Conducting polymer functionalization in search of advanced materials in ionometry: ion-selective electrodes and optodes

Abstract

Functionalized conducting polymers (FCPs) have recently garnered attention as ion-selective sensor materials, surpassing their intrinsic counterparts due to synergistic effects that lead to enhanced electrochemical and analytical parameters. Following a brief introduction of the fundamental concepts, this article provides a comprehensive review of the recent developments in the application of FCPs in ion-selective electrodes (ISEs) and ion-selective optodes (ISOs), particularly as ion-to-electron transducers, optical transducers, and ion-selective membranes. Utilizing FCPs in these devices offers a promising avenue for detecting and measuring ions in various applications, regardless of the sample nature and composition. Research has focused on functionalizing different conducting polymers, such as polyaniline and polypyrrole, through strategies such as doping and derivatization to alter their hydrophobicity, conductance, redox capacitance, surface area, pH sensitivity, gas and light sensitivity, etc. These modifications aim to enhance performance outcomes, including potential stability/emission signal stability, reproducibility and low detection limits. The advancements have led to the transition of ISEs from conventional zero-current potentiometric ion sensing to innovative current-triggered sensing approaches, enabling calibration-free applications and emerging concepts such as opto-electro dual sensing systems. The intrinsic pH cross-response and instability of the optical signal of ISOs have been overcome through the novel optical signal transduction mechanisms facilitated by FCPs. In this review, the characteristics of materials, functionalization approaches, particular implementation strategies, specific performance outcomes and challenges faced are discussed. Consolidating dispersed information in the field, the in-depth analysis presented here is poised to drive further innovations by broadening the scope of ion-selective sensors in real-world scenarios.