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Addition of E2O (E = Me3Si or H) to [(pyridyl)BX2][AlX4] (X = Cl or Br) and subsequent heating produced the unprecedented trications [(2,6-lutidine)4B5O6]3+ and [(pyridine)4B3O3]3+.

Graphical abstract: Tricationic analogues of boroxines and polyborate anions

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