Issue 17, 2015

An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

Abstract

We present the first example of an extended 3D framework synthesised without the use of an isolable organic component. This is achieved by the combination of two cage complexes isolated and functionalised prior to synthesis; [nPr2NH2][Cr7NiF8(O2CtBu)14(O2CC5H4N)2] and [Fe2CoO(O2CtBu)6(HO2CtBu)3], where the former is as a bidentate linker, bridging between three nodes of the latter.

Graphical abstract: An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

Supplementary files

Article information

Article type
Communication
Submitted
16 ዲሴም 2014
Accepted
22 ጃንዩ 2015
First published
03 ፌብሩ 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 3533-3536

Author version available

An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

G. F. S. Whitehead, S. J. Teat, K. J. Gagnon, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2015, 51, 3533 DOI: 10.1039/C4CC10035B

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