this low symmetry cage was favoured as a consequence of the strong interaction between Th and the cage, which makes the predictions by the ionic model less reliable for these endohedral mono-metallofullerenes.

This article is part of the themed collection: SU 120: Celebrating 120 Years of Soochow University

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9CC04613E
Article type: Communication
Submitted: 17 ጁን 2019
Accepted: 04 ጁላይ 2019
First published: 04 ጁላይ 2019

Download Citation

Chem. Commun., 2019,55, 9271-9274

Permissions

Request permissions

Th@C₁(11)-C₈₆: an actinide encapsulated in an unexpected C₈₆ fullerene cage

Y. Wang, R. Morales-Martínez, W. Cai, J. Zhuang, W. Yang, L. Echegoyen, J. M. Poblet, A. Rodríguez-Fortea and N. Chen, Chem. Commun., 2019, 55, 9271 DOI: 10.1039/C9CC04613E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications