Issue 16, 2017

Phosphine-pyridonate ligands containing octahedral ruthenium complexes: access to esters and formic acid

Abstract

The preparation of three well-defined ruthenium complexes arising from phosphine-pyridon-e/-ate ligands is described. Solvent dependent Lewis acidic species formation was observed with these complexes. Selective formation of acetals or esters from primary alcohols was observed in the presence of these catalysts. Preliminary evaluation of these complexes in the base free hydrogenation of carbon dioxide is also reported.

Graphical abstract: Phosphine-pyridonate ligands containing octahedral ruthenium complexes: access to esters and formic acid

Supplementary files

Article information

Article type
Paper
Submitted
10 ሜይ 2017
Accepted
08 ጁላይ 2017
First published
10 ጁላይ 2017

Catal. Sci. Technol., 2017,7, 3492-3498

Phosphine-pyridonate ligands containing octahedral ruthenium complexes: access to esters and formic acid

A. R. Sahoo, F. Jiang, C. Bruneau, G. V. M. Sharma, S. Suresh, T. Roisnel, V. Dorcet and M. Achard, Catal. Sci. Technol., 2017, 7, 3492 DOI: 10.1039/C7CY00932A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements