Issue 5, 2022

A fluorinated 2D magnetic coordination polymer

Abstract

Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(II) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization.

Graphical abstract: A fluorinated 2D magnetic coordination polymer

Supplementary files

Article information

Article type
Paper
Submitted
04 ኖቬም 2021
Accepted
03 ጃንዩ 2022
First published
03 ጃንዩ 2022

Dalton Trans., 2022,51, 1861-1865

A fluorinated 2D magnetic coordination polymer

J. López-Cabrelles, S. Mañas-Valero, I. J. Vitórica-Yrezábal, P. J. Bereciartua, E. Coronado and G. Mínguez Espallargas, Dalton Trans., 2022, 51, 1861 DOI: 10.1039/D1DT03734J

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