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The miscellaneously substituted silyltellanes tBu2PhSiTeSiMe3 (1) and (Me3Si)3SiTeSiMe3 were used to synthesize the cyclic tin(II) and lead(II) tellurolates [(tBu2PhSiTe)4M2] (M = Sn (2), Pb (3)), [tBu2PhSiTePbC(SiMe3)3]2 (4) and the uncommon cluster compound [{(Me3Si)3SiTe}4Te2Sn4] (5).

Graphical abstract: Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition

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