Issue 4, 2018

A helically-twisted ladder based on 9,9′-bifluorenylidene: synthesis, characterization, and carrier-transport properties

Abstract

We synthesized a ladder-shaped 9,9′-bifluorenylidene cyclic dimer (CBF), in which the two 9,9′-bifluorenylidene units are connected directly with two covalent bonds. CBF has a pair of enantiomers which are alternately packed in a perpendicular fashion in the crystal, and these enantiomers exhibit rapid interconversion in solution. Owing to the ladder-type connection, the two 9,9′-bifluorenylidene units in CBF electronically interact upon redox, and thus the structure of CBF is changed stepwise during the oxidation and reduction processes, which was confirmed by electrochemistry and quantum chemical calculations. The π-network of CBF in the solid state leads to its hole transport properties.

Graphical abstract: A helically-twisted ladder based on 9,9′-bifluorenylidene: synthesis, characterization, and carrier-transport properties

Supplementary files

Article information

Article type
Research Article
Submitted
14 ዲሴም 2017
Accepted
24 ጃንዩ 2018
First published
26 ጃንዩ 2018

Mater. Chem. Front., 2018,2, 780-784

A helically-twisted ladder based on 9,9′-bifluorenylidene: synthesis, characterization, and carrier-transport properties

J. Xu, A. Takai, A. Bannaron, T. Nakagawa, Y. Matsuo, M. Sugimoto, Y. Matsushita and M. Takeuchi, Mater. Chem. Front., 2018, 2, 780 DOI: 10.1039/C7QM00583K

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