Issue 45, 2013

Indium metal–organic frameworks as catalysts in solvent-free cyanosilylation reaction

Abstract

Two new Indium MOFs with the bending multicarboxylate ligand H2dpmda as a linker and different N-donor ancillary ligands were obtained; the two compounds are isoreticular with 2D-hcb uninodal 3-connected nets. Comparison of their activity in cyanosilylation reactions with another eight In-MOFs is also reported. Eight out of the ten resulted in being good catalysts under mild and environmentally friendly conditions. Correlations between indium coordination number (CN), framework topology and catalytic activity are made and discussed, demonstrating that among the studied MOFs, the indium material named InPF-6 with the formula [In2(dpa)3(1,10-phen)2]·H2O is the most effective catalyst. A possible catalytic mechanism is discussed.

Graphical abstract: Indium metal–organic frameworks as catalysts in solvent-free cyanosilylation reaction

Supplementary files

Article information

Article type
Paper
Submitted
12 ጁን 2013
Accepted
26 ጁላይ 2013
First published
29 ጁላይ 2013

CrystEngComm, 2013,15, 9562-9571

Indium metal–organic frameworks as catalysts in solvent-free cyanosilylation reaction

L. M. Aguirre-Díaz, M. Iglesias, N. Snejko, E. Gutiérrez-Puebla and M. Á. Monge, CrystEngComm, 2013, 15, 9562 DOI: 10.1039/C3CE41123K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements