Issue 46, 2006

Structural diversity and chemical trends in hybrid inorganic–organic framework materials

Abstract

Hybrid framework compounds, including both metal–organic coordination polymers and systems that contain extended inorganic connectivity (extended inorganic hybrids), have recently developed into an important new class of solid-state materials. We examine the diversity of this complex class of materials, propose a simple but systematic classification, and explore the chemical and geometrical factors that influence their formation. We also discuss the growing evidence that many hybrid frameworks tend to form under thermodynamic rather than kinetic control when the synthesis is carried out under hydrothermal conditions. Finally, we explore the potential applications of hybrid frameworks in areas such as gas separations and storage, heterogeneous catalysis, and photoluminescence.

Graphical abstract: Structural diversity and chemical trends in hybrid inorganic–organic framework materials

Article information

Article type
Feature Article
Submitted
18 ጁላይ 2006
Accepted
20 ኦክቶ 2006
First published
07 ኖቬም 2006

Chem. Commun., 2006, 4780-4795

Structural diversity and chemical trends in hybrid inorganic–organic framework materials

A. K. Cheetham, C. N. R. Rao and R. K. Feller, Chem. Commun., 2006, 4780 DOI: 10.1039/B610264F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements