Issue 45, 2013

Activation of metal–organic framework materials

Abstract

Crystalline metal–organic frameworks (MOFs) have emerged as a highly desirable class of solid-state materials. Some of their most attractive features include exceptionally high porosities as well as surface areas. A key aspect to the realization of high porosity is the removal of guest molecules from the framework while still maintaining its structural integrity (i.e., “activation”). This contribution highlights the strategies utilized to date for activating MOFs, including: (i) conventional heating and vacuum; (ii) solvent-exchange; (iii) supercritical CO2 (scCO2) exchange; (iv) freeze-drying; and (v) chemical treatment.

Graphical abstract: Activation of metal–organic framework materials

Supplementary files

Article information

Article type
Highlight
Submitted
25 ጁን 2013
Accepted
04 ሴፕቴ 2013
First published
11 ኦክቶ 2013

CrystEngComm, 2013,15, 9258-9264

Activation of metal–organic framework materials

J. E. Mondloch, O. Karagiaridi, O. K. Farha and J. T. Hupp, CrystEngComm, 2013, 15, 9258 DOI: 10.1039/C3CE41232F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements