A viologen-functionalized metal–organic framework for efficient CO2 photoreduction reaction

Tong Wang; Lei Zhang; Jiang Liu; Xiao-Xin Li; Lin Yuan; Shun-Li Li; Ya-Qian Lan

doi:10.1039/D2CC02650C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A viologen-functionalized metal–organic framework for efficient CO₂ photoreduction reaction†

Tong Wang,^a Lei Zhang,^b Jiang Liu,*^ab Xiao-Xin Li,^ac Lin Yuan,^a Shun-Li Li^b and Ya-Qian Lan

*^ab

Author affiliations

* Corresponding authors

^a Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, P. R. China
E-mail: liuj@njnu.edu.cn, yqlan@m.scnu.edu.cn, yqlan@njnu.edu.cn
Web: https://www.yqlangroup.com

^b School of Chemistry, South China Normal University, Guangzhou, P. R. China

^c School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P. R. China

Abstract

Here, a viologen-functionalized metal–organic framework (MOF), MIL-125-RV²⁺, was obtained by modification of MIL-125-NH₂ with viologen molecules. MIL-125-RV²⁺, the first viologen-based MOF for photocatalytic CO₂RR, exhibited excellent photocatalytic activity and high selectivity for HCOO⁻. The strategy of using photo-responsive color-changing organics to functionalize the MOF is significant for achieving efficient CO₂RR.

This article is part of the themed collections: Emerging Trends in MOFs and Chemical Communications HOT Articles 2022

Download options Please wait...

Supplementary files

Supplementary information PDF (1835K)

Article information

DOI: https://doi.org/10.1039/D2CC02650C
Article type: Communication
Submitted: 10 ሜይ 2022
Accepted: 07 ጁን 2022
First published: 07 ጁን 2022

Download Citation

Chem. Commun., 2022,58, 7507-7510

Permissions

Request permissions

A viologen-functionalized metal–organic framework for efficient CO₂ photoreduction reaction

T. Wang, L. Zhang, J. Liu, X. Li, L. Yuan, S. Li and Y. Lan, Chem. Commun., 2022, 58, 7507 DOI: 10.1039/D2CC02650C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications