FLP-catalysis meets hydrogen-bond activation†
Peter W.
Roesky 
b
and
Jan
Paradies
*a
b
and
Jan
Paradies
*a
Abstract
The potential of two chiral amidines and three non-chiral boranes in the metal-free hydrogen activation was explored. The resulting chiral amidiunium borohydride salts were investigated in asymmetric hydrogenation reactions of ketimines, activated double bonds and dehydro amioacid esters.
- This article is part of the themed collections: p-Block Lewis Acids in Organic Synthesis and Hybrid Catalysis
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